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Surface Enhanced Second Harmonic Generation from Metals

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Nonlinear Optics in Solids

Part of the book series: Springer Series on Wave Phenomena ((SSWAV,volume 9))

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Abstract

Second Harmonic Generation (SHG) at a metallic surface was first reported by F. Brown et al. [1] in 1965. At the same time, Jha [2] established that this phenomenon is a surface effect. Indeed, in bulk centrosymmetric media, even order nonlinear (NL) effects, in particular SHG, are forbidden. However, there is, by geometry, a break of the symmetry at the surface. The second harmonic (SH) signal is generated because of the discontinuities occurring at the surface. A second source term is due to the decay of the pump field in the medium. These initial ideas are well described in a famous paper by Bloembergen et al. [3] published in 1968.

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References

  1. F. Brown, R.E. Parks, A.M. Sleeper, Phys. Rev. 14, 1029 (1965)

    ADS  Google Scholar 

  2. S.S. Jha, Phys. Rev. Lett. 15, 412 (1965)

    Article  ADS  Google Scholar 

  3. N. Bloembergen, R. Chang, S. Jha, C. Lee, Phys. Rev. 174, 813 (1968)

    Article  ADS  Google Scholar 

  4. H.J. Simon, D.E. Mitchell, J.G. Watson, Phys. Rev. Lett. 33, 1531 (1974)

    Article  ADS  Google Scholar 

  5. E. Kretschmann, H. Raether, Z. Naturforsch. 23a, 2135 (1968)

    Google Scholar 

  6. J.M. Chen, J.R. Bower, C. Wang, C.H. Lee, Opt. Commun. 9, 132 (1973)

    Article  ADS  Google Scholar 

  7. M. Fleischmann, P.J. Rendra, A.J. McMillan, Chem. Phys. Lett. 26, 163 (1974)

    Article  ADS  Google Scholar 

  8. M. Moskovitz, Rev. Mod. Phys. 53, 783 (1985)

    Article  ADS  Google Scholar 

  9. D. Ricard, Ann. Phys. Fr. 8, 273 (1983)

    Google Scholar 

  10. C.K. Chen, A.R.B. de Castro,Y.R. Shen, Phys. Rev. Lett. 46, 145 (1981)

    Article  ADS  Google Scholar 

  11. J.L. Coutaz, M. Nevière, E. Pic, R. Reinisch, Phys. Rev. B32, 2227 (1985)

    Article  ADS  Google Scholar 

  12. Y.R. Shen, Nature 337, 519 (1989)

    Article  ADS  Google Scholar 

  13. O. Keller, in Nonlinear Optics in Solids, edited by O. Keller, Springer-Verlag, Berlin (1989)

    Google Scholar 

  14. D. Maystre, M. Nevière, R. Reinisch, Appl. Phys. A39, 115 (1986)

    Article  Google Scholar 

  15. R. Reinisch, M. Nevière, A. Akhouayri, J.L. Coutaz, D. Maystre, E. Pic, Opt. Engineering 27, 961 (1988)

    Google Scholar 

  16. J.E. Sipe, G.I. Stegeman, in Surface Polaritons, edited by V.M. Agranovich and A.A Maradudin, North Holland, Amsterdam (1982)

    Google Scholar 

  17. P. Guyot-Sionnest, W. Chen, Y.R. Shen, Phys. Rev. B33, 8254 (1986)

    Article  ADS  Google Scholar 

  18. P. Guyot-Sionnest, Y.R. Shen, Phys. Rev. B38, 7985 (1988)

    Article  ADS  Google Scholar 

  19. Y.R. Shen, The Principles of Nonlinear Optics, Wiley Interscience, New-York (1984)

    Google Scholar 

  20. J.E. Sipe, D.T. Moss, H. M. van Driel, Phys. Rev. B35, 1129 (1987)

    Article  ADS  Google Scholar 

  21. J.E. Sipe, V. Mizrahi, G.I. Stegeman, Phys. Rev. B35, 9091 (1987)

    Article  ADS  Google Scholar 

  22. H. Sonnenberg, H. Heffner, J. Opt. Soc. Am. 58, 209 (1968)

    Google Scholar 

  23. J.L. Coutaz, D. Maystre, M. Nevière, R. Reinisch, J. Appl. Phys. 62, 1529 (1987)

    Article  ADS  Google Scholar 

  24. J.C. Quail, H.J. Simon, Phys. Rev. B31, 4900 (1985)

    Article  ADS  Google Scholar 

  25. W. Zheng, L. Li, S. Dong, Z. Zhang, paper ThA4, IQEC, Tokyo (1988)

    Google Scholar 

  26. J. Rudnick, E.A. Stern, Phys. Rev. B4, 4274 (1971)

    Article  ADS  Google Scholar 

  27. J.E. Sipe, V. So, M. Fukui, G.I. Stegeman, Phys. Rev. B21, 4389 (1980)

    Article  ADS  Google Scholar 

  28. M. Corvi, W.L. Schaich, Phys. Rev. B33, 3688 (1986)

    MathSciNet  ADS  Google Scholar 

  29. M.G. Weber, A. Liebsch, Phys. Rev. B35, 7411 (1987)

    Article  ADS  Google Scholar 

  30. A. Liebsch, Phys. Rev. Lett. 61, 1233 (1988)

    Article  ADS  Google Scholar 

  31. A. Chizmeshya, E. Zaremba, Phys. Rev. B37, 2805 (1988)

    MathSciNet  ADS  Google Scholar 

  32. K.J. Song, E.W. Plummer (unpublished) cited in [34]

    Google Scholar 

  33. M.G. Weber, A. Liebsch, Phys. Rev. B36, 6411 (1987)

    Article  ADS  Google Scholar 

  34. B.N.J. Persson, L.H. Dubois, Phys. Rev. B39, 8220 (1989)

    Article  ADS  Google Scholar 

  35. H.W.K. Tom, C.M. Mate, X.D. Zhu, J.E. Crowell, Y.R. Shen, G.A. Somorjai, Surf. Sci. 172, 466 (1986)

    Article  ADS  Google Scholar 

  36. K.J. Song, D. Heskett, H.L. Dai, A. Liebsch, E.W. Plummer, Phys. Rev. Lett. 61, 1380 (1988)

    Article  ADS  Google Scholar 

  37. H. Raether, Excitation of Plasmons and Interband Transitions by Electrons, Springer Verlag, Berlin (1980)

    Google Scholar 

  38. Electromagnetic Surface Modes, edited by A. D. Boardman, Wiley-Interscience, New-York (1982)

    Google Scholar 

  39. Surface Polaritons, edited by V.M. Agranovich and A.A. Maradudin, North Holland, Amsterdam (1982)

    Google Scholar 

  40. A. Otto, Z. Physik 216, 398 (1968)

    Article  ADS  Google Scholar 

  41. D. Sarid, Phys. Rev. Lett. 47, 1927 (1981)

    Article  ADS  Google Scholar 

  42. See for example chapter 13 of M. Born and E. Wolf, Principles of Optics, Pergamon Press, Oxford (1964)

    Google Scholar 

  43. M.C. Hutley, Diffraction Gratings, Academic Press, London (1982)

    Google Scholar 

  44. Electromagnetic Theory of Gratings, edited by R. Petit, Springer-Verlag, Berlin (1980)

    Google Scholar 

  45. D. Maystre, in Progress in Optics XXI, edited by E. Wolf, Elsevier, Amsterdam (1986)

    Google Scholar 

  46. D. Maystre, M. Nevière, R. Reinisch, J.L. Coutaz, J. Opt. Soc. Am. B5, 338 (1988)

    Google Scholar 

  47. M.C. Hutley, D. Maystre, Opt. Commun. 19, 431 (1976)

    Article  ADS  Google Scholar 

  48. See for example F. Abelcs, in Electromagnetic Surface Excitations, edited by R.F. Wallis and G.I. Stegeman, Springer-Verlag, Berlin (1986)

    Google Scholar 

  49. M.A. Ordal, L. Long, R.J. Bell, S. Bell, R.R. Bell, R.W. Alexander, C.A. Ward, Appl. Opt. 22, 1099 (1983)

    Article  ADS  Google Scholar 

  50. H.J. Simon, R.E. Brenner, J.G. Rako, Opt. Commun. 23, 245 (1977)

    Article  ADS  MATH  Google Scholar 

  51. J.G. Rako, J.C. Quail, H.J. Simon, Phys. Rev. B30, 5552 (1984)

    Article  ADS  Google Scholar 

  52. Z. Chen, W. Wang, G. Wang, Z. Zhang, Kexue Tongbao 29, 1160 (1984)

    Google Scholar 

  53. F. De Martini, P. Ristori, E. Santamato, A.C.A. Zammit, Phys. Rev. B23, 3797 (1980)

    Google Scholar 

  54. J. Quail, J. Rako, H.J. Simon, R. Deck, Phys. Rev. Lett. 50, 1987 (1983)

    Google Scholar 

  55. J.C. Quail, H.J. Simon, J. Opt. Soc. Am. B1, 317 (1984)

    Google Scholar 

  56. J.C. Quail, H.J. Simon, J. Appl. Phys. 56, 2589 (1984)

    Article  ADS  Google Scholar 

  57. M.G. Weber, Phys. Rev. B33, 6775 (1986)

    Article  ADS  Google Scholar 

  58. G.I. Stegeman, J.J. Burke, D.G. Hall, Appl. Phys. Lett. 41, 906 (1982)

    Article  ADS  Google Scholar 

  59. R.T. Deck, D. Sarid, J. Opt. Soc. Am. 72, 1613 (1982)

    Google Scholar 

  60. G.I. Stegeman, C. Liao, C. Karaguleff, Opt. Commun. 46, 253 (1983)

    Article  ADS  Google Scholar 

  61. Y.J. Chen, E. Burstein, Nuovo Cimento 39B, 807 (1977)

    Article  ADS  Google Scholar 

  62. M. Fukui, V.C.Y. So, J.E. Sipe, G.I. Stegeman, J. Phys. Chem. Solids 40, 523 (1979)

    Article  ADS  Google Scholar 

  63. C.K. Chen, A.R.B. de Castro,Y.R. Shen, Opt. Lett. 4, 393 (1979)

    Article  ADS  Google Scholar 

  64. K. Sasaki, H. Kawagishi, Y. Ishijima, Appl. Phys. Lett. 47, 783 (1985)

    Article  ADS  Google Scholar 

  65. R. Reinisch, G. Chartier, M. Nevière, M.C. Hutley, G. Clauss, J.P. Galaup, J.F. Eloy, J. Phys. (Paris) 44, L1007 (1983)

    Article  Google Scholar 

  66. J.L. Coutaz, J. Opt. Soc. Am B4, 105 (1987)

    Google Scholar 

  67. J.C. Quail, H.J. Simon, J. Opt. Soc. Am B5, 325 (1988)

    Google Scholar 

  68. H.J. Simon, C. Huang, J.C. Quail, Z. Chen, Phys. Rev. 1138, 7408 (1988)

    Google Scholar 

  69. Z. Chen, H.J. Simon, Opt. Lett. 13, 1008 (1988)

    Article  ADS  Google Scholar 

  70. H.J. Simon, Z. Chen, Phys. Rev. B39, 3077 (1989)

    Article  ADS  Google Scholar 

  71. Z. Chen, D. Cui, H. Lu, Y. Zhou, Opt. Lett. 8, 563 (1983)

    Article  ADS  Google Scholar 

  72. Z. Chen, D. Cui, Y. Zhou, H. Lu, G. Yang, S. Gu, Appl. Phys. Lett. 51, 1301 (1987)

    Article  ADS  Google Scholar 

  73. D. Cui, Z. Chen, Y. Zhou, H. Lu, G. Yang, S. Gu, Physica Scripta 37, 746 (1988)

    Article  Google Scholar 

  74. A. Wokaun, J.G. Bergman, J.P. Heritage, A.M. Glass, P.F. Liao, D.H. Olson, Phys. Rev. B24, 849 (1981)

    ADS  Google Scholar 

  75. G.S. Agarwal, S.S. Jha, Solid State Comm. 41, 499 (1982)

    Article  ADS  Google Scholar 

  76. G.S. Agarwal, S.S. Jha, Phys. Rev. 1126, 482 (1982)

    Google Scholar 

  77. R. Reinisch, M. Nevière, Phys. Rev. B28, 1870 (1983)

    Article  MathSciNet  ADS  Google Scholar 

  78. M. Nevière, R. Reinisch, D. Maystre, Phys. Rev. B32, 3634 (1985)

    Article  ADS  Google Scholar 

  79. M. Nevière, P. Vincent, D. Maystre, R. Reinisch, J.L. Coutaz, J. Opt. Soc. Am. 115, 330 (1988)

    Google Scholar 

  80. G.A. Farias, A.A. Maradudin, Phys. Rev. B30, 3002 (1984)

    Article  ADS  Google Scholar 

  81. J.E. Gersten, A. Nitzan, J. Chem. Phys. 73, 3023 (1980)

    Article  ADS  Google Scholar 

  82. Surface Enhanced Raman Scattering,edited by R.K. Chang and T.E. Furtak, Plenum Press, New York (1982)

    Google Scholar 

  83. S. Ushioda, A. Aziza, J.B. Valdez, G. Mattei, Phys. Rev. B19, 4012 (1979)

    Article  ADS  Google Scholar 

  84. A.M. Glass, A. Wokaun, J.P. Heritage, J.G. Bergman, P.F. Liao, D.H. Olson, Phys. Rev. B24, 4906 (1981)

    Article  ADS  Google Scholar 

  85. J.P. Heritage, J.G. Bergman, Opt. Commun. 35, 373 (1980)

    Article  ADS  Google Scholar 

  86. E.C. Stoner, Philos. Mag. 36, 803 (1945)

    Google Scholar 

  87. P.F. Liao, A. Wokaun, J. Chem. Phys. 76, 751 (1982)

    Article  ADS  Google Scholar 

  88. C.K. Chen, T. Heinz, D. Ricard, Y.R. Shen, Phys. Rev. B27, 1965 (1983)

    Article  ADS  Google Scholar 

  89. G.T. Boyd, Th. Rasing, J.R. Leite, Y.R. Shen, Phys. Rev. B30, 519 (1984)

    Article  ADS  Google Scholar 

  90. See.for example R.K. Chang and B.L. Laube, CRC Critical Rev. Sol. State Mat. Sci. 12 1(1984)

    Google Scholar 

  91. K. Arya, Phys. Rev. B29, 4451 (1984)

    Article  ADS  Google Scholar 

  92. R.T. Deck, R.K. Grygier, Appl. Opt. 23, 3202 (1984)

    Article  ADS  Google Scholar 

  93. A.A. Maradudin, D.L. Mills, Phys. Rev. B11, 1392 (1975)

    Article  ADS  Google Scholar 

  94. D.V. Murphy, K.U. Von Raben, T.T. Chen, J.F. Owen, R.K. Chang, Surf. Sci. 124, 529 (1983)

    Article  ADS  Google Scholar 

  95. V.E. Albano, S. Daiser, G. Entl, R. Miranda, K. Wandelt, N. Garcia, Phys. Rev. Lett. 51, 2314 (1983)

    Article  ADS  Google Scholar 

  96. H. Seki, T.J. Chuang, Chem. Phys. Lett. 100, 393 (1983)

    Article  ADS  Google Scholar 

  97. O.A. Aktsipetrov, E.M. Dubinina, S.S. Elovikov, D.A. Esikov, E.D. Mishina, N.N. Fominykh, JETP Lett. 44, 475 (1986)

    ADS  Google Scholar 

  98. O.A. Aktsipetrov, S.I. Vasilev, V.Panov, Soy. Phys. JETP 67, 1010 (1988)

    Google Scholar 

  99. C.K. Chen, T. Heinz, D. Ricard, Y. Shen, Phys. Rev. Lett 46, 1010 (1981)

    Article  ADS  Google Scholar 

  100. O.A. Aktsipetrov, V.Y. Bartenev, E.D. Mishina, A.V. Petukhov, Sov. J. Quantum Electron. 13, 712 (1983)

    Article  ADS  Google Scholar 

  101. G.L. Richmond, Surf. Sci. 147, 115 (1984)

    Article  ADS  Google Scholar 

  102. Y. R. Shen, J. Vac. Sci. Technol. B3, 1464 (1985)

    Google Scholar 

  103. J.G. Bergman, D.S. Chemla, P.F. Liao, A.M. Glass, A. Pinczuk, R. M. Hart, D.H. Olson, Opt. Lett. 6, 33 (1981)

    Article  ADS  Google Scholar 

  104. O.A. Aktsipetrov, I.M. Baranova, E.D. Mishina, A.V. Petukhov, JETP Lett. 40, 1012 (1984)

    ADS  Google Scholar 

  105. A.A. Golubtsov, N.F. Pilipetskii, A.N. Sudarkin, V.V. Shelepenko, V.V. Yakimenko, JETP Lett. 43, 277 (1986)

    ADS  Google Scholar 

  106. G.T. Boyd, Y.R. Shen, T.W. Hansch, Opt. Lett. 11, 97 (1986)

    Article  ADS  Google Scholar 

  107. D. Maystre, Opt. Commun. 6, 50 (1972)

    Article  ADS  Google Scholar 

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Coutaz, JL. (1990). Surface Enhanced Second Harmonic Generation from Metals. In: Keller, O. (eds) Nonlinear Optics in Solids. Springer Series on Wave Phenomena, vol 9. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-84206-1_5

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  • DOI: https://doi.org/10.1007/978-3-642-84206-1_5

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