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Long Mean Free Path Coherent Transport in Doped Polyacetylene

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Electronic Properties of Conjugated Polymers

Part of the book series: Springer Series in Solid-State Sciences ((SSSOL,volume 76))

Abstract

A modified technique has been used to synthesize stretch oriented polyacetylene with fewer sp3 defects than in material prepared by other methods. The higher quality material exhibits substantially higher electrical conductivity. The data indicate a long electronic mean free path consistent with coherent metallic transport.

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References

  1. For reviews, see the following

    Google Scholar 

  2. Handbook of Conducting Polymers, ed. Skotheim, T.J. (Marcel Dekker, Inc., NY, 1986).

    Google Scholar 

  3. Etemad, S., Heeger, A.J. and MacDiarmid, A.G., Ann. Rev. Phys. Chem. 33, 443 (1982).

    Article  CAS  Google Scholar 

  4. Gould, CM., Bates, D.M., Bozler, H.M., Heeger, A.J., Druy, M.A., and MacDiarmid, A.G.; Phys. Rev B23, 6820 (1981).

    Google Scholar 

  5. Shirakawa, H. and Ikeda, S.; Synth. Met. 1, 175 (1980).

    Article  CAS  Google Scholar 

  6. Naarmann, H., Proc. of ICSM 86, Synth. Met. (to be published).

    Google Scholar 

  7. Catalyst: 31 ml AI(C2H5)3 and 41 ml Ti(C4H9O)4 in 50 ml silicone oil (Wacker).

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  8. Elemental analysis: C, 91.7–92.2%; H, 7.6–7.7%; O, <0.5%; Al/Ti. 0.01%.

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  9. Three hours in toluene followed by sixteen hours in methanol containing 6% HCl and finally two periods of 1–1.5 hours each with methanol.

    Google Scholar 

  10. H. Naarmann, Symposium on “Conducting Polymers: Their Emergence and Future”; American Chemical Society Meeting, Denver, Colorado; April 8 and 9, 1987.

    Google Scholar 

  11. S. Kivelson and A.J. Heeger, Phys. Rev. Lett. 55, 308 (1985).

    Article  CAS  Google Scholar 

  12. E. J. Mele and M.J. Rice, Phys. Rev. B 23. 5397 (1981).

    CAS  Google Scholar 

  13. P. M. Grant and I. Batra, J. Phys. (Paris) Colloq. 44, C3–4377, (1983).

    Google Scholar 

  14. G. Fink and G. Leising, Phys. Rev. B 34 (1986).

    Google Scholar 

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© 1987 Springer-Verlag Berlin Heidelberg

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Basescu, N., Liu, ZX., Moses, D., Heeger, A.J., Naarmann, H., Theophilou, N. (1987). Long Mean Free Path Coherent Transport in Doped Polyacetylene. In: Kuzmany, H., Mehring, M., Roth, S. (eds) Electronic Properties of Conjugated Polymers. Springer Series in Solid-State Sciences, vol 76. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-83284-0_3

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  • DOI: https://doi.org/10.1007/978-3-642-83284-0_3

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-83286-4

  • Online ISBN: 978-3-642-83284-0

  • eBook Packages: Springer Book Archive

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