Skip to main content

Phase Formation of Monotectic Al–In and Al–Ga–In Alloys and Implications Thereof

  • Conference paper
  • First Online:
Light Metals 2018 (TMS 2018)

Part of the book series: The Minerals, Metals & Materials Series ((MMMS))

Included in the following conference series:

  • 185 Accesses

Abstract

The separation of phases in monotectic Al-In and Al–Ga–In alloys is studied. Different cooling rates result in different morphologies and dispersions of the secondary In or Ga–In phases in an Al matrix. Both uniform dispersion of In particles in an Al matrix and layered In phase along the Al grain boundaries are produced. Ga–In liquid phases are situated primarily along the Al grain boundaries. It is the co-effects of coalescence and particle pushing in addition to a monotectic reaction in solidification. The Ga–In layer along the Al grain boundaries acts as a catalyst in splitting water and provides a passageway for oxygen to oxide the Al matrix. As a result, hydrogen can be separated from water for clean energy applications.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 309.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Murray J. The Al–Ga (Aluminum–Gallium) system. Journal of Phase Equilibria 1983;4:183–90.

    Article  Google Scholar 

  2. Predel B. Constitution and thermodynamics of monotectic alloys—A survey. Journal of phase equilibria 1997;18:327–37.

    Article  CAS  Google Scholar 

  3. Huang T, Gao Q, Liu D, Xu S, Guo C, Zou J, Wei C. Preparation of Al–Ga–In–Sn–Bi quinary alloy and its hydrogen production via water splitting. International Journal of Hydrogen Energy 2015;40:2354–62.

    Article  CAS  Google Scholar 

  4. Ziebarth JT, Woodall JM, Kramer RA, Choi G. Liquid phase-enabled reaction of Al–Ga and Al–Ga–In–Sn alloys with water. international journal of hydrogen energy 2011;36:5271–9.

    Article  CAS  Google Scholar 

  5. Anderson T, Ansara I. The Ga–In (gallium–indium) system. Journal of phase equilibria 1991;12:64–72.

    Article  CAS  Google Scholar 

  6. Ladd C, So JH, Muth J, Dickey MD. 3D printing of free standing liquid metal microstructures. Advanced Materials 2013;25:5081–5.

    Article  CAS  Google Scholar 

  7. Park J, Wang S, Li M, Ahn C, Hyun JK, Kim DS, Kim DK, Rogers JA, Huang Y, Jeon S. Three-dimensional nanonetworks for giant stretchability in dielectrics and conductors. Nature communications 2012;3:916.

    Google Scholar 

  8. Rus D, Tolley MT. Design, fabrication and control of soft robots. Nature 2015;521:467–75.

    Article  CAS  Google Scholar 

  9. Gelles S, Mark worth A. Microgravity studies in the liquid-phase immiscible system: Aluminum–indium. AIAA Journal 1978;16:431–8.

    Article  CAS  Google Scholar 

  10. Wang C, Liu X, Ohnuma I, Kainuma R, Ishida K. Formation of immiscible alloy powders with egg-type microstructure. Science 2002;297:990–3.

    Article  CAS  Google Scholar 

  11. Goswami R, Chattopadhyay K. The solidification behaviour of Bi particles embedded in an Al matrix. Acta materialia 1996;44:2421–9.

    Article  CAS  Google Scholar 

  12. Gröbner J, Mirković D, Schmid-Fetzer R. Monotectic four-phase reaction in Al–Bi–Zn alloys. Acta materialia 2005;53:3271–80.

    Article  Google Scholar 

  13. Grugel RN, Well AH. Alloy solidification in systems containing a liquid miscibility gap. Metallurgical Transactions A 1981;12:669–81.

    Article  CAS  Google Scholar 

  14. Kamio A, Kumai S, Tezuka H. Solidification structure of monotectic alloys. Materials Science and Engineering: A 1991;146:105–21.

    Article  Google Scholar 

  15. Murray J. The Al-In (Aluminum-Indium) system. Bulletin of Alloy Phase Diagrams 1983;4:271–8.

    Article  Google Scholar 

  16. Clarke A, Imhoff S, Gibbs P, Cooley J, Morris C, Merrill F, Hollander B, Mariam F, Ott T, Barker M. Proton radiography peers into metal solidification. Scientific reports 2013;3.

    Google Scholar 

  17. Gilpin R. Theoretical studies of particle engulfment. Journal of Colloid and Interface Science 1980;74:44–63.

    Article  CAS  Google Scholar 

  18. Pereiro-Lopez E, Ludwig W, Bellet D, Cloetens P, Lemaignan C. Direct evidence of nanometric invasionlike grain boundary penetration in the Al/Ga system. Physical review letters 2005;95:215501.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Xiaoming Wang .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2018 The Minerals, Metals & Materials Society

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Wang, X., Liu, X. (2018). Phase Formation of Monotectic Al–In and Al–Ga–In Alloys and Implications Thereof. In: Martin, O. (eds) Light Metals 2018. TMS 2018. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-72284-9_38

Download citation

Publish with us

Policies and ethics