Skip to main content
SpringerLink
Log in

Dielectric Spectroscopy of Reactive Network-Forming Polymers

  • Chapter
Broadband Dielectric Spectroscopy

Abstract

There are very good reasons for the current surge of interest in fundamental and applied aspects of dielectric spectroscopy (DS) of polymeric materials. Fundamental investigations of the dielectric response yield a wealth of information about different molecular motions and relaxation processes. A unique characteristic of DS is the wide frequency range, from 10-5 Hz to 1011 Hz, over which polymers respond to an applied electric field. This remarkable breadth is the key feature that enables one to relate the observed dielectric response to slow (low frequency) and/or fast (high frequency) molecular events. Complementary information to DS studies can be obtained from nuclear magnetic resonance (NMR), dynamic mechanical analysis (DMA), quasi-elastic light scattering (QELS), quasi-elastic neutron scattering (QENS), transient fluorescence depolarization, and ultrasonic measurements, but none of those techniques can cover as wide a frequency range. A strong industrial interest in dielectric and electrical properties of polymers reflects the growing use of these materials in electronic interconnect devices, optoelectronic switches, printed board circuitry, microwave assemblies for radar, batteries, fuel cells, and so on.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 429.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 549.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 549.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. McCrum NG, Read B, Williams G (1967) In: Anelastic and dielectric effects in polymeric solids. Wiley, NY

    Google Scholar 

  2. Karasz FE (ed) (1972) Dielectric properties of polymers. Plenum Press, NY

    Google Scholar 

  3. Hedvig P (1977) Dielectric spectroscopy of polymers. Adam Hilger, Bristol

    Google Scholar 

  4. Böttcher CJF, Bordewijk P (1978) Theory of electric polarization. Elsevier, Amsterdam

    Google Scholar 

  5. Williams G (1979)Adv Polym Sci 33:60

    Google Scholar 

  6. Jonscher AK (1983) Dielectric relaxation in solids. Chelsea Dielectric Press, London

    Google Scholar 

  7. Ku CC, Liepins R (1987) Electrical properties of polymers. Hanser, Munich

    Google Scholar 

  8. Owen J (1988) In: Allen G, Bevington JC (eds) Comprehensive polymer science, vol 2. Pergamon Press, Oxford, pp 669–686

    Google Scholar 

  9. Williams G (1988) In: Allen G, Bevington JC (eds) Comprehensive polymer science, vol 2. Pergamon Press, Oxford, pp 601–632

    Google Scholar 

  10. Riande E, Saiz E (1992) Dipole moments and birefringence of polymers. Prentice Hall, NY

    Google Scholar 

  11. Williams G (1997) In: Riande E (ed) Keynote lectures in selected topics of polymer science, chap 1. CSIC, Madrid, pp 1–40

    Google Scholar 

  12. Block H (1979) Conductive polymers, where charge carriers are electrons and electron holes, will not be discussed here and the reader is referred to the excellent article by Block .Adv Polym Sci 33:93

    CAS  Google Scholar 

  13. Block H (1979)Adv Polym Sci 33:93

    CAS  Google Scholar 

  14. Bockris JO’M, Reddy AKN (1970) Modern electrochemistry, vols 1 and 2. Plenum Press, NY

    Google Scholar 

  15. Barker RE Jr (1976)Pure Appl Chem 46:157

    CAS  Google Scholar 

  16. Seanor DA (ed) (1982) Electrical properties of polymers. Academic Press, NY

    Google Scholar 

  17. Gray FM (1991) Solid polymer electrolytes.VCH, New York

    Google Scholar 

  18. Gallone G, Levita G, Mijovic J, Andjelic S, Rolla P (1998)Polymer 39:2095

    CAS  Google Scholar 

  19. Macdonald JR (1987) Impedance spectroscopy. Wiley, New York

    Google Scholar 

  20. Metaxas AC, Meredith RJ (1983) Industrial microwave heating. Peregrinus, London

    Google Scholar 

  21. Kremer F, Arndt M (1997) In: Runt JP, Fitzgerald JJ (eds) Dielectric spectroscopy of polymeric materials, chap 2. Amererican Chemical Society, Washington, DC, p 67

    Google Scholar 

  22. Gotro J, Yandrasits M (1989)Polym Eng Sci 29:278

    CAS  Google Scholar 

  23. Andjelic S, Fitz B, Mijovic J (1997)Macromolecules 30:5239; Fitz B, Andjelic S, Mijovic J (1997) Macromolecules 30:5227

    CAS  Google Scholar 

  24. Mijovic J, Andjelic S (1995)Macromolecules 28:2787

    CAS  Google Scholar 

  25. Mijovic J, Andjelic S (1995)Polymer 36:3783

    CAS  Google Scholar 

  26. Sheppard NF, Garverick SL, Day DR, Senturia SD (1981)SAMPE Int Symp 26:65

    CAS  Google Scholar 

  27. Senturia SD, Sheppard NF Jr, Lee HL, Day DR (1982)J Adhesion 15:69

    CAS  Google Scholar 

  28. Day DR, Lewis TJ, Lee HL, Senturia SD (1985)J Adhesion 18:73

    CAS  Google Scholar 

  29. Bidstrup WW, Sheppard NF Jr, Senturia SD (1986)Polym Eng Sci 26:358

    CAS  Google Scholar 

  30. Kranbuehl DE, Delos SE, Jue PK (1986)Polymer 27:11

    CAS  Google Scholar 

  31. Kranbuehl DE, Delos SE, Hoff M, Weller L, Haverty L, Seeley J (1987)SAMPE Int Symp 32:338

    Google Scholar 

  32. Kranbuehl DE, Hoff M, Haverty L, Loss A, Freeman T (1988)SAMPE Int Symp 33:1276

    CAS  Google Scholar 

  33. Sluyters-Rehbach M, Sluyters JH (1977) In: Bard AJ (ed) Electroanalytical chemistry, vol 4. Marcel Dekker, New York, pp 1–127

    Google Scholar 

  34. Archer WI, Armstrong RD (1980)Electrochemistry 7:157

    CAS  Google Scholar 

  35. Walter GW (1986)Corrosion Sci 26:681

    CAS  Google Scholar 

  36. Cole RH, Cole KS (1941)J Chem Phys 9:341

    CAS  Google Scholar 

  37. Kenny JM, Trivisano A (1991)Polym Sci Eng 31:19

    Google Scholar 

  38. Mijovic J, Bellucci F (1996)Trends Polym Sci 4:74

    CAS  Google Scholar 

  39. Tajima YA (1982)Polym Composites 3:162

    CAS  Google Scholar 

  40. Koike T (1993)J Appl Polym Sci 50:1943

    CAS  Google Scholar 

  41. Maistros GM, Bucknall CB (1994)Polym Eng Sci 34:1517

    CAS  Google Scholar 

  42. Opalicki M, Kenny JM (1993)Makromol Chem Makromol Symp 68:41

    Google Scholar 

  43. Senturia SD, Sheppard NF (1986)Adv Polym Sci 80:1

    CAS  Google Scholar 

  44. Mijovic J, Kenny JM, Maffezzoli A, Trivisano A, Bellucci F, Nicolais L (1993)Comp Sci Tech 49:277

    CAS  Google Scholar 

  45. Kranbuehl DE (1997) In: Runt JP, Fitzgerald JJ (eds) Dielectric spectroscopy of polymeric materials. American Chemical Society, Washington, DC, Chap 11, p 303

    Google Scholar 

  46. Sanjana ZN (1986)Polym Eng Sci 26:373

    CAS  Google Scholar 

  47. Zukas WX, Wentworth SE (1987)Polym Composites 8:232

    CAS  Google Scholar 

  48. Day DR, Sheppard DD (1989)Mater Res Soc Symp Proc 142:227

    CAS  Google Scholar 

  49. Day DR (1989)Polym Eng Sci 29:334

    CAS  Google Scholar 

  50. Day DR, Sheppard DD (1991)Polym Composites 12:87

    CAS  Google Scholar 

  51. Mathieu C, Boiteux G, Seytre G, Villain R, Dublineau P (1994)J Non-Cryst Solids 172/ 174:1012

    Google Scholar 

  52. Maistros GM, Partridge IK (1995)Comp Sci Tech 53:355

    CAS  Google Scholar 

  53. Maistros GM, Partridge IK (1998)Composites Part B 29B:245

    CAS  Google Scholar 

  54. Kranbuehl DE, Eichinger D, Hamilton T, Clark R (1991)Polym Eng Sci 31:5

    Google Scholar 

  55. Kranbuehl DE (1991)J Non-Cryst Solids 131/133:930

    Google Scholar 

  56. Kranbuehl DE, Kingsley P, Hart S, Hasko G, Dexter B, Loos A (1994)Polym Composites 15:297

    Google Scholar 

  57. Ciriscioli PR, Springer GS (1989)SAMPE J 25:35

    CAS  Google Scholar 

  58. Ulanski J, Friedrich K, Boiteux G, Seytre G (1997)J Appl Polym Sci 65:1143

    CAS  Google Scholar 

  59. Angell CA, Boehm L, Oguni M, Smith DL (1993)J Mol Liq 56:275

    CAS  Google Scholar 

  60. Johari GP (1984) In: Ngai K, Wright GB (eds) Relaxations in complex systems. National Technical Information Service, US Department of Commerce, Springfield, VA

    Google Scholar 

  61. Lewis LJ, Wahnstrom G (1994)Phys Rev E 50:3865

    CAS  Google Scholar 

  62. Johari GP, Goldstein M (1970)J Chem Phys 53:2372

    CAS  Google Scholar 

  63. Meier G, Fujara F, Petry W (1989)Macromolecules 22:4421

    CAS  Google Scholar 

  64. Stockmayer WH (1967)Pure Appl Chem 15:539

    Google Scholar 

  65. Imanishi Y, Adachi L, Kotaka T (1988)J Chem Phys 89:7585

    CAS  Google Scholar 

  66. Adachi K, Yoshida H, Fukui F, Kotaka T (1990)Macromolecules 23:3138

    CAS  Google Scholar 

  67. Boese D, Kremer F (1990)Macromolecules 23:8298

    Google Scholar 

  68. Boese D, Kremer F, Fetters LJ (1990)Macromolecules 23:1826

    CAS  Google Scholar 

  69. Adachi K, Kotaka T (1993)Prog Polym Sci 18:585

    CAS  Google Scholar 

  70. Watanabe H, Urakawa O, Yamada H, Yao M-L (1996)Macromolecules 29:755

    CAS  Google Scholar 

  71. Pakula T, Geyler S, Edling T, Boese D (1996)Rheol Acta 35:1

    Google Scholar 

  72. Fitz BD, Mijovic J (1999)Macromolecules 32:3518

    CAS  Google Scholar 

  73. Müller M, Stadler R, Kremer F, Williams G (1995)Macromolecules 28:6942

    Google Scholar 

  74. Müller M, Kremer F, Stadler R, Fischer EW, Seidel U (1995)Colloid Polym Sci 273:38

    Google Scholar 

  75. Carlini C, Rolla PA, Tombari E (1990)J Appl Polym Sci 41:805

    CAS  Google Scholar 

  76. Tombari E, Johari GP (1993)J Chem Soc Faraday Trans 89:3477

    CAS  Google Scholar 

  77. Carlini C, Livi A, Rolla PA, Fioretto D (1994)J Non-Cryst Solids 172/174:569

    Google Scholar 

  78. Fournier J, Williams G, Holmes PA (1997)Macromolecules 30:2042

    CAS  Google Scholar 

  79. Casalini R, Corezzi S, Fioretto D, Livi A, Rolla PA (1996)Chem Phys Lett 258:470

    CAS  Google Scholar 

  80. Wasylyshyn DA, Johari GP, Tombari E, Salvetti G (1997)Chem Phys 223:313

    CAS  Google Scholar 

  81. Mijovic J, Fitz B (1998)Polym Adv Tech 9:721

    Google Scholar 

  82. Fitz BD, Mijovic J (1999)Macromolecules 32:4134

    CAS  Google Scholar 

  83. Ngai KL, Mashimo S, Fytas G (1988)Macromolecules 21:3030

    CAS  Google Scholar 

  84. Boese D, Momper B, Meier G, Kremer F, Hagenah J, Fischer E (1989)Macromolecules 22:4416

    CAS  Google Scholar 

  85. Hwang Y, Patterson GD, Stevens J (1996)J Polym Sci Part B Polym Phys 34:2291

    CAS  Google Scholar 

  86. Floudas G, Placke P, Stepanek P, Brown W, Fytas G, Ngai KL (1995)Macromolecules 28:6799

    CAS  Google Scholar 

  87. Meier G, Gerharz B, Boese D, Fischer, E (1991)J Chem Phys 94:3050

    CAS  Google Scholar 

  88. Lane JW, Seferis JC, Bachmann MA (1986)Polym Eng Sci 26:346

    CAS  Google Scholar 

  89. Lane JW, Seferis JC, Bachmann MA (1986)J Appl Polym Sci 31:1155

    CAS  Google Scholar 

  90. Nass KA, Seferis JC (1989)Polym Eng Sci 29:315

    CAS  Google Scholar 

  91. Dusi MR, May CA, Seferis JC (1983) In: May CA (ed) Chemorheology of thermosetting polymers.Am Chem Soc Symp Ser 227, p 301

    Google Scholar 

  92. Mangion M, Johari GP (1990)J Polym Sci Part B Polym Phys 29:1127

    Google Scholar 

  93. Parthun MG, Johari GP (1992)Macromolecules 25:3254

    CAS  Google Scholar 

  94. Parthun MG, Johari GP (1992)Macromolecules 25:3149

    CAS  Google Scholar 

  95. Zukas W (1992)Macromolecules 26:2390

    Google Scholar 

  96. Barton JM (1985)Adv Polym Sci 72:111

    CAS  Google Scholar 

  97. Fournier J, Williams G, Duch C, Aldridge GA (1996)Macromolecules 29:7097

    CAS  Google Scholar 

  98. Andjelic S, Mijovic J (1998)Macromolecules 31:8463

    CAS  Google Scholar 

  99. Deng Y, Martin GC (1994)J Polym Sci Part B Polym Phys 32:2115

    CAS  Google Scholar 

  100. Deng Y, Martin GC (1994)Macromolecules 27:5141

    CAS  Google Scholar 

  101. Deng Y, Martin GC (1994)Macromolecules 27:5147

    CAS  Google Scholar 

  102. Huguenin FGAE, Klein MT (1985)Ind Eng Chem Prod Res Dev 24:166

    CAS  Google Scholar 

  103. Kenny JM, Apicella A, Nicolais L (1989)Polym Eng Sci 29:972

    Google Scholar 

  104. Dusek K (1986)Adv Polym Sci 78:1

    CAS  Google Scholar 

  105. Rozenberg BA (1985)Adv Polym Sci 75:113

    Google Scholar 

  106. Tanaka Y, Bauer RS (1988) In: May CA (ed) Epoxy resins chemistry and technology, 2nd edn. Marcel Dekker, New York, chap 3, pp 285–464

    Google Scholar 

  107. Roland CM (1994)Macromolecules 27:4242

    CAS  Google Scholar 

  108. Glatz-Reichenbach JKW, Sorriero LJ, Fitzgerald JJ (1994)Macromolecules 27:1338

    CAS  Google Scholar 

  109. Boese D, Momper B, Meier G, Kremer F, Hagenah J, Fischer EW (1989)Macromolecules 22:4416

    CAS  Google Scholar 

  110. Matsuoka S (1997)J Appl Polym Sci 64:77

    CAS  Google Scholar 

  111. The phenomenon of a network relaxation becoming entirely local because of the network’s disturbance of the cooperative domain size is the subject of current research in our laboratory. The effect is similar to the situation of amorphous polymer confined within a thin space between crystalline lamellar walls; e.g., Schick C, Donth E (1991) Phys Scr 43:423; Arndt M, Stannarius R, Groothues H, Hempel E, Kremer F (1997) Phys Rev Lett 79:2077; Sy JW, Mijovic J (2000) Macromolecules 33:933

    Google Scholar 

  112. Sillescu H (1999)J Non-Cryst Solids 243:81

    CAS  Google Scholar 

  113. Fröhlich H (1949) Theory of dielectrics. Oxford University Press, London

    Google Scholar 

  114. Wei Y, Sridhar S (1989)Rev Sci Instr 60:3041

    Google Scholar 

  115. Stuchly M, Stuchly S (1980) IEEE Trans on Instr Meas IM29, p 176

    Google Scholar 

  116. Das NK, Voda SM, Pozar DM (1987) IEEE Trans Microwave Theory and Techniques MTT35, p 636

    Google Scholar 

  117. Cole RH, Mashimo S, Windsor P IV (1980)J Phys Chem 84:786

    CAS  Google Scholar 

  118. Carrozzino S, Levita G, Rolla PA, Tombari E (1990)Polym Eng Sci 30:366

    CAS  Google Scholar 

  119. Fioretto D, Livi A, Rolla PA, Socino G, Vardini G (1994)J Phys Condensed Matter 6:5294

    Google Scholar 

  120. Baker KR, Graybeal JD (1991) In: Symposium on Polymer Radiation Chemistry. American Chemical Society, p 470

    Google Scholar 

  121. Marand E, Baker K, Graybeal J (1992)Macromolecules 25:2243

    CAS  Google Scholar 

  122. Jow J, Hawley M, Finzel M, Kern T (1988)Polym Eng Sci 28:1450

    CAS  Google Scholar 

  123. Havriliak S, Negami S (1966)J Polym Sci C14:99

    Google Scholar 

  124. Arbe A, Richter D, Colmenero J, Farago B (1996)Phys Rev E 54:3853

    CAS  Google Scholar 

  125. Williams G, Watts D (1970)Trans Farad Soc 66:80

    CAS  Google Scholar 

  126. Bendler JT, Shlesinger MF (1987)J Mol Liq 36:37

    CAS  Google Scholar 

  127. Ngai KL, Rendell RW (1991)J Non-Cryst Solids 131/133:233

    Google Scholar 

  128. Chamberlin RV, Kingsbury DW (1994)J Non-Cryst Solids 172/174:318

    Google Scholar 

  129. Ngai KL, Roland M (1992)Macromolecules 24:5315

    Google Scholar 

  130. For a review see: Angell CA (1995) Science 267:1924

    Google Scholar 

  131. Matsuoka S, Quan X, Bair HE, Boyle DJ (1989)Macromolecules 22:4093

    CAS  Google Scholar 

  132. Adam G, Gibbs J (1965)J Chem Phys 43:139

    CAS  Google Scholar 

  133. Casalini R, Livi A, Rolla PA (1996)Phys Rev B 53:564

    CAS  Google Scholar 

  134. Andjelic S, Mijovic J (1998)Macromolecules 31:2872

    CAS  Google Scholar 

  135. Langier JM, Luck JM (1987)J Phys A 20:L885

    Google Scholar 

  136. Schönhals A, Schlosser E (1989)Colloid Polym Sci 267:125

    Google Scholar 

  137. Tabellout M, Randrianantoandro H, Emery JR, Durand D, Hayward D, Pethrick RA (1995)Polymer 36:4547

    CAS  Google Scholar 

  138. Katana G, Kremer F, Fischer E, Plaetschke R (1993)Macromolecules 26:3075

    CAS  Google Scholar 

  139. Kumar S, Colby R, Anastasiadis S, Fytas G (1996)J Chem Phys 105:3777

    CAS  Google Scholar 

  140. Ngai KL, Roland MC (1993)Macromolecules 26:6824

    CAS  Google Scholar 

Download references

Authors
  1. J. Mijovic
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Faculty of Physics and Geosciences, University of Leipzig, Linnéstraβe 5, 04103, Leipzig, Germany

    Friedrich Kremer

  2. Federal Institute for Materials Research and Testing, Unter den Eichen 87, 12205, Berlin, Germany

    Andreas Schönhals

Rights and permissions

Reprints and permissions

Copyright information

© 2003 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Mijovic, J. (2003). Dielectric Spectroscopy of Reactive Network-Forming Polymers. In: Kremer, F., Schönhals, A. (eds) Broadband Dielectric Spectroscopy. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-56120-7_9

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-56120-7_9

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-62809-2

  • Online ISBN: 978-3-642-56120-7

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation