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Superconductivity, Magnetism and Metal-Insulator Transitions in Some Ternary and Pseudoternary 3d-, 4d-, and 5d-Metal Oxides

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Spectroscopy of Mott Insulators and Correlated Metals

Abstract

Electron correlation effects have been found to be particularly important in metallic LiV2O4 and possibly Sr2Ir1−xRuxO4 (x > 0.7), but not in metallic Sr1−xLaxVO3 (x < 0.7), and they cause the compounds LaVO3, Sr2IrO4 and ZnV2O4 to be (Mott-Hubbard) insulators. The LiV2O4 spinel compound is especially interesting, because the V ions exhibit rather clear local moment (S = 1/2) behavior even though the compound is a metal.

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Johnston, D.C. et al. (1995). Superconductivity, Magnetism and Metal-Insulator Transitions in Some Ternary and Pseudoternary 3d-, 4d-, and 5d-Metal Oxides. In: Spectroscopy of Mott Insulators and Correlated Metals. Springer Series in Solid-State Sciences, vol 119. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-57834-2_22

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  • DOI: https://doi.org/10.1007/978-3-642-57834-2_22

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-63371-3

  • Online ISBN: 978-3-642-57834-2

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