Abstract
Recent studies by means of thin-layer electrochemistry of the chemisorption at polycrystalline Pt of hydroquinone, catechol and more than 50 related compounds have revealed that a layer of oriented molecules is formed in virtually all instances1–4. Variables affecting adsorbate orientation include: adsorbate molecular structure, adsorbate concentration, electrode potential, nature of the electrolyte anion, temperature, solvent and structure of the Pt surface. Adsorbate orientation strongly influences the course of electrocatalytic oxidation and reduction3. References 1 and 2 are recent reviews; Reference 4 includes subsequent work.
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References
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© 1988 Plenum Press, New York
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Hubbard, A.T. et al. (1988). Surface Electrochemistry of Amino Acids: Voltammetry Assisted by Eels, Auger Spectroscopy and Leed. In: Dryhurst, G., Niki, K. (eds) Redox Chemistry and Interfacial Behavior of Biological Molecules. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-9534-2_17
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DOI: https://doi.org/10.1007/978-1-4615-9534-2_17
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