Skip to main content
SpringerLink
Log in

Solid State 13C-NMR Studies on Condensed Tannins

  • Chapter
Plant Polyphenols

Part of the book series: Basic Life Sciences ((BLSC,volume 59))

Abstract

Solid-state 13C-NMR spectroscopy with interrupted decoupling can be used for semi-quantitative determination of condensed tannins in plant fragments. The spectra can also provide some information about the procyanidin:prodelphinidin ratio but not about ratios of cis:trans stereochemistry.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 259.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 329.00
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 329.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Newman R.H.; Porter, L.J.; Foo, L.Y.; Johns, S.R.; Willing, R.I. High-resolution 13C NMR studies of proanthocyanidin polymers (condensed tannins). Mag. Res. Chem. 25:118 (1987).

    Article  CAS  Google Scholar 

  2. Wilson, M.A.; Hatcher, P.G. Detection of tannins in modern and fossil barks and in plant residues by high-resolution solid-state 13C nuclear magnetic resonance. Org. Geochem. 12:539 (1988).

    Article  CAS  Google Scholar 

  3. Czochanska, Z.; Foo, L.Y.; Newman, R.H.; Porter, L.J. Polymeric proanthocyanidins. Stereochemistry, structural units, and molecular weight. J. Chem. Soc., Perkin Trans. 1:2278 (1980).

    Article  Google Scholar 

  4. VanderHart, D.L.; Earl, W.L.; Garroway, A.N. Resolution in 13C NMR of organic solids using high-power proton decoupling and magic-angle sample spinning. J. Magn. Reson. 44:361 (1981).

    Google Scholar 

  5. Czochanska, Z.; Foo, L.Y.; Newman, R.H.; Porter, L.J.; Thomas, W.A.; Jones, W.T. Direct proof of a homogeneous polyflavan-3-ol structure for polymeric proanthocyanidins. J.C.S. Chem. Commun.:375 (1979).

    Google Scholar 

  6. Wilson, M.A.; Verheyen, T.V.; Vassallo, A.M.; Hill, R.S.; Perry, G.J. Selective loss of carbohydrates from plant remains during coalification. Org. Geochem. 4:265(1987).

    Article  Google Scholar 

  7. Harbison, G.S; Mulder, P.P.J.; Pardoen, H.; Lugtenburg, J; Herzfeld, J.; Griffin, R.G. High-resolution carbon-13 NMR of retinal derivatives in the solid state. J. Am. Chem. Soc. 107:4809 (1985).

    Article  CAS  Google Scholar 

  8. Newman, R.H. Analysis of results from interrupted-decoupling NMR pulse sequences combined with high-speed magic-angle spinning. J. Magn. Reson. 86:176 (1990).

    CAS  Google Scholar 

  9. Morgan, K.R.; Newman, R.H. Principal values of carbon-13 NMR chemical shift tensors for a collection of substituted benzenes. J. Am. Chem. Soc. 112:4(1990).

    Article  CAS  Google Scholar 

  10. Wilson, M.A.; Sawyer, J.; Hatcher, P.G.; Lerch, H.E. 1,3,5-hydroxybenzene structures in mosses. Phytochemistry 28:1395 (1989).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. DSIR Chemistry, Private Bag, Lower Hutt, New Zealand

    Roger H. Newman & Lawrence J. Porter

Authors
  1. Roger H. Newman
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Lawrence J. Porter
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. United States Department of Agriculture, Forest Service, Pineville, Louisiana, USA

    Richard W. Hemingway

  2. Institute of Wood Research, Houghton, Michigan, USA

    Peter E. Laks

Rights and permissions

Reprints and permissions

Copyright information

© 1992 Springer Science+Business Media New York

About this chapter

Cite this chapter

Newman, R.H., Porter, L.J. (1992). Solid State 13C-NMR Studies on Condensed Tannins. In: Hemingway, R.W., Laks, P.E. (eds) Plant Polyphenols. Basic Life Sciences, vol 59. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-3476-1_19

Download citation

  • DOI: https://doi.org/10.1007/978-1-4615-3476-1_19

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-6540-2

  • Online ISBN: 978-1-4615-3476-1

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation