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Self-Assembly and Nano-layering of Apatitic Calcium Phosphates in Biomaterials

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Advances in Calcium Phosphate Biomaterials

Part of the book series: Springer Series in Biomaterials Science and Engineering ((SSBSE,volume 2))

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Abstract

Among many calcium phosphates, apatitic ones are by far familiar because of their lattice structure similar to bone apatites. Yet, if one wants an apatite layer as a tool for improving tissue compatibility, regardless of hard or soft tissues, stoichiometric apatite is not necessary but nonstoichiometric apatite, e.g., with calcium ion deficiency or partial carbonate ion substitution, is preferable. Such apatite is easily provided on the surface of several materials when they are in contact with plasma; the materials include silicate glass and glass-ceramics and organic–inorganic hybrids with Si–O or Ti–O bonds as their skeleton, as well as some oxide gels derived via the sol-gel procedure. Moreover, proper water-soluble glass with specific compositions will be converted to apatite agglomerates or to rod- or needlelike apatite crystallites in array on their surface. The present chapter reviews deposition of apatitic calcium phosphates on such materials under body environment and their deposition mechanism in relation to constructing bone tissue as a hybrid between collagen fibrils and apatite crystallites.

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Acknowledgment

The author is very grateful of all the works introduced here and should apologize for not all work pertinent to this topic are described, as it is impossible.

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  1. Faculty of Engineering, Okayama University, Tsushima, Okayama-shi, 700-8530, Japan

    Akiyoshi Osaka

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  1. Chemistry and Forensic Science, University of Technology, Sydney, New South Wales, Australia

    Besim Ben-Nissan

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Osaka, A. (2014). Self-Assembly and Nano-layering of Apatitic Calcium Phosphates in Biomaterials. In: Ben-Nissan, B. (eds) Advances in Calcium Phosphate Biomaterials. Springer Series in Biomaterials Science and Engineering, vol 2. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-53980-0_5

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