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Optical and Magnetic Functionalities on Molecule-Based Magnetic Materials

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Progress in Photon Science

Part of the book series: Springer Series in Chemical Physics ((CHEMICAL,volume 119))

Abstract

In this chapter, the optical and magnetic properties of multifunctional cyanido-bridged metal assemblies are introduced. Cyanido-bridged metal assemblies draw much attention due to their magnetic properties and functionalities. As for magnetic properties, they have an advantage to show long-range magnetic ordering due to strong magnetic couplings between magnetic metal ions via cyanide. In addition, the cyanido-bridged metal assemblies can acquire structural diversity and various electronic states by combination of metal ions and ligand, resulted in their functionalities. For examples, introduction of transition metal ions showing charge transfer and spin crossover could allow switching of spin states by external stimuli, and metal assemblies containing lanthanide ions are expected to show luminescence and slow magnetic relaxation. Herein, some cyanido-bridged metal assemblies with unique characters of photoinduced magnetization, luminescence, and slow magnetic relaxation are presented.

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Author information

Authors and Affiliations

  1. Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-0033, Japan

    Koji Nakabayashi & Shin-ichi Ohkoshi

  2. Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060, Kraków, Poland

    Szymon Chorazy

Authors
  1. Koji Nakabayashi
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  2. Shin-ichi Ohkoshi
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  3. Szymon Chorazy
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Corresponding author

Correspondence to Shin-ichi Ohkoshi .

Editor information

Editors and Affiliations

  1. Department of Chemistry, The University of Tokyo, Tokyo, Japan

    Kaoru Yamanouchi

  2. Institute of Chemistry, Saint Petersburg State University, Saint Petersburg, Russia

    Sergey Tunik

  3. Physics Faculty, Lomonosov Moscow State University, Moscow, Russia

    Vladimir Makarov

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Nakabayashi, K., Ohkoshi, Si., Chorazy, S. (2019). Optical and Magnetic Functionalities on Molecule-Based Magnetic Materials. In: Yamanouchi, K., Tunik, S., Makarov, V. (eds) Progress in Photon Science. Springer Series in Chemical Physics, vol 119. Springer, Cham. https://doi.org/10.1007/978-3-030-05974-3_23

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