Abstract
Carbon nanotube reinforced aluminum matrix composites are considered a promising solution for applications that require high specific mechanical properties. Even though there are numerous methods for their manufacturing, these are frequently based on powder metallurgy approaches, limiting the fabrication of components with significant volumes and complex shapes. Casting, as a manufacturing technique, is regarded as the most appropriate route to obtain complex-shaped components with a relative high microstructural quality. These techniques to obtain Al-CNT cast components is still challenging due to the agglomeration, lack of dispersion, reduced bonding and density of the CNTs in Al. To address these issues, CNTs are usually pre-processed by ball-milling with Al powder to promote bonding and disperse the reinforcement, however, these techniques are not really beneficial to casting approaches due to the increase of Al2O3 content that do not disperse within the Al alloy melts. This study proposes the use of Al spheres (~1 mm) in these ball milling techniques to prevent significant plastic deformation, the formation of Al flakes and the increase in Al2O3 content. It is shown that CNTs may be dispersed and bonded to the Al sphere surfaces. Results suggest that this is a promising novel technique to allow a successful implementation of casting-based routes to fabricate high-volume and complex-shaped Al-CNT components.
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References
Iijima, S.: Helical microtubules of graphitic carbon. Nature 354, 56–58 (1991)
Tjong, S.C.: Recent progress in the development and properties of novel metal matrix nanocomposites reinforced with carbon nanotubes and graphene nanosheets. Mater. Sci. Eng. R Rep. 74, 281–350 (2013)
Coleman, J.N., Khan, U., Blau, W.J., Gunko, Y.K.: Small but strong: A review of the mechanical properties of carbon nanotube–polymer composites. Carbon 44, 1624–1652 (2006)
Bakshi, S.R., Lahiri, D., Agarwal, A.: Carbon nanotube reinforced metal matrix composites - a review. Int. Mater. Rev. 55, 41–64 (2010)
Jargalsaikhan, B., Bor, A., Lee, J., Choi, H.: Al/CNT nanocomposite fabrication on the different property of raw material using a planetary ball mill. Adv. Powder Technol. 31, 1957–1962 (2020)
Hou, Y., Tang, J., Zhang, H., Qian, C., Feng, Y., Liu, J.: Functionalized few-walled carbon nanotubes for mechanical reinforcement of polymeric composites. ACS Nano 3, 1057–1062 (2009)
Thostenson, E.T., Ren, Z., Chou, T.-W.: Advances in the science and technology of carbon nanotubes and their composites: a review. Compos. Sci. Technol. 61, 1899–1912 (2001)
Peigney, A., Laurent, C., Flahaut, E., Rousset, A.: Carbon nanotubes in novel ceramic matrix nanocomposites. Ceram. Int. 26, 677–683 (2000)
Liao, J., Tan, M.-J.: Mixing of carbon nanotubes (CNTs) and aluminum powder for powder metallurgy use. Powder Technol. 208, 42–48 (2011)
Liu, F., et al.: Preparation of short carbon nanotubes by mechanical ball milling and their hydrogen adsorption behavior. Carbon 41, 2527–2532 (2003)
Bradbury, C.R., Gomon, J.-K., Kollo, L., Kwon, H., Leparoux, M.: Hardness of Multi Wall Carbon Nanotubes reinforced aluminium matrix composites. J. Alloy. Compd. 585, 362–367 (2014)
George, R., Kashyap, K.T., Rahul, R., Yamdagni, S.: Strengthening in carbon nanotube/aluminium (CNT/Al) composites. Scripta Mater. 53, 1159–1163 (2005)
Choi, H., Shin, J., Min, B., Park, J., Bae, D.: Reinforcing effects of carbon nanotubes in structural aluminum matrix nanocomposites. J. Mater. Res. 24(8), 2610–2616 (2009). https://doi.org/10.1557/jmr.2009.0318
Sridhar, I., Narayanan, K.R.: Processing and characterization of MWCNT reinforced aluminum matrix composites. J. Mater. Sci. 44(7), 1750–1756 (2009). https://doi.org/10.1007/s10853-009-3290-5
Esawi, A.M.K., Morsi, K., Sayed, A., Taher, M., Lanka, S.: Effect of carbon nanotube (CNT) content on the mechanical properties of CNT-reinforced aluminium composites. Compos. Sci. Technol. 70, 2237–2241 (2010)
Popov, V.N.: Carbon nanotubes: properties and application. Mater. Sci. Eng. R Rep. 43, 61–102 (2004)
Casati, R., Vedani, M.: Metal matrix composites reinforced by nano-particles - a review. Metals 4, 65–83 (2014)
Kim, K.T., Eckert, J., Menzel, S.B., Gemming, T., Hong, S.H.: Grain refinement assisted strengthening of carbon nanotube reinforced copper matrix nanocomposites. Appl. Phys. Lett. 92, 121901 (2008)
Liu, Z.Y., Xiao, B.L., Wang, W.G., Ma, Z.Y.: Modelling of carbon nanotube dispersion and strengthening mechanisms in Al matrix composites prepared by high energy ball milling-powder metallurgy method. Compos. A Appl. Sci. Manuf. 94, 189–198 (2017)
Prabhakar, G.V.N.B., Pavan Kumar, Y.V.R.S.N., Dileep Kumar, P., Prasanna Kumar, B., Gopi Raju, M., Naseema, S., Ravi Kumar, N., Jagannatham, M., Ratna Sunil, B.: Producing Al5083-CNT composites by friction stir processing: influence of grain refinement and CNT on mechanical and corrosion properties. Mater. Today Proc. 15, 44–49 (2019)
Khanna, V., Kumar, V., Bansal, S.A.: Mechanical properties of aluminium-graphene/carbon nanotubes (CNTs) metal matrix composites: advancement, opportunities and perspective. Mater. Res. Bull. 138, 111224 (2021)
Bi, S., et al.: Enhancing strength-ductility synergy of carbon nanotube/7055Al composite via a texture design by hot-rolling. Mater. Sci. Eng. A 806, 140830 (2021)
Ramkumar, K.R., Dinaharan, I.: Accumulative roll bonding route for composite materials production. In: Reference Module in Materials Science and Materials Engineering. Elsevier (2020)
Alladi, A., Aluri, M., Maddela, N., Abbadi, C.R.: Recent progress of CNTs reinforcement with metal matrix composites using friction stir processing. Mater. Today Proc. (2021, in press)
Liu, Z.Y., Xiao, B.L., Wang, W.G., Ma, Z.Y.: Singly dispersed carbon nanotube/aluminum composites fabricated by powder metallurgy combined with friction stir processing. Carbon 50, 1843–1852 (2012)
Chen, M., et al.: Design of an efficient flake powder metallurgy route to fabricate CNT/6061Al composites. Mater. Des. 142, 288–296 (2018)
Trinh, P.V., et al.: Microstructure, microhardness and thermal expansion of CNT/Al composites prepared by flake powder metallurgy. Compos. A Appl. Sci. Manuf. 105, 126–137 (2018)
Zhang, Y., Wang, Q., Chen, G., Ramachandran, C.S.: Mechanical, tribological and corrosion physiognomies of CNT-Al metal matrix composite (MMC) coatings deposited by cold gas dynamic spray (CGDS) process. Surf. Coat. Technol. 403, 126380 (2020)
Guo, B., et al.: Microstructures and mechanical properties of carbon nanotubes reinforced pure aluminum composites synthesized by spark plasma sintering and hot rolling. Mater. Sci. Eng. A 698, 282–288 (2017)
Toozandehjani, M., Ostovan, F., Jamaludin, K.R., Amrin, A., Matori, K.A., Shafiei, E.: Process−microstructure−properties relationship in Al−CNTs−Al2O3 nanocomposites manufactured by hybrid powder metallurgy and microwave sintering process. Trans. Nonferrous Metals Soc. China 30, 2339–2354 (2020)
Ma, P.-C., Siddiqui, N.A., Marom, G., Kim, J.-K.: Dispersion and functionalization of carbon nanotubes for polymer-based nanocomposites: a review. Compos. A Appl. Sci. Manuf. 41, 1345–1367 (2010)
Bakshi, S.R., Agarwal, A.: An analysis of the factors affecting strengthening in carbon nanotube reinforced aluminum composites. Carbon 49, 533–544 (2011)
Rodríguez-Reyes, M., Pech-Canul, M.I., Rendón-Angeles, J.C., López-Cuevas, J.: Limiting the development of Al4C3 to prevent degradation of Al/SiCp composites processed by pressureless infiltration. Compos. Sci. Technol. 66, 1056–1062 (2006)
Fan, G., et al.: Enhanced interfacial bonding and mechanical properties in CNT/Al composites fabricated by flake powder metallurgy. Carbon 130, 333–339 (2018)
Lalet, G., Kurita, H., Miyazaki, T., Kawasaki, A., Silvain, J.-F.: Microstructure of a carbon fiber-reinforced aluminum matrix composite fabricated by spark plasma sintering in various pulse conditions. J. Mater. Sci. 49(8), 3268–3275 (2014). https://doi.org/10.1007/s10853-014-8032-7
Kurita, H., et al.: Load-bearing contribution of multi-walled carbon nanotubes on tensile response of aluminum. Compos. A Appl. Sci. Manuf. 68, 133–139 (2015)
Esawi, A.M.K., Morsi, K., Sayed, A., Taher, M., Lanka, S.: The influence of carbon nanotube (CNT) morphology and diameter on the processing and properties of CNT-reinforced aluminium composites. Compos. A Appl. Sci. Manuf. 42, 234–243 (2011)
Ostovan, F., et al.: Effects of CNTs content and milling time on mechanical behavior of MWCNT-reinforced aluminum nanocomposites. Mater. Chem. Phys. 166, 160–166 (2015)
Liu, Z.Y., Xu, S.J., Xiao, B.L., Xue, P., Wang, W.G., Ma, Z.Y.: Effect of ball-milling time on mechanical properties of carbon nanotubes reinforced aluminum matrix composites. Compos. A Appl. Sci. Manuf. 43, 2161–2168 (2012)
Hassan, M.T.Z., Esawi, A.M.K., Metwalli, S.: Effect of carbon nanotube damage on the mechanical properties of aluminium–carbon nanotube composites. J. Alloy. Compd. 607, 215–222 (2014)
Soni, S.K., Thomas, B., Kar, V.R.: A comprehensive review on CNTs and CNT-reinforced composites: syntheses. Charact. Appl. Mater. Today Commun. 25, 101546 (2020)
Li, G., Qu, Y., Yang, Y., Zhou, Q., Liu, X., Li, R.: Improved multi-orientation dispersion of short carbon fibers in aluminum matrix composites prepared with square crucible by mechanical stirring. J. Mater. Sci. Technol. 40, 81–87 (2020)
Yan, H., Huang, Z.-X., Qiu, H.-X.: Microstructure and mechanical properties of CNTs/A356 nanocomposites fabricated by high-intensity ultrasonic processing. Metall. Mater. Trans. A 48(2), 910–918 (2016). https://doi.org/10.1007/s11661-016-3872-1
Li, Q., Rottmair, C.A., Singer, R.F.: CNT reinforced light metal composites produced by melt stirring and by high pressure die casting. Compos. Sci. Technol. 70, 2242–2247 (2010)
Mansoor, M., Shahid, M.: Carbon nanotube-reinforced aluminum composite produced by induction melting. J. Appl. Res. Technol. 14, 215–224 (2016)
Yuan, C., et al.: Enhanced ductility by Mg addition in the CNT/Al-Cu composites via flake powder metallurgy. Mater. Today Commun. 26, 101854 (2020)
Saif, M.T.A., Zhang, S., Haque, A., Hsia, K.J.: Effect of native Al2O3 on the elastic response of nanoscale Al films. Acta Mater. 50, 2779–2786 (2002)
Acknowledgements
This work was supported by PTDC/EMEEME/30967/2017 and NORTE-0145-FEDER-030967, co-financed by the European Regional Development Fund (ERDF), through the Operational Programme for Competitiveness and Internationalization (COMPETE 2020), under Portugal 2020, and by the Fundação para a Ciência e a Tecnologia – FCT I.P. national funds. Also, this work was supported by Portuguese FCT, under the reference project UIDB/04436/2020, Stimulus of Scientific Employment Application CEECIND/03991/2017.
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Puga, H., Carneiro, V.H., Vieira, M. (2022). Ball Milled Al Spheres for the Manufacturing of Casting-Based Al-CNT Composites. In: Machado, J., Soares, F., Trojanowska, J., Ottaviano, E. (eds) Innovations in Mechanical Engineering. icieng 2021. Lecture Notes in Mechanical Engineering. Springer, Cham. https://doi.org/10.1007/978-3-030-79165-0_5
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