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Effects of Porous Carbon and CNTs on the Discharge Performance of Li-Air Batteries

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TMS 2015 144th Annual Meeting & Exhibition
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Abstract

In Li/air batteries, the discharge process and capacity are closely related to the composition of air electrode. Carbon is the main component of air electrode and therefore its intrinsic properties will affect the performance of batteries. It has been found that the discharge product was epiphytic on carbon surface during discharge, and the large mesopores (> 30 nm) or macropores in the carbon were the response site of discharge reaction where the discharge product was stored. These have also been confirmed by comparison with ideal electrode composed of carbon nanotubes (CNTs).

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References

  1. S. Zaromb. “The Use and Behavior of Aluminum Anodes in Alkaline Primary Batteries,” Journal of the Electrochemical Society, 109(12) (1962),1125–1129.

    Article  Google Scholar 

  2. David Linden, Thomas B. Reddy, Handbook of Batteries (3rd ed., McGraw-Hill, New York,1989),222.

    Google Scholar 

  3. Guo-Qing Zhang, Xiao-Gang Zhang, Yong-Gang Wang. “A new air electrode based on carbon nanotubes and Ag-MnO2 for metal air electrochemical cells,” Carbon, 42(15) (2004),3097–3102.

    Article  Google Scholar 

  4. Weiyang Li, Chunsheng Li, Chunyuan Zhou et al. “Metallic Magnesium Nano/Mesoscale Structures:Their Shape-Controlled Preparation and Mg/Air Battery Applications,” Angew. Chem., 45(36)(2006),6009–6012.

    Article  Google Scholar 

  5. G.Girish Kumar, N. Munichandraiah. “Reversibility of Mg/Mg2+ couple in a gel polymer electrolyte,” Electrochimica Acta, 44(15) (1999), 2663–2666.

    Article  Google Scholar 

  6. A. Patrick, M. Glasse, R. Latham et al. “Novel solid state polymeric batteries,” Solid State Ionics,18–19 (1)(1986),1063–1067.

    Article  Google Scholar 

  7. Sheng S. Zhang, Donald Foster, Jeffrey Read. “A high energy density lithium/sulfur-oxygen hybrid battery,” Journal of Power Sources, 195(11) (2010),3684–3688

    Article  Google Scholar 

  8. K.M. Abraham, Z. Jiang, “A Polymer Electrolyte-Based Rechargeable,” Journal of the Electrochemical Society,143(1) (1996),1–5

    Article  Google Scholar 

  9. Jiguang Zhang, Deyu Wang, Wu Xu et al. “Ambient operation of Li/Air batteries,” Journal of Power Sources, 195(13) (2010),4332–4337

    Article  Google Scholar 

  10. Chris Trana, Xiao-Qing Yangb, Deyang Qu. “Investigation of the gas-diffusion-electrode used as lithium/air cathode in non-aqueous electrolyte and the importance of carbon material porosity,” Journal of Power Sources, 195 (7)(2010),2057–2063

    Article  Google Scholar 

  11. Richard Padbury, Xiangwu Zhang. “Lithium-oxygen batteries—Limiting factors that affect performance,” Journal of Power Sources, 196(10) (2011),4436–4444

    Article  Google Scholar 

  12. Doretta Capsoni, Marcella Bini, Stefania Ferrari et al. “Recent advances in the development of Li-air batteries,” Journal of Power Sources, 220(12) (2012),253–263

    Article  Google Scholar 

  13. Alexander Kraytsberg, Yair Ein-Eli. “Review on Li-air batteries—Opportunities, limitations and perspective,” Journal of Power Sources, 196 (3)(2011),886–893

    Article  Google Scholar 

  14. S.J. Gregg, K.S.W. Sing, Adsorption, Surface Area and Porosity(Academic Press, New York4, 1967),123.

    Google Scholar 

  15. G. Q. Zhang, J. P. Zheng, R. Liang et al. “Lithium-Air Batteries Using SWNT/CNF Buckypapers as Air Electrodes,” Journal of The Electrochemical Society, 157(8)(2010),A953-A956

    Article  Google Scholar 

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© 2015 TMS (The Minerals, Metals & Materials Society)

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Yan, Y., Zhang, Y., Xiao, Z., Li, M. (2015). Effects of Porous Carbon and CNTs on the Discharge Performance of Li-Air Batteries. In: TMS 2015 144th Annual Meeting & Exhibition. Springer, Cham. https://doi.org/10.1007/978-3-319-48127-2_42

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