Abstract
Second-order rate constants are reported for the reactions of the ammoniated electron with triphenylmethane, dimethyl sulfide, diethyl sulfide, imidazole, pyrrole, dimethyl sulfoxide, dl-norleucine, thiophene and pyridine. The second-order rate constants were found to vary from 5 × 105 to 6.5 × 10−2M−1sec−1 while activation energies for the reactions in which present data allowed determination, were invariant at 4–6 kcal/mole. The kinetic behavior of the ammoniated electron is compared with results obtained for the hydrated electron.
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Dewald, R.R., Jones, R.L., Boll, H. (1973). Kinetic Studies of Reactions Involving the Ammoniated Electron. In: Jortner, J., Kestner, N.R. (eds) Electrons in Fluids. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-61962-5_39
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DOI: https://doi.org/10.1007/978-3-642-61962-5_39
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