Skip to main content

Multiferroic and Magnetoelectric Hexagonal Ferrites

  • Chapter
  • First Online:
Mesoscopic Phenomena in Multifunctional Materials

Part of the book series: Springer Series in Materials Science ((SSMATERIALS,volume 198))

Abstract

The hexagonal ferrites, also known as hexaferrites, have become massively important materials commercially and technologically, accounting for the bulk of the total magnetic materials manufactured globally, and they have a multitude of uses and applications. As well as their use as permanent magnets, common applications are as magnetic recording and data storage materials, and as components in electrical devices, particularly those operating at microwave/GHz frequencies for mobile and wireless communications, electromagnetic wave absorbers for electromagnetic compatibility (EMC), radar absorbing materials (RAM) and stealth technologies. One of the most exciting recent developments has been the discovery of single phase magnetoelectric/multiferroic hexaferrites, firstly Ba2Mg2Fe12O22 Y-type ferrite at cryogenic temperatures, and more recently Sr3Co2Fe24O41 Z-type ferrite at room temperature. Several Y-type, substituted M-type, and U-type (Sr4Co2Fe36O60) ferrites have now been characterised as room temperature multiferroics, and are discussed in this chapter.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. R.C. Pullar, Prog. Mat. Sci. 57, 1191 (2012)

    Article  Google Scholar 

  2. Q. Mohsen, Am. J. Appl. Sci. 7, 914 (2010)

    Article  Google Scholar 

  3. U. Ozgur, Y. Alivov, H. Morkoc, J. Mat. Sci. Mater Electron 20, 789 (2009)

    Google Scholar 

  4. O. Gutfleisch, M.A. Willard, E. Brück, C.H. Chen, S.G. Sankar, J.P. Liu, Adv. Mater. 23, 821 (2011)

    Article  Google Scholar 

  5. V.G. Harris, IEEE Trans. Mag. 48, 1075 (2012)

    Article  Google Scholar 

  6. J.J. Went, G.W. Rathenau, E.W. Gorter, G.W. Van Oosterhout, Phil. Tech. Rev. 13, 194 (1952)

    Google Scholar 

  7. H.P.J. Wijn, Nature 170, 707 (1952)

    Article  Google Scholar 

  8. P.B. Braun, Nature 170, 708 (1952)

    Article  Google Scholar 

  9. G.H. Jonker, H.P.J. Wijn, P.B. Braun, Phil. Tech. Rev. 18, 145 (1956)

    Google Scholar 

  10. J. Smit, H.P.J. Wijn, Ferrites (Philips Technical Library, Eindhoven, 1959)

    Google Scholar 

  11. D. Lisjak, D. Makovec, M. Drofenik, J. Mater. Res. 19, 2462 (2004)

    Article  Google Scholar 

  12. N. Hill, J. Phys. Chem. B 104, 6694 (2000)

    Article  Google Scholar 

  13. C.N.R. Rao, A. Sundaresan, R. Saha, J. Phys. Chem. Lett. 3, 2237 (2012)

    Article  Google Scholar 

  14. Y. Tokura, S. Seki, Adv. Mat. 22, 1554 (2012)

    Article  Google Scholar 

  15. P.B. Braun, Phil. Res. Rep. 12, 491 (1957)

    Google Scholar 

  16. C. Sudakar, G.N. Subbanna, T.R.N. Kutty, J. Magn. Magn. Mater. 263, 253 (2003)

    Article  Google Scholar 

  17. M. Sugimoto, in Ferromagnetic Materials, vol. 3. ed. E.P. Wohfarth, (North-Holland Physics Publishing, Amsterdam 1980) pp. 392–440

    Google Scholar 

  18. K. Kamishima, N. Hosaka, K. Kakizaki, N. Hiratsuka, J. Appl. Phys. 109, 013904 (2011)

    Article  Google Scholar 

  19. A.E. Van Arkel, E.J.W. Verwey, M.G. Van Bruggen, Rev. Trv. Chim. 55, 331 (1936)

    Article  Google Scholar 

  20. W.H. Von Aulok, in Handbook of Microwave Ferrites (Academic Press, New York, 1965)

    Google Scholar 

  21. International Centre for Diffraction Data, Newton Square, PA, USA PDF no. 84-1531 (SrFe12O19), 84-757 (Ba Fe12O19), 84-2046 (PbFe12O19)

    Google Scholar 

  22. S. Ram, D. Bahadur, D. Chakravorty, J, Non-Cryst. Sol. 101, 227 (1988)

    Google Scholar 

  23. V. Adelskold, Arkiv. Kemi., Min. Geol. 12a, 1 (1938)

    Google Scholar 

  24. J. Kreisel, H. Vincent, F. Tasset, M. Paté, J.P. Ganne, J. Magn. Mag. Mat. 224, 17 (2001)

    Article  Google Scholar 

  25. L.M. Castelliz, K.M. Kim, P.S. Boucher, J. Can. Ceram. Soc. 38, 57 (1969)

    Google Scholar 

  26. G. Albanese, A. Deriu, S. Rinaldi, Appl. Phys. 7, 1313 (1975)

    Article  Google Scholar 

  27. A.J. Kerecman, A. Tauber, T.R. Avlon, R.O. Savage, J. Appl. Phys. 39, 726 (1968)

    Article  Google Scholar 

  28. J.A. Kohn, D.W. Eckart, C.F. Cook Jr., Science 172, (May 7, No. 3983), 519 (1971)

    Google Scholar 

  29. D. Lisjak, D. Makovec, M. Drofenik, J. Mater. Res. 19, 2462 (2004)

    Article  Google Scholar 

  30. K. Okumura, T. Ishikura, M. Soda, T. Asaka, H. Nakamura, Y. Wakabayashi, T. Kimura, Appl. Phys. Lett. 98, 212504 (2011)

    Article  Google Scholar 

  31. C.G. Koop, Phys. Rev. 83, 121 (1951)

    Article  Google Scholar 

  32. L.G. van Uitert, Proc. Ire 44, 1294 (1956)

    Article  Google Scholar 

  33. L.G. van Uitert, Proc. Comf. Mag. Magn. Mat. AIEE 44, 299 (1955)

    Google Scholar 

  34. R. Parker, B.A. Griffiths, D. Elwell, Br. J. Appl. Phys. 17, 1269 (1966)

    Article  Google Scholar 

  35. D. Ravinder, P. Shalini, P. Manesh, K. Koteswara Rao, M. Vithal, B.S. Boyanov, J. Alloys Comp. 364, 17 (2004)

    Google Scholar 

  36. E. Neckenburger, H. Severin, J.K. Vogel, G. Winkler, Z. Angew Phys. 18, 65 (1964)

    Google Scholar 

  37. M.A. Vinnik, Russ. J. Inorg. Chem. 10, 1164 (1965)

    Google Scholar 

  38. S.I. Kuznetsova, E.P. Naiden, T.N. Stepanova, Inorg. Mat. 24, 856 (1988)

    Google Scholar 

  39. J. Drobek, W.C. Bigelow, R.G. Wells, J. Am. Ceram. Soc. 44, 262 (1961)

    Article  Google Scholar 

  40. F.K. Lotgering, J. Inorg. Nuclear Chem. 9, 113 (1959)

    Article  Google Scholar 

  41. F.K. Lotgering, J. Inorg. Nuclear Chem. 16, 100 (1960)

    Article  Google Scholar 

  42. Y. Goto, T. Takada, J. Am. Ceram. Soc. 43, 150 (1960)

    Article  Google Scholar 

  43. H.J. Van Hook, J. Am. Ceram. Soc. 47, 57 (1964)

    Article  Google Scholar 

  44. P. Batti, Ann. Chim. (Rome) 50, 1461 (1960)

    Google Scholar 

  45. H. Stablein, W. May, Ber. Deut. Keram. Geselschaft 46, 69 (1969)

    Google Scholar 

  46. J.S. Reed, R.M. Fulrath, J. Am. Ceram. Soc. 56, 207 (1973)

    Article  Google Scholar 

  47. J. Lipka, A. Grusková, M. Michalíková, M. Miglierini, J. Sláma, I. Tóth, J. Magn. Mag. Mat. 140–144, 2209 (1995)

    Article  Google Scholar 

  48. R.C. Pullar, M.D. Taylor, A.K. Bhattacharya, J. Mat. Sci. 32, 352 (1997)

    Google Scholar 

  49. R.C. Pullar, S.G. Appleton, A.K. Bhattacharya, J. Magn. Mag. Mat. 186, 326 (1998)

    Article  Google Scholar 

  50. R.C. Pullar, M.D. Taylor, A.K. Bhattacharya, J. Euro, Ceram. Soc. 22, 2039 (2002)

    Article  Google Scholar 

  51. R.C. Pullar, A.K. Bhattacharya, Mat. Lett. 57, 537 (2002)

    Article  Google Scholar 

  52. H. Wullkopf, Int. J. Mag. 3, 179 (1972)

    Google Scholar 

  53. D. Lisjak, M. Drofenik, J. Euro, Ceram. Soc. 27, 4515 (2007)

    Article  Google Scholar 

  54. D. Lisjak, M. Drofenik, J. Euro, Ceram. Soc. 26, 3681 (2006)

    Article  Google Scholar 

  55. D. Lisjak, M. Drofenik, J. Mat. Sci. 42, 8606 (2007)

    Article  Google Scholar 

  56. X. Liu, J. Wang, L.M. Gan, S.C. Ng, J. Magn. Mag. Mat. 195, 452 (1999)

    Article  Google Scholar 

  57. H. Yamamoto, H. Kumehara, R. Takeuchi, N. Nishio, J. De Phys. IV 7, C1–535 (1997)

    Google Scholar 

  58. R.C. Pullar, M.D. Taylor, A.K. Bhattacharya, J. Mat. Res. 16, 3162 (2001)

    Article  Google Scholar 

  59. R.C. Pullar, M.D. Taylor, A.K. Bhattacharya, J. Mat. Sci. 32, 365 (1997)

    Article  Google Scholar 

  60. S.I. Kuznetsova, E.P. Naiden, T.N. Stepanova, Inorg. Mat. 24, 856 (1988)

    Google Scholar 

  61. A.L. Stuijts, in Ceramic Microstructures (Wiley, New York, 1968), p. 443

    Google Scholar 

  62. E.M.C. Huijser-Gerits, G.D. Rieck, J. Appl. Cryst. 9, 18 (1976)

    Article  Google Scholar 

  63. R.C. Pullar, S.G. Appleton, M.H. Stacey, M.D. Taylor, A.K. Bhattacharya, J. Magn. Mag. Mat. 186, 313 (1998)

    Article  Google Scholar 

  64. R.C. Pullar, M.H. Stacey, M.D. Taylor, A.K. Bhattacharya, Acta. Mat. 49, 4241 (2001)

    Article  Google Scholar 

  65. T.M. Perekalina, A.D. Shchvrova, S.S. Fonton, D. G. Annikov, Soviet Phys. JETP-31, 440 (1970)

    Google Scholar 

  66. R.C. Pullar, A.K. Bhattacharya, Mat. Res. Bull. 36, 1531 (2001)

    Article  Google Scholar 

  67. T. Nakamura, E. Hanuki, J. Magn. Mag. Mat. 257, 158 (2003)

    Article  Google Scholar 

  68. Y. Takada, T. Nakagawa, M. Tokunaga, Y. Fukuta, T. Tachibana, Y. Ishii, N. Igawa, J. Appl. Phys. 100, 043904 (2006)

    Article  Google Scholar 

  69. T. Kikuchi, T. Nakamura, T. Yamasaki, M. Nakanishi, T. Fujii, J. Takada, Y. Ikeda, Mat. Res. Bull. 46, 1085 (2011)

    Article  Google Scholar 

  70. R.C. Pullar, A.K. Bhattacharya, J. Mat. Sci. 36, 4805 (2001)

    Article  Google Scholar 

  71. D. Lisjak, V.B. Bregar, M. Drofenik, J. Magn. Mag. Mat. 310, 2558 (2007)

    Article  Google Scholar 

  72. G. Xiong, M. Xu, Z. Mai, Solid State Comm. 118, 53 (2001)

    Article  Google Scholar 

  73. D. Lisjak, M. Drofenik, J. Magn. Mag. Mat. 272–6, e1817 (2004)

    Article  Google Scholar 

  74. M. Chandra Dimri, H. Khanduri, H. Kooskora, I. Heinmaa, E. Joon, R. Stern, J. Magn. Mag. Mat. 323, 2210 (2011)

    Google Scholar 

  75. T. Kimura, Ann. Rev. Mat. Res. 37, 387 (2007)

    Article  Google Scholar 

  76. T. Kimura, G. Lawes, A.P. Raimirez, Phys. Rev. Lett. 94, 137201 (2005)

    Article  Google Scholar 

  77. N. Momozawa, Y. Yamaguchi, H. Takei, M. Mita, J. Phys. Soc. Jpn. 54, 771 (1985)

    Article  Google Scholar 

  78. N. Momozawa, Y. Yamaguchi, J. Phys. Soc. Jpn. 62, 1292 (1993)

    Article  Google Scholar 

  79. P. Novák, K. Knizek, J. Rusz, Phys. Rev. B 76, 024432 (2007)

    Article  Google Scholar 

  80. Y.S. Chai, S.H. Chun, S.Y. Haam, Y.S. Oh, I. Kim, K.H. Kim, New J. Phys. 11, 073030 (2009)

    Article  Google Scholar 

  81. S. Kamba, V. Goian, M. Savinov, E. Buixaderas, D. Nuzhnyy, M. Maryško, M. Kempa, V. Bovtun, J. Hlinka, K. Knížek, P. Vaněk, P. Novák, J. Buršík, Y. Hiraoka, T. Kimura, K. Kouřil, H. Štěpánková, J. Appl. Phys. 107, 104109 (2010)

    Article  Google Scholar 

  82. S.H. Chun, Y.S. Chai, Y.S. Oh, D. Jaiswal-Nagar, S. Y. Haam, I. Kim, B. Lee, D.H. Nam, K-T. Ko, J-H. Park, J-H. Chung, K.H. Kim, Phys. Rev. B. 104, 037204 (2010)

    Google Scholar 

  83. H. Chang, H.B. Lee, Y-S. Song, J-H. Chung, S.A. Kim, I.H. Oh, M. Reehuis, J. Schefer, Phys. Rev. B 85, 064402 (2012)

    Google Scholar 

  84. H.B. Lee, Y-S. Song, J-H. Chung, S.H. Chun, Y.S. Chai, K.H. Kim, M. Reehuis, K. Prokes, S. Mat’as, Phys. Rev. B 83, 144425 (2011)

    Google Scholar 

  85. M.A. El Hiti, A.M. Abo El Ata, J. Magn. Mag. Mat. 195, 667 (1999)

    Article  Google Scholar 

  86. Y. Hiraoka, H. Nakamura, M. Soda, Y. Wakabayashi, T. Kimura, J. Appl. Phys. 110, 033920 (2011)

    Article  Google Scholar 

  87. H.B. Lee, S.H. Chun, K.W. Shin, B-G. Jeon, Y.S. Chai, K.H. Kim, J. Scherfer, H, Chang, S-N. Yun, T-Y. Joung and J-H. Chung, Phys. Rev. B 86 (2012) 094435

    Google Scholar 

  88. F. Wang, T. Zou, L-Q. Yan, Y. Liu, Y. Sun, Appl. Phys. Lett. 100, 122901 (2012)

    Google Scholar 

  89. K. Taniguchi, N. Abe, S. Ohtani, H. Umetsu, T-H. Arima, Appl. Phys. Express 1, 031201 (2008)

    Google Scholar 

  90. S. Ishiwata, Y. Taguchi, H. Murakawa, Y. Onose, Y. Tokura, Science 319, 1643 (2008)

    Article  Google Scholar 

  91. S. Ishiwata, D. Okuyama, K. Kakurai, M. Nishi, Y. Taguchi, Y. Tokura, Phys. Rev. B 81, 174418 (2010)

    Article  Google Scholar 

  92. S. Ishitawa, Y. Taguchi, Y. Tokunaga, H. Murakawa, Y. Onose, Y. Tokura, Phys. Rev. B 79, 180408 (2009)

    Article  Google Scholar 

  93. Y. Kitagawa, Y. Hiraoka, T. Honda, T. Ishikura, H. Nakamura, T. Kimura, Nat. Mat. 9, 797 (2010)

    Article  Google Scholar 

  94. Y. Takada, T. Tachibana, T. Nakagawa, T.A. Yamamoto, T. Shimada, S. Kawano, J. Japn, Soc. Powder Powder Metal. 50, 618 (2003)

    Article  Google Scholar 

  95. M. Soda, T. Ishikura, H. Nakamura, Y. Wakabayashi, T. Kimura, Phys. Rev. Lett. 106, 087201 (2011)

    Article  Google Scholar 

  96. K. Ebnabbasi, C. Vittoria, A. Widom, Cornell University Library ArXiv, arXiv:1111.5636v1 [cond-mat.mtrl-sci], 23rd November 2011 http://arxiv.org/abs/1111.5636. Accessed Feb 2012

  97. K. Okumura, K. Haruki, T. Ishikura, S. Hirose, T. Kimura, Appl. Phys. Lett. 103, 032906 (2013)

    Google Scholar 

  98. J. Wu, Z. Shi, J. Xu, N. Li, Z. Zheng, H. Geng, Z. Xie, L. Zheng, Appl. Phys. Lett. 101, 122903 (2012)

    Article  Google Scholar 

  99. E. Matsubara, Y. Onishi, T. Ishikura, T. Kimura, M. Ashida, in Proceedings of 2011 Conference Lasers Electro-Optics Europe (CLEO) (2011) 59425222 DOI: 10.1109/CLEOE.2011.5942522

  100. N. Kida, D. Okuyama, S. Ichitawa, Y. Taguchi, R. Shimano, K. Iwasa, T. Arima, Y. Tokura, Phys. Rev. B 80, 220406 (2009)

    Article  Google Scholar 

  101. K. Ebnabbasi, M. Mohebbi, C. Vittoria, Appl. Phys. Lett. 101, 062406 (2012)

    Article  Google Scholar 

  102. K. Ebnabbasi, Y. Chen, A. Geiler, V. Harris, C. Vittoria, J. Appl. Phys. 111, 07C719 (2012)

    Article  Google Scholar 

  103. K. Ebnabasi, C. Vittoria, A. Widom, Phys. Rev. B 86, 024430 (2012)

    Article  Google Scholar 

  104. Y. Tokunaga, Y. Kaneko, D. Okuyama, S. Ishitawa, T. Arima, S. Wakimoto, K. Kakurai, Y. Taguchi, Y. Tokura, Phys. Rev. Lett. 105, 257201 (2010)

    Article  Google Scholar 

  105. M. Mohebbi, K. Ebnabbasi, C. Vittoria, J. Appl. Phys. 113, 17C710 (2013)

    Article  Google Scholar 

Download references

Acknowledgments

The author would firstly like to thank Prof. Avadh Saxena for being an extremely patient and understanding editor. The FCT (Fundação para a Ciência e a Tecnologia in Portugal) and the FCT Ciência 2008 program are acknowledged for funding the author during the writing and publication of this chapter. The author would also like to thank the publishers and copy write holders of all figures from previous sources used in this article, which have been referenced in the relevant figure captions.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Robert C. Pullar .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2014 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Pullar, R.C. (2014). Multiferroic and Magnetoelectric Hexagonal Ferrites. In: Saxena, A., Planes, A. (eds) Mesoscopic Phenomena in Multifunctional Materials. Springer Series in Materials Science, vol 198. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-55375-2_7

Download citation

Publish with us

Policies and ethics