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Improvement of Dynamic Properties of PLLA/PBAT Polymer Alloys Using Dialkyl Peroxide

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Dynamic Behavior of Materials, Volume 1

Abstract

Polymer alloys of poly(lactic acid) (PLA) and poly(butylene adipate/terephthalate) (PBAT) were used, and the effects of the mixing ratio of PLA and PBAT and the addition of dialkyl peroxide (compatibilizing agent) were examined. The stress–strain curves of PLA/PBAT and PLA/PBAT/dialkyl peroxide specimens were measured using the tensile split Hopkinson pressure bar (Kolsky Bar) method. The mixing ratio of PLA and PBAT and the dialkyl peroxide addition affected the stress–strain curve behavior. The dialkyl peroxide addition increased the elongation at break and changed the fracture surface to a whitened form that was markedly uneven. The elongation at break increased with increasing PBAT content.

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References

  1. Fukuda N, Matsubara H, Kitagawa R (2007) The crystallization behaviors and mechanical properties of poly(lactic acid)/poly(butylenes adipate terephthalate) alloys. In: Proceedings of 59th symposium on macromolecules, in Nagoya pp 5657–5658 2007

    Google Scholar 

  2. Coltelli M-B, Maggiore ID, Bertoldo M, Signori F, Bronco S, Ciardelli F (2008) Poly(lactic acid) properties as a consequence of poly(butylene adipate-co-terephthalate) blending and acetyl tributyl citrate plasticization. J Appl Polym Sci 110:1250–1262

    Article  Google Scholar 

  3. Signori F, Coltelli M-B, Bronco S (2009) Thermal degradation of poly(lactic acid) (PLA) and poly(butylenes adipate-co-terephthalate) (PBAT) and their blends upon melt processing. Polym Degrad Stab 94:74–82

    Article  Google Scholar 

  4. Nishida M, Ichihara H, Fukuda N (2011) Evaluation of dynamic compressive properties of PLA/PBAT polymer alloys using split Hopkinson pressure bar. Eng Trans 59(1):23–30

    Google Scholar 

  5. Nishida M, Ichihara H, Fukuda N (2011) Dynamic properties of PLA/PBAT polymer alloys. In: Proceedings of annual international workshop 2011, dynamic behavior of structures and materials, interaction and friction, in Metz 2011

    Google Scholar 

  6. Gray GT III (2000) Classic split Hopkinson pressure bar testing. In: Mechanical testing and evaluation, vol 8, ASM Handbook. ASM, Materials Park, pp 462–476

    Google Scholar 

  7. Chen W, Song B (2010) Split Hopkinson (Kolsky) bar: design. Testing and Applications, Springer

    Google Scholar 

  8. Ogawa K (2001) Impact tensile characteristics of 6061-T6 aluminum alloy. J Jpn Inst Light Met 51:175–181, in Japanese

    Article  Google Scholar 

  9. Nakai K, Yokoyama T (2008) Strain rate dependence of compressive stress–strain loops of several polymers. J Solid Mech Mater Eng 2(4):557–566

    Article  Google Scholar 

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Acknowledgment

The authors are greatly indebted to Dr. K. Ogawa of the Space Dynamics Laboratory in Japan for his valuable advice with respect to the tensile split Hopkinson pressure bar.

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Correspondence to Masahiro Nishida .

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© 2013 The Society for Experimental Mechanics, Inc.

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Nishida, M., Ichihara, H., Watanabe, H., Fukuda, N., Ito, H. (2013). Improvement of Dynamic Properties of PLLA/PBAT Polymer Alloys Using Dialkyl Peroxide. In: Chalivendra, V., Song, B., Casem, D. (eds) Dynamic Behavior of Materials, Volume 1. Conference Proceedings of the Society for Experimental Mechanics Series. Springer, New York, NY. https://doi.org/10.1007/978-1-4614-4238-7_42

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  • DOI: https://doi.org/10.1007/978-1-4614-4238-7_42

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  • Publisher Name: Springer, New York, NY

  • Print ISBN: 978-1-4614-4237-0

  • Online ISBN: 978-1-4614-4238-7

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