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Recent Developments in Chemistry of Organolanthanides and Organoactinides

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Organotransition-Metal Chemistry

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Abstract

In contrast with pi-bonded organometallic compounds of the lanthanides1 and actinides2, which date to the mid 1950’s, encompass a large variety of ligands3 and culminate with the synthesis of bis-(cyclooctatetraenyl)uranium (“uranocene”),4 the preparation of sigma-bonded lanthanide and actinide organometallics is relatively recent. Early attempts to prepare simple oganometallic derivatives, such as U(CH3)4 5, Y(C2H5)3, and Sc(C2H5)3 6, often resulted in poorly characterized or irreproducible products. Sigma-bonded derivatives of both the lanthanide7,8 and actinide9 elements are now known and well characterized.10

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Author information

Authors and Affiliations

  1. Department of Chemistry, Texas A&M University, College Station, Texas, 77843, USA

    Minoru Tsutsui, Carol Hyde, Alan Gebala & Neal Ely

Authors
  1. Minoru Tsutsui
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  2. Carol Hyde
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  3. Alan Gebala
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  4. Neal Ely
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Editor information

Editors and Affiliations

  1. Department of Synthetic Chemistry, Nagoya University, Chikusa, Nagoya, Japan

    Yoshio Ishii

  2. Department of Chemistry, Texas A&M University, College Station, Texas, USA

    Minoru Tsutsui

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© 1975 Plenum Press, New York

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Tsutsui, M., Hyde, C., Gebala, A., Ely, N. (1975). Recent Developments in Chemistry of Organolanthanides and Organoactinides. In: Ishii, Y., Tsutsui, M. (eds) Organotransition-Metal Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-2142-2_8

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  • DOI: https://doi.org/10.1007/978-1-4684-2142-2_8

  • Publisher Name: Springer, Boston, MA

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