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Phase Separation for Langmuir Monolayer in Binary System Based on a π-A Isotherm Measurement

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Trends in Colloid and Interface Science XXIV

Part of the book series: Progress in Colloid and Polymer Science ((PROGCOLLOID,volume 138))

Abstract

The mixing behavior of binary monolayer of fatty acid was investigated on the basis of π-A isotherm measurements. The (palmitic acid(C16)/arachidic acid(C20)) and (C20/lignoceric acid(C24)) mixed monolayers were in a miscible state, whereas the (C16/C24) mixed monolayer was an immiscible state. The (C16/behenic acid(C22)) and (stearic acid(C18)/C24) mixed monolayers were in an incomplete miscible state. The dependence of mixing behavior on the difference in the number of methylene group between components in monolayer is probably due to an enthalpic contribution based on the difference in cohesive energy between the monolayer components.

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Acknowledgments

The authors thank Dr. Masao Suzuki (NOF Co.) for providing the samples of fatty acids used in this study.

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Authors and Affiliations

  1. Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga University, 1 Honjo, Saga, 840-8502, Japan

    Yushi Oishi

Authors
  1. Miyuki Kuramori
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  2. Takamasa Ishikawa
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  3. Takayuki Narita
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  4. Yushi Oishi
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Corresponding author

Correspondence to Yushi Oishi .

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Editors and Affiliations

  1. , Chemical Engineering, Loughborough University, Leicestershire, LE11 3TU, Montserrat

    Victor Starov

  2. Faculty of Science, Department of Physical and Macromolecula, Charles University in Praha, Hlavova 8, Praha, 12843, Czech Republic

    Karel Procházka

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© 2011 Springer-Verlag Berlin Heidelberg

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Kuramori, M., Ishikawa, T., Narita, T., Oishi, Y. (2011). Phase Separation for Langmuir Monolayer in Binary System Based on a π-A Isotherm Measurement. In: Starov, V., Procházka, K. (eds) Trends in Colloid and Interface Science XXIV. Progress in Colloid and Polymer Science, vol 138. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-19038-4_18

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