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Vibrational Spectroscopy Applied to Solution and Metal/Solution Interface Chemistry Studies

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Modern Problems of the Physics of Liquid Systems (PLMMP 2018)

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Abstract

Infrared (IR) and Raman experiments as well as SERS (Surface Enhanced Raman Scattering) and surface investigations were carried out in order to obtain detailed vibrational information on solution and metal/solution interface chemistry. For the former system, especial attention has been given to metal-catalyzed peptide bond cleavage reactions, in which the research of new and more efficient metal complexes is needed. A methodology based on the shifts of the νCO and νCN modes of a simple amide (formamide/FA) has shown to be useful for the prediction of the catalytic activity of metals and a data collection is presented. For the latter, the adsorption dynamics of different species on a copper electrode, in the presence of chloride anions, and the inhibition efficiency of a specific azole (imidazole/Imid) are analyzed and discussed. A proposal for the adsorption mechanism of Imid is suggested on the basis of potential-dependent spectra.

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Acknowledgements

This project was sponsored by Conselho Nacional de Desenvolvimento Científico e Tecnológico-CNPq and partly by the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior—Brazil (CAPES)—Finance Code 001. The author thanks all collaborators for fruitful discussions and Laboratório de Ensaios Não-Destrutivos, Corrosão e Soldagem (LNDC) for the Raman facilities.

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Authors and Affiliations

  1. Departamento de Química Inorgânica, Instituto de Química, Universidade Federal do Rio de Janeiro, Caixa Postal 68563, Rio de Janeiro, RJ, 21941-909, Brazil

    Wagner A. Alves

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  1. Wagner A. Alves
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Correspondence to Wagner A. Alves .

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Editors and Affiliations

  1. National Academy of Sciences of Ukraine, Kyiv, Ukraine

    Leonid A. Bulavin

  2. International Center for Quantum Materials and School of Physics, Peking University, Beijing, China

    Limei Xu

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Alves, W.A. (2019). Vibrational Spectroscopy Applied to Solution and Metal/Solution Interface Chemistry Studies. In: Bulavin, L., Xu, L. (eds) Modern Problems of the Physics of Liquid Systems. PLMMP 2018. Springer Proceedings in Physics, vol 223. Springer, Cham. https://doi.org/10.1007/978-3-030-21755-6_5

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