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New Methods of Parameter Identification in Kinetics of Closed and Open Reaction Systems

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Numerical Treatment of Inverse Problems in Differential and Integral Equations

Part of the book series: Progress in Scientific Computing ((PSC,volume 2))

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Abstract

By means of multiwavelength spectrometry the inverse problem of chemical kinetics may be solved by analysing not the concentration matrix, but the absorbance matrix, directly. The number of linearly independent reaction steps can be determined by graphical matrix rank analysis. Closed and open reaction systems may be kinetically analysed with high precision and significance by simultaneous evaluation of absorbance-time curves at different wavelengths.

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References

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Authors
  1. H. Lachmann
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Editors and Affiliations

  1. Institut für Angewandte Mathematik Abt. Numerische Mathematik, Universität Heidelberg, 6900, Heidelberg 1, Fed. Rep. of Germany

    Peter Deuflhard  & Ernst Hairer  & 

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© 1983 Birkhäuser Boston

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Lachmann, H. (1983). New Methods of Parameter Identification in Kinetics of Closed and Open Reaction Systems. In: Deuflhard, P., Hairer, E. (eds) Numerical Treatment of Inverse Problems in Differential and Integral Equations. Progress in Scientific Computing, vol 2. Birkhäuser Boston. https://doi.org/10.1007/978-1-4684-7324-7_4

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  • DOI: https://doi.org/10.1007/978-1-4684-7324-7_4

  • Publisher Name: Birkhäuser Boston

  • Print ISBN: 978-0-8176-3125-3

  • Online ISBN: 978-1-4684-7324-7

  • eBook Packages: Springer Book Archive

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