Abstract
Transition metal complexes with an open-shell configuration (dn, n < 10) have received considerable attention for their interesting photophysical properties. The binuclear metal-metal bonded complexes of RhI, IrI, and PtII display rich photochemistry.1 One example of particular interest is the PtII complex, [Pt2(H2P2O5)4]4−, which has an excited state that is better oxidant and reductant than its ground state,2 and undergoes facile atom-transfer reactions with a variety of organic substrates.3 However, perhaps the most extensively studied transition metal complexes in this area are based on [Ru(bpy)3]2+, bpy = bipyridine. The complexes have been used in the study of both electron and energy transfer reactions and contributed a great deal to the understanding of photochemistry in inorganic systems.4
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
a) D. M. Roundhill, Photochemistry and Photophysics of Metal Complexes, Plenum Press, New York (1994);
S. E Rice, S. J. Midler, H. B. Gray, R. A. Goldbeck and D. S. Klieger Coord. Chem. Rev 43, 349 (1982);
D. C. Smith and H. B. Gray, Coord. Chem. Rev. 100, 169 (1990).
J. K. Nagle and D. M. Roundhill, Chemtract, Inorganic Chemistry 4, 141 (1992);
D. M. Roundhill, H. B. Gray, and C. M. Che, Acc. Chem. Res. 22, 55 (1989).
R. J. Sweeney, E. L. Harvey, and H. B. Gray, Coord. Chem. Rev. 105, 23 (1990);
A. P. Zipp, Coord. Chem. Rev. 84, 47 (1988).
E. Krausz and J. Ferguson, Prog. Inorg. Chem. 37, 293 (1989);
A. Juris, V. Balzani, E. Barigelletti, S. Campagna, P. Belser, and A. Von Zelewsky, A. Coord. Chem. Rev. 84, 85 (1988);
V. Balzani, F. Bolletta, M. T. Gandolfi, and M. Maestri, Top. Curr. Chem. 75, 1 (1978).
R. E. Ziolo, S. Lipton and Z. Dori, J. Chem. Soc., Chem. Commun. 1124 (1970).
a) D. T. Walz, in Advances in Inflammation Research, I. Ottemess, R. Capetola, and S. Wond, eds., Vol. 7, p 239, Raven Press, New York (1984);
B. M. Sutton, E. McCusty, D. T. Walz, M. J. DiMartino, J. Med. Chem. 15, 1095 (1972);
D. T. Hill and B. M. Sutton, Cryst. Struct. Commun. 9, 679 (1980);
P. W. Roy, R. C. Elder, and K. Tepperman, Metal Based Drugs 1 521 (1994). Other articles in this issue of Metal Based Drugs also relate to this topic.
E. J. Corey, M. M. Mehrotra, and A. U. Khan, Science 236, 68 (1987).
C. E. Briant, K. P. Hall, and D. M. P. Mingos, J Organomet. Chem. 229 C5 (1992);
H. Schmidbaur, J. R. Mandl, J. M. Bassett, G. Blaschke, and B. Zimmer-Gasser, Chem. Ber. 114, 433 (1981).
H. Schmidbaur, U. S. Wohlleben, A. Frank, and G. Huttner, Chem. Ber. 110, 2751 (1997).
R. Uson, A. Laguna, M. Laguna, M. N. Fraile, P. G. Jones, and G. M. Sheldrick, J Chem. Soc., Dalton Trans. 291 (1986).
J. Kozelka, H. R. Oswald and E. Dubler, Acta. Crystallogr. C42, 1007 (1986).
W. Ludwig and W. Meyer, Helv. Chim. Acta 65, 934 (1982).
a) E J. Farrell and T. G. Spiro, Inorg. Chem. 10, 1606 (1971).
J. B. Miller and J. L. Burmeister, Synth, React. Inorg. Met.-Org. Chem. 15, 223 (1985).
S. L. Lawton, W. J. Rohrbaugh, and G. T. Kokotailo, Inorg. Chem. 11, 2227 (1972).
J. Weinstock, B. M. Sutton, G. Y. Kuo, D. T. Walz, and M. J. DiMartino, J. Med. Chem. 17, 139 (1974).
H. Schmidbaur, J. R. Mandl, W. Richter, V. Bejenke, A. Frank, and G. Huttner, Chem. Ber. 110, 2236 (1977).
J. Vicente, M. T. Chicote, I. Sauva-Llamas, P. G. Jones, K. Meyer-Base, and C. E. Erdbrüger, Organometallics 7, 997 (1988).
H. Schmidbaur, W. Grag, and G. Müller, Angew. Chem., Int. Ed. Engl. 27, 417 (1988).
C. M. Che, W. T. Wong, T. E Lai, and H. L. Kwong, J. Chem. Soc., Chem. Commun. 243 (1989).
C. King, J. C. Wang, M. N. I. Khan, and J. P. Fackler Jr., Inorg. Chem. 28, 2145 (1989).
W. P. Schaefer, R. E. Marsch, T. M. McCleskey, and H. B. Gray, Acta. Crystallogr. C47, 2553 (1991).
C. M. Che, H. L. Kwong, V. W. W. Yam, and K. C. Cho, J. Chem. Soc., Chem. Commun. 885 (1989).
C. M. Che, H. L. Kwong, C. K. Poon, and V. W. W. Yam, J. Chem. Soc., Dalton Trans. 3215 (1990).
D. Li, C. M. Che, H. L. Kwong, and V. W. W. Yam, J. Chem. Soc., Dalton Trans. 3325 (1992).
H. R. C. Jaw, M. M. Savas, R. D. Rodgers, and W. R. Mason, Inorg. Chem. 28, 1028 (1989).
H. Schmidbaur, A. Wohlleben, U. Schubert, A. Frank, and G. Huttner, Chem. Ber. 110, 2751 (1977).
D. Li, X. Hong, C. M. Chem, W. C. Lo, and S. M. Peng, J. Chem. Soc., Dalton Trans. 2929 (1993).
C. M. Che, H. K. Yip, W. C. Lo, and S. M. Peng, Polyhedron 13, 887 (1994).
W. B. Jones, J. Yuan, R. Naraanaswamy, M. A. Young, R. C. Elder, A. E. Bruce, and M. R. M. Bruce, Inorg. Chem. 34, 1996 (1995).
R. Narayanaswamy, M. A. Young, E. Parkhurst, M. Ouellette, M. E. Kern, D. M. Ho, R. C. Elder, A. E. Bruce, and M. R. M. Bruce, Inorg. Chem. 32, 2506 (1993).
Z. Assefa, B. G. McBurnett, R. J. Staples, and J. P. Fackler, Jr., Inorg. Chem. 34, 4965 (1995).
X. Hong, K. K. Cheung, C. X. Guo, and C. M. Che, J. Chem. Soc., Dalton Trans. 186 (1994).
V. W. W. Yam and S. W. K. Choi, J. Chem. Soc., Dalton Trans. 2057 (1994).
C. M. Che, H. K. Yip, V. W. W. Yam, P. Y. Cheung, T. F. Lai, S. J. Shieh, and S. M. Peng, J. Chem. Soc., Dalton Trans. 427 (1992).
V. W. W. Yam, T. E Lai, and C. M. Che, J. Chem. Soc., Dalton Trans. 3747 (1990).
D. H. Brown, G. McKinlay, and W. E. Smith, J. Chem. Soc., Dalton Trans. 1874 (1977).
A. L. Balch, L. A. Fossett, J. K. Nagle, and M. M. Olmstead, J. Am. Chem. Soc. 110, 6732 (1988).
J. P. Fackler, Jr, R. J. Staples, and Z. Assefa, J. Chem. Soc., Chem. Commun. 431 (1994).
B.-C. Tzeng, C.-M. Che, and S.-M. Peng, J. Chem. Soc., Dalton Trans. 1769 (1996).
A. L. Balch, V. J. Catalano, and M. M. Olmstead, Inorg. Chem. 29, 585 (1990).
M. Inga, S. Kenney, J. W. Kenney, III, and G. A. Crosby, Organometallics 5, 230 (1986);
D. R. Striplin and G. A. Crosby, J. Phys. Chem. 99, 7977 (1995);
D. R. Striplin, J. A. Brozik, and G. A. Crosby, Chem. Phys. Lett. 231, 159 (1994);
D. R. Striplin and G. A. Crosby, J. Phys. Chem. 99, 11041 (1995).
A. L. Balch and V. J. Catalano, Inorg. Chem. 30, 1302 (1991).
H. K. Yip and C. M. Che, J. Chem. Soc., Chem. Commun. 885 (1989).
H. K. Yip, H. M. Lin, K. K. Cheung, C. M. Che, and Y. Wang, Inorg. Chem. 33, 1644 (1994).
H. K. Yip, H. M. Li, Y. Wang, and C. M. Che, Inorg. Chem. 32, 3402 (1993).
C. K. Chan, C. X. Guo, K. K. Cheung, D. Li, and C. M. Che, J. Chem. Soc. Dalton Trans. 2097 (1993).
A. J. Lees, Chem. Rev. 87, 71 (1987);
G. J. Ferraudi, Elements of Inorganic Photochemistry, Wiley, New York (1988).
A. L. Balch, D. E. Oram, J. K. Nagle, and P. E. Reedy, J. Am. Chem. Soc. 110, 454 (1988).
A. L. Balch, V. J. Catalano, and M. M. Olmstead, J. Am. Chem. Soc. 112, 2010 (1990).
A. L. Balch, V. J. Catalano, B. C. Noll, and M. M. Olmstead, J. Am. Chem. Soc. 112, 7558 (1990).
a) V. W. W. Yam, S. W. K, Choi, K. K. W. Lo, W. F. Dung, and R. Y. C. Kong, J. Chem. Soc., Chem. Commun. 2379 (1994);
H. K. Yip, C. M. Che, S. M. Peng, J. Chem. Soc., Chem. Commun., 1626 (1991).
S. Wang, G. Garzön, C. King, J. C. Wang and J. P. Fackler, Jr., Inorg. Chem. 28, 4623 (1989).
a) V. W. W. Yam, S. W. K, Choi, K. K. W. Lo, W. F. Dung, and R. Y. C. Kong, J. Chem. Soc., Chem. Commun. 2379 (1994);
H. K. Yip, C. M. Che, S. M. Peng, J. Chem. Soc., Chem. Commun., 1626 (1991).
Z. Assefa, G. Shankle, H. H. Patterson and R. Reynolds, Inorg. Chem. 33, 2187 (1994);
Z. Assefa, R. J. Staples, J. P. Fackler, Jr., H. H. Patterson and G. Shankle, Acta. Crystallogr. C51, 2527 (1995).
Z. Assefa, H. H. Patterson, Inorg. Chem. 33, 6194 (1994).
G. Glieman, Struct. and Bonding 62 87 (1985) and references cited therein.
A. Rosenzweig and D. T. Cromer, Acta Crystallogr. 12, 709 (1959).
H. Prosser, G. Wortmann, K. Syassen, and W. B. Holzapfel, Z. Physik. B24, 7 (1976);
D. Guenzburger and D. E. Ellis, Phys. Rev. B22, 4203 (1980).
H. H. Patterson, G. Roper, J. Biscoe A. Ludi, and N. Blom, J. Luminescence 555 (1984).
N. Blom, A. Ludi, H. B. Bürgi, and K. Tichÿ, Acta Crystallogr. C40, 1767 (1984).
J. T. Marken, N. Blom, G. Roper, A. D. Perregaux, N. Nagasundaram, M. R. Corson, A. Ludi, J. K. Nagle, and H. H. Patterson, Chem. Phys. Lett. 258, (1985).
J. H. Lacasce, Jr., W. A. Turner, M. R. Corson, P. J. Dolan, Jr., and J. K. Nagle, Chem. Phys. Lett. 289 (1987).
N. Nagasundaram, G. Roper, J. Biscoe, J. W. Chai, H. H. Patterson, N. Blom, and A. Ludi, Inorg. Chem. 25, 2947 (1986).
L. H. Jones, J. Chem. Phys. 27, 468 (1957).
J. K. Nagle, J. H. Lacasce, Jr., P. J. Dolan, M. R. Corson, Z. Assefa, and H. H. Patterson, Mol. Cryst. Liq. Cryst. 181, 359 (1990).
H. Stammereich, B. M. Chadwick and S. G. Frankiss, J. Mol. Struct. 1, 196 (1967).
Z. Assefa, F. DeStafan, M. A. Garepapaghi, J. H. Lacasce, Jr., S. Ouellete, M. R. Corson, J. K. Nagle, and H. H. Patterson, Inorg. Chem. 30, 2868 (1991).
P. Pyykkö, J. Li, and N. Runeberg, Chem. Phys. Lett. 218, 133 (1994).
M. Nakamoto, W. Hiller, and H. Schmidbaur, Chem. Ber. 126, 605 (1993).
H.-N. von Adams, J. Strähle, and W. Hiller, Z Anorg. Allg. Chem. 485, 81 (1982).
E. Eitel, D. Oelknzg, W. Hiller, and J. Strähle, Z. Naturforsch B35, 1247 (1980).
Z. Assefa, B. G. McBurnett, R. J. Staples, J. P. Fackler, Jr., B. Assmann, K. Angermaier, and H. Schmibaur, Inorg. Chem. 34, 75 (1995).
M. Y. Darensbourg and D. Daigle, Inorg. Chem. 14, 1217 (1975).
D. V. Toronto, B. Weissbart, D. S. Tinti, and A. L. Balch, Inorg. Chem. 35, 2484 (1996);
B. Weissbart, D. V. Toronto, A. L. Balch, and D. S. Tinti, Inorg. Chem. 35, 2490 (1996).
M. J. Forward, D. Bohmann, J. P. Fackler, Jr., and R. J. Staples, Inorg. Chem. 34, 6330 (1995).
S. D. Hanna and J. I. Zink, Inorg. Chem. 35, 297 (1996).
Z. Assefa, R. J. Staples, and J. P. Fackler, Jr., Inorg. Chem. 33, 2390 (1994).
C. King, M. N. I. Khan, R. J. Staples, and J. P. Fackler, Jr., Inorg. Chem. 31, 3236 (1992).
N. C. Baenziger, K. Dittermore, and J. R. Doyle, Inorg. Chem. 13, 805 (1974).
V. W.-W. Yam and W.-K. Lee, J Chem. Soc., Dalton Trans. 2907 (1993).
P. D. Harvey and H. B. Gray, J. Am. Chem. Soc. 110, 2145 (1988).
T. M. McCleskey and H. B. Gray, Inorg. Chem. 31, 1733 (1992).
M. N. I. Khan, R. J. Staples, C. King, J. P. Fackler, Jr., and R. E.. Winpenny, Inorg. Chem. 32, 5800 (1993).
M. N. I. Khan, C. King, J. P. Fackler, Jr., and R. E. P. Winpenny, Inorg. Chem. 32, 2502 (1993).
J. M. Forward, A. Assefa, and J. P. Fackler, Jr., ] Am. Chem. Soc. 117, 9103 (1995).
R. H. Uang, C. K. Chan, S. M. Peng, and C. M. Che, J. Chem. Soc., Chem. Commun. 2561 (1994).
J. C. Vickery, M. M. Olmstead, E. Y. Fung, and A. L. Balch, Angew. Chem. Int. Ed. Engl. 36, 1178–1181 (1997).
M. A. Mansour, W. B. Connick, R. J. Lachiocotte, H. J. Gysling, and R. Eisenberg, J Am. Chem. Soc. 120, 1329–1330 (1998).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1999 Springer Science+Business Media New York
About this chapter
Cite this chapter
Forward, J.M., Fackler, J.P., Assefa, Z. (1999). Photophysical and Photochemical Properties of Gold(l) Complexes. In: Roundhill, D.M., Fackler, J.P. (eds) Optoelectronic Properties of Inorganic Compounds. Modern Inorganic Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-6101-6_6
Download citation
DOI: https://doi.org/10.1007/978-1-4757-6101-6_6
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4419-3273-0
Online ISBN: 978-1-4757-6101-6
eBook Packages: Springer Book Archive