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Scaling Description of Polymerization Kinetics

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Scaling Phenomena in Disordered Systems

Abstract

Applications of scaling ideas to the analysis of geometric features of polymeric molecules has been numerous and very succesful.1 Recently, it has been realized that these ideas can be extended further and applied to yet another domain of polymer chemistry,2 the kinetics of branched polymer formation. This opened a new and exciting field in which geometric, fractal, nature of polymers imposes itself on the dynamics and in which reaction time (age of the system) appears as a scaling variable3.

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References

  1. P.G. de Gennes, „Scaling Concepts in Polymer Physics“, Cornell University Press, Ithaca (1979)

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  2. P.J. Flory, “Principles of Polymer Chemistry”, Cornell University Press, Ithaca (1953)

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  3. R. Botet and R. Jullien, J. Phys. A17, 2517 (1984)

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  4. Z.B. Djordjevid, “Branched Polymers and Sol-Gel Transition”, Ph.D. Thesis, M.I.T., Cambridge (1984)

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  5. T.A. Witten and L.M. Sander, Phys. Rev. Lett. 47, 1400 (1984)

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  6. P. Meakin, Phys. Rev. Lett. 51, 1119 (1983)

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  7. K.G. Wilson, Rev. Mod. Phys. 47, 773 (1975)

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© 1991 Springer Science+Business Media New York

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Djordjević, Z.B., Djordjević, Z.V. (1991). Scaling Description of Polymerization Kinetics. In: Pynn, R., Skjeltorp, A. (eds) Scaling Phenomena in Disordered Systems. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-1402-9_44

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  • DOI: https://doi.org/10.1007/978-1-4757-1402-9_44

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4757-1404-3

  • Online ISBN: 978-1-4757-1402-9

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