Abstract
The potential of metal homoenolates as multifunctional reagents in organic synthesis has become recognized in the last decade. Ring opening of siloxycyclopropanes by Lewis acidic metals currently provides the best route to the metal homoenolates, which are either isolable as a stable complex or exist only as a transient organometallic species. This review summarizes, for the first time, the research activities of metal homoenolate chemistry. Other synthetically useful routes to metal homoenolates are also described.
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8 References
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Kuwajima, I., Nakamura, E. (1990). Metal homoenolates from siloxycyclopropanes. In: deMeijere, A. (eds) Small Ring Compounds in Organic Synthesis IV. Topics in Current Chemistry, vol 155. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-52422-3_1
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DOI: https://doi.org/10.1007/3-540-52422-3_1
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