Abstract
The aim of the present work was to investigate the metallurgical parameters controlling porosity formation in Al–Si–Cu alloys, through a study of the microstructural characteristics of directionally solidified 319.2 alloys as a function of iron content, Sr addition (250 ppm), and solidification rate . The iron levels selected varied from 0.12 to 0.8 wt%, and cover the range of Fe levels found in commercial casting alloys. The use of an end-chilled mold provided different solidification rates along the height of the same casting, with DAS values that varied from ~15 to 85 μm, corresponding to levels of 5, 10, 30, 50 and 100 mm above the chill end. The amount of iron present in the alloy affects the size of the beta-iron Al5FeSi platelets and their distribution, particularly at low solidification rates. Addition of strontium leads to fragmentation of co-eutectic or post-eutectic beta-iron platelets.
References
L.A. Narayanan, F.H. Samuel, J.E., Gruzleski, “Crystallization behavior of iron-containing intermatllic compounds in 319 Aluminum alloy”. Metall. Mater. Trans. A. 25A, 1761–1773 (1994)
R.S. Rana, R. Purohit, S. Das, Review on the influence of alloying elements on the microstructure and mechanical properties of aluminum alloys and aluminum alloy composites. Int. J. Sci Res. Publ. 2, 1–7 (2012)
L. Lu, A.K. Dahle, Iron-rich intermetallic phases and their role in casting defect formation in hypoeutectic Al–Si alloys. Metall. Mater. Trans. A A36, 819–835 (2005)
S. Lee, B. Kim, S. Lee, Prediction of solidification paths in Al-Si-Fe ternary system and experimental verification: part II. Fe-containing eutectic Al-Si alloys. Mater. Trans. 52(6), 1308–1315 (2011)
G. Gustafsson, T. Thorvaldsson, G.L. Dunlop, The influence of Fe and Cr on the microstructure of cast Al-Fe-Si alloys. Metall. Trans. A 17A, 45–52 (1986)
P. Ashtari, H. Tezuka, T. Sato, “Influence of Sr and Mn additions on intermetallic morphologies in Al-Si-Cu-Fe cast alloys”. Mater. Trans. 12, 2611–2616 (2003)
Y. Awano, Y. Shimizu, Non-equilibrium crystallization of AlFeSi compound in melt-superheated Al-Si alloy castings. AFS Trans. 98, 889–895 (1990)
A.M. Samuel, H.W. Doty, F.H. Samuel, “Influence of melt treatment and solidification parameters on the quality of 319.2 Endchill Aluminum Castings,” in Proceedings of 4th International Conferences on Molten Aluminum Processing, Orlando, Florida, 12–14 Nov 1995, pp. 261–294
M. Sha, S. Wu, L. Wan, S. Lu, Effect of heat treatment on morphology of Fe-Rich intermetallics in hypereutrctic Al-Si-Cu-Ni alloy with 1.26 pct Fe. Metall. Mater. Trans. A 44A, 5642–5652 (2013)
N. Roy, A.M. Samuel, F.H. Samuel, Porosity formation in Al-9 Wt Pct Si-3 Wt Pct Cu alloy aystems: metallographic observations. Metall. Mater. Trans. A 27A, 415–429 (1996)
M.A. Moustafa, Effect of iron content on the formation of β-Al5FeSi and porosity in Al-Si eutectic alloys. J. Mater. Process. Technol. 209, 605–610 (2009)
A.M. Samuel, H.W. Doty, S. Valtierra, F.H. Samuel, Relationship between tensile and impact properties in Al–Si–Cu–Mg cast alloys and their fracture mechanisms. Mater. Des. 53, 938–946 (2014)
E. Tilová, M. Chalupová, L. Hurtalová, M. Bonek, L.A. Dobrzański, Structural analysis of heat treated automotive cast alloy. J. Achievements Mater. Manufact. Eng. 47(1), 19–25 (2011)
J.E. Gruzleski, B.M. Closset, The treatment of liquid aluminum-silicon alloys, American Foundrymen’s Society Inc, Des Plaines (U.S.A, IL, 1990)
C. Villeneuve, F.H. Samuel, Fragmentation and dissolution of β-Al5FeSi phase during solution heat treatment of Al-13%Si-Fe alloys. Int. J. Cast Met. Res. 12(3), 145–160 (1999)
S.G. Shabestari, J.E. Gruzleski, The kinetics of formation and growth of complex intermetallic compounds in aluminum-silicon alloys. Cast Metals 6(4), 241–251 (1994)
Z. Ma, “Effect of Fe-intermetallics and porosity on tensile and impact properties of Al-Si-Cu and Al-Si-Mg cast alloys”, Ph.D. Thesis, Université du Québec à Chicoutimi, Canada, 2003
C. Mascré, «Influence du fer et du manganèse sur les alliages du type de l’A-S13 (Alpax),» Fonderie, 108 (Jan. 1955), pp. 4330–4336
J.A. Taylor, G.B. Schaffer, D.H. StJohn, The role of iron in the formation of porosity in Al-Si-Cu-based casting alloys: part II. A phase-diagram approach. Metall. Mater. Trans. A 30A, 1651–1655 (1999)
J.A. Taylor, G.B. Schaffer, D.H. StJohn, The role of iron in the formation of porosity in Al-Si-Cu-based casting alloys: part III. A microstructural model. Metall. Mater. Trans. A 30A, 1657–1662 (1999)
J.A. Taylor, G.B., Schaffer, D.H. St John, “The role of iron in the formation of porosity in Al-Si-Cu-based casting alloys: part I. Initial experimental”. Metall. Mater. Trans. A. 30A, 1643–1650 (1999)
Z. Ma, A.M. Samuel, F.H. Samuel, H.W. Doty, S. Valtierra, A study of tensile properties in Al-Si-Cu and Al-Si-Mg alloys: effect of beta-iron intermetallics and porosity. Mater. Sci. Eng. A 490(1–2), 36–51 (2008)
P. Mikolajezak, L. Ratke, Three Dimensional Morphology of β-Al5FeSi Intermetallics in AlSi Alloys. Arch. Foundry Eng. 15(1), 47–50 (2015)
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Samuel, F.H., Samuel, A.M., Doty, H.W., Valtierra, S. (2017). On Porosity Formation in Al–Si–Cu Cast Alloys. In: Ratvik, A. (eds) Light Metals 2017. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-51541-0_33
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