Abstract
Mössbauer spectroscopy, used in conjunction with the other spectroscopic methods which are normally employed in structure elucidation, such as infrared, nuclear magnetic resonance (NMR), and x-ray diffraction techniques, provides a powerful tool for the study of organometallic compounds incorporating the nuclides which are suitable for such studies. Fortunately, the two elements which are most readily accessible for Mössbauer work by chemists—iron and tin—have a very extensive and varied organometallic chemistry and are representative in many ways of transition metals and nontransition metals, respectively. In the present chapter, some of the broad outlines of Mössbauer studies on organometallic compounds of iron and tin will be summarized, and some examples from the recent literature will be reviewed. However, this discussion is intended to be neither encyclopedic nor exhaustive, and the interested reader is referred to some of the reviews on this topic which have appeared in the literature [1,2].
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References
E. Fluck, in Chemical Applications of Mössbauer Spectroscopy, V. I. Gol’danskii and R. H. Herber, Eds. (Academic Press, New York, 1968), Chap. 4.
V. I. Gol’danskii, V. V. Khrapov, O. Yu. Okhlobystin, and V. Ya. Rochev, in Chemical Applications of Mössbauer Spectroscopy, (Academic Press, New York, 1968), Chap. 6.
See also J. J. Zuckerman, Adv. Organomet, Chem. Vol 9, (Academic Press, New York, 1970).
R. H. Herber, R. B. King, and G. K. Wertheim, Inorg. Chem, 3, 101 (1964).
R. H. Herber and R. G. Hayter, J. Am. Chem. Soc. 86, 301 (1964).
R. R. Berrett and B. W. Fitzsimmons, Chem. Commun. 1966, 91.
V. I. Gordanskii et al, Dokl. Akad. Nauk. SSSR 147, 127 (1962).
R. H. Herber, H. A. Stöckler, and W. T. Reichle, Chem. Phys. 42, 2447 (1965).
H. A. Stöckler, H. Sano, and R. H. Herber, J. Chem. Phys. 45, 1182 (1966); 46, 2020 (1967).
R. H. Herber and G. I. Parisi, Inorg. Chem. 5, 769 (1966); R. H. Herber and Y. Goscinny (unpublished observations).
C. B. Harris, Inorg. Chem. 7, 1517 (1968).
R. L. Collins, J. Chem, Phys. 42, 1072 (1965).
S. L. Ruby and P. A. Flinn, Rev. Mod. Phys. 36, 351 (1964).
G. K. Wertheim and R. H. Herber, Chem. Phys. 38, 2106 (1963);
U. Zahn, P. Kienle, and H. Eicher, Proceedings of the Second International Conference on the Mössbauer Effect, D. M. J. Compton and A. H. Schoen, Eds. (John Wiley and Sons, New York, 1962), p. 271; Z. Physik. 166, 220 (1962).
M. F. Hawthorne, D. C. Young, and P. A. Wegner, J. Am. Chem. Soc. 87, 1818 (1965);
M. F. Hawthorne and T. D. Andrews, ibid., 87, 2496 (1965);
M. F. Hawthorne and R. L. Pilling, ibid., 87, 3987 (1965).
A. Zalkin, D. H. Templeton, and T. E. Hopkins, J. Am. Chem. Soc. 87, 3988 (1965).
R. H. Herber, Inorg. Chem. 8, 174 (1969).
R. H. Herber, Intern. At. Energy Agency, Tech. Rept. Ser. 50, 121 (1966).
T. C. Gibb and N. N. Greenwood, Intern. At. Energy Agency, Tech. Rept. Ser. 50, 163 (1966).
N. N. Greenwood, P. G. Perkins, and D. H. Wall, Symp. Faraday Soc. No. 1, 51 (1967).
H. A. Bent, J. Inorg. Nucl. Chem. 19, 43 (1961); Chem. Rev. 61, 275 (1961).
M. Cordey-Hayes, J. Inorg. Nucl. Chem. 26, 2307 (1964).
A. Yu. Aleksandrov et al, Dokl. Akad. Nauk SSSR 165, 593 (1965).
See discussion by V. I. Gol’danskii et al. [2], p. 343.
V. V. Khrapov, Ph.D. Thesis, Inst. Chem. Phys. Akad. Sci., USSR, Moscow, 1965.
B. Gassenheimer and R. H. Herber, Inorg. Chem. 8, 1120 (1969).
T. C. Gibb and N. N. Greenwood, J. Chem. Soc. 1966, 43.
N. N. Greenwood and J. N. R. Ruddick, Chem. Soc. A 1967, 1979.
T. A. Manuel and F. G. A. Stone, Proc. Chem. Soc. 1959, 90; J. Am. Chem. Soc. 82, 336 (1960).
M. D. Rausch and G. N. Schrautzer, Chem. Ind. (London) 957 (1959).
A. Nakamura and N. Hagihara, Bull. Chem. Soc. Japan 32, 880 (1959).
F. A. Cotton, J. Chem. Soc. 1960, 400.
B. Dickens and W. N. Lipscomb, J. Am. Chem. Soc. 83, 489 (1961).
C. G. Kreiter et al., J. Am. Chem. Soc. 88, 3444 (1966).
F. A. Cotton, A. Davidson, and J. W. Faller, J. Am. Chem. Soc. 88, 4507 (1966).
C. E. Keller, B. A. Shoulders, and R. Pettit, J. Am. Chem. Soc. 88, 4760 (1966).
R. Grubbs, R. Breslow, R. H. Herber, and S. J. Lippard, J. Am. Chem. Soc. 89, 6864 (1967).
F. Bonati and G. Wilkinson, J. Chem. Soc. 1964, 79.
R. H. Herber, Symp. Faraday Soc. No. 1, 86 (1967).
J. E. O’Connor and E. R. Corey, Inorg. Chem. 6, 969 (1967).
R. H. Herber and Y. Goscinny, Inorg. Chem. 7, 1293 (1968).
M. A. Bush and P. Woodward, J. Chem. Soc. A 1967, 1833.
W. Jetz and W. A. Graham, J. Am. Chem. Soc. 89, 2773 (1967).
W. Jetz, P. Simons, J. Thompson, and W. A. G. Graham, Inorg. Chem. 5, 2217 (1966).
H. R. H. Patil and W. A. G. Graham, Inorg. Chem. 5, 1401 (1966).
R. H. Herber and H. -S. Cheng, Inorg. Chem. 8, 2145 (1969).
H. -S. Cheng and R. H. Herber, Inorg. Chem. 9, 1686 (1970).
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Herber, R.H. (1971). Application to Organometallic Compounds. In: May, L. (eds) An Introduction to Mössbauer Spectroscopy. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-8911-8_7
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