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Stationary Phases for Packed Column Supercritical Fluid Chromatography

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Analysis with Supercritical Fluids: Extraction and Chromatography

Abstract

Virtually all contemporary research using packed columns in SFC is performed with column packings and column dimensions optimized for high pressure liquid chromatography (HPLC) [1]. This catalyzed the early development of practical applications of packed column SFC and provided a variety of stationary phase chemistries to optimize individual separations with the limited selection of available supercritical fluids with favorable critical constants. The lack of a reliable theoretical framework for kinetic optimization of column parameters has also served to deflect attention from the question of whether columns designed for the separation of low-molecular-weight solutes with incompressible liquids are necessarily ideal for the typical separations most suited to SFC [2]. It is still too early to answer this question definitively but at least some positive statements can be made concerning column dimensions, packings, and operating conditions that are most useful for SFC.

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References

  1. Poole CF, Schuette SA (1984) Contemporary Practice of Chromatography. Elsevier, Amsterdam

    Google Scholar 

  2. Dean TA, Poole CF (1989) J Chromatogr 468:127

    Article  Google Scholar 

  3. Sanders LC, Wise SA (1987) CRC Crit Revs Anal Chem 18:299

    Google Scholar 

  4. Nawroeki J, Buszewski B (1988) J Chromatogr 449:1

    Article  Google Scholar 

  5. Kohler J, Kirkland J (1987) J Chromatogr 385:125

    Article  Google Scholar 

  6. Nawroeki J, Moir DL, Szczepaniak W (1989) J Chromatogr 28:143

    Article  Google Scholar 

  7. Sands PW, Kim YS, Bass JL (1986) J Chromatogr 360:353

    Article  CAS  Google Scholar 

  8. Buszewski B, Berek D, Garaj J, Novak I, Suprynowicz (1988) J Chromatogr 446:191

    Article  CAS  Google Scholar 

  9. Figge H, Deege A, Kohler J, Schomburg G (1986) H Chromatogr 351:393

    Article  CAS  Google Scholar 

  10. Bien-Vogelsand U, Deege A, Figge H, Koehler J, Schomburg G (1985) Chromatographia 19:170

    Article  Google Scholar 

  11. Engelhardt H, Low H, Eberhardt W, Mauss M (1989) Chromatographia 27:535

    Article  CAS  Google Scholar 

  12. Springston SR, David P, Steger J, Novotny M (1986) Anal Chem 58:997

    Article  CAS  Google Scholar 

  13. Unger KK (1983) Anal Chem 55:361A

    Article  CAS  Google Scholar 

  14. Knox JH, Kaur B, Millward GR (1986) J Chromatogr 352:3

    Article  CAS  Google Scholar 

  15. Bassler BJ, Hartwick RA (1989) J Chromatogr Sci 27:162

    CAS  Google Scholar 

  16. Lee DP (1988) J Chromatogr 443:143

    Article  CAS  Google Scholar 

  17. Stuurman HW, Kohler J, Jansson SO, Litzen A (1987) Chromatographia 23:341

    Article  CAS  Google Scholar 

  18. Neverjans F, Verzele M (1987) J Chromatogr 406:325

    Article  Google Scholar 

  19. King JW, Eissler AL, Friedrich JP (1988) In: Charpentier BA, Sevenants MR (ed) Supercritical Fluid Extraction and Chromatography Tfechniques and Applications. American Chemical Society, Washington, DC, p 63 (ACS Symposium Series nos 366)

    Chapter  Google Scholar 

  20. Nomura A, Yamada J, Tsunoda K-I (1988) J Chromatogr 448:87

    Article  CAS  Google Scholar 

  21. Nomura A, Yamada J, Tsunoda K-I, Sakaki K, Yokochi T (1989) Anal Chem 61:2076

    Article  CAS  Google Scholar 

  22. Warren FV, Bidlingmeyer B (1984) Anal Chem 56:950

    Article  CAS  Google Scholar 

  23. Schoenmakers PJ, Uunk LG, De Bokx PK (1988) J Chromatogr 459:201

    Article  CAS  Google Scholar 

  24. Ashraf-Khorassani M, Taylor LT (1988) J Chromatogr Sci 26:33

    Google Scholar 

  25. Ashraf-Khorassani M, Taylor LT (1989) J High Resolut Chromatogr 12:40

    Article  CAS  Google Scholar 

  26. Doehl J, Farbrot A, Greibrokk T, Iversen B (1987) J Chromatogr 392:175

    Article  CAS  Google Scholar 

  27. Jinno K, Niimi S (1988) J Chromatogr 455:29

    Article  CAS  Google Scholar 

  28. Evans MB, Smith MS, Oxford JM (1989) J Chromatogr 379:170

    Article  Google Scholar 

  29. Hirata Y (1984) J Chromatogr 315:31, 39

    Article  CAS  Google Scholar 

  30. Schmitz FP, Leyendecker D, Leyendecker D (1987) J Chromatogr 389:245

    Article  CAS  Google Scholar 

  31. Geiser FO, Yocklovich SG, Lurcott SM, Guthrie JW, Levy EJ (1988) J Chromatogr 459:173

    Article  CAS  Google Scholar 

  32. Engelhardt H, Gross A, Mertens R, Petersen M (1989) J Chromatogr 477:169

    Article  CAS  Google Scholar 

  33. Schwartz HE, Barthel PJ, Moring SE, Yates TL, Lauer HH (1988) Fresenius’ Z Anal Chem 330:204

    Article  CAS  Google Scholar 

  34. Blilie AL, Greibrokk T (1985) Anal Chem 57:2239

    Article  CAS  Google Scholar 

  35. Janicot JL, Caude M, Rosset R (1988) J Chromatogr 437:351

    Article  CAS  Google Scholar 

  36. Saunders CW, Taylor LT (1989) Chromatographia 28:253

    Article  CAS  Google Scholar 

  37. Ashraf-Khorassani M, Taylor LT, Henry RA (1988) Anal Chem 60:1529

    Article  CAS  Google Scholar 

  38. Keystone Scientific Newsletter Vol 2, nos 2 (1989)

    Google Scholar 

  39. Morin P, Caude M, Rosset R (1987) J Chromatogr 407:87

    Article  CAS  Google Scholar 

  40. Smith RM, Sanagi MM (1989) J Chromatogr 481:63

    Article  CAS  Google Scholar 

  41. Gemmel B, Lorenschat B, Schmitz FP (1989) Chromatographia 27:605

    Article  CAS  Google Scholar 

  42. Mourier PA, Eliot E, Caude MH, Rosset RH, Tambute AG (1985) Anal Chem 57:2819

    Article  CAS  Google Scholar 

  43. Hara S, Dobashi A, Hondo T, Saito M, Senda M (1986) J High Resolut Chromatogr 9:249

    Article  CAS  Google Scholar 

  44. Macaudiere P, Caude M, Rosset R, Tambute A (1989) J Chromatogr Sci 27:383

    CAS  Google Scholar 

  45. Macaudiere P, Caude M, Rosset R, Tambute A (1989) J Chromatogr Sci 27:583

    CAS  Google Scholar 

  46. Dobashi A, Dobashi Y, Ono T, Hara S, Saito M, Higashidate S, Yamauchi Y (1989) J Chromatogr 461:121

    Article  CAS  Google Scholar 

  47. Poole CF, Furton KG, Kersten BR (1986) J Chromatogr Sci 24:400

    CAS  Google Scholar 

  48. Kersten BR, Poole SK, Poole CF (1989) J Chromatogr 468:235

    Article  Google Scholar 

  49. Furton KG, Poole SK, Poole CF (1987) Anal Chim Acta 192:49

    Article  CAS  Google Scholar 

  50. Dean TA, Poole CF (1989) J High Resolut Chromatogr 12:773

    Article  CAS  Google Scholar 

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Authors
  1. Colin F. Poole
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  2. John W. Oudsema
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  3. Thomas A. Dean
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  4. Salwa K. Poole
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Editor information

Editors and Affiliations

  1. Fachbereich 8, Analytische Chemie I, Universität-GH Siegen, Adolf-Reichwein-Straße, W-5900, Siegen, Germany

    Bernd Wenclawiak

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© 1992 Springer-Verlag Berlin Heidelberg

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Poole, C.F., Oudsema, J.W., Dean, T.A., Poole, S.K. (1992). Stationary Phases for Packed Column Supercritical Fluid Chromatography. In: Wenclawiak, B. (eds) Analysis with Supercritical Fluids: Extraction and Chromatography. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-77474-4_7

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  • DOI: https://doi.org/10.1007/978-3-642-77474-4_7

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-77476-8

  • Online ISBN: 978-3-642-77474-4

  • eBook Packages: Springer Book Archive

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