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Photoluminescence of Zinc-Sulfo-Selenide Single Crystals Grown by Sublimation Method

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Electroluminescence

Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 38))

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Abstract

Zinc-sulfo-selenide (ZnSex S1–x) single crystals which can be used in blue luminescent devices are prepared by sublimation method and their photoluminescence spectra are measured. Free exciton luminescence is very weak; but, the bound exciton emissions are very pronounced indicating the presence of substitutional impurities in the form of neutral donors and acceptors. The incorporation of Na or Li is observed to enhance donor-acceptor pair transitions where the DAP band of the Na-doped sample is at 12 meV higher energy than the DAP band of the Li-doped sample. The energies of the luminescence transitions decrease curvilinearly with the increasing ZnSe composition x (0.80≤x≤1).

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References

  1. P.J. Dean and J.L. Merz: Phys. Rev. 178, 1310 (1969).

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  2. J.L. Merz, K. Nassau, and J.W. Shiever: Phys. Rev. 88, 1444 (1972).

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Author information

Authors and Affiliations

  1. College of Liberal Arts and Sciences, Okayama University, Okayama 700, Japan

    S. R. Tiong, M. Hiramatsu & Y. Matsushima

  2. Department of Applied Physics, Okayama University of Science, Okayama 700, Japan

    M. Ohishi, K. Ohmori & H. Saito

Authors
  1. S. R. Tiong
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  2. M. Hiramatsu
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  3. Y. Matsushima
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  4. M. Ohishi
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  5. K. Ohmori
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  6. H. Saito
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Editor information

Editors and Affiliations

  1. Department of Electronics, Tokyo Engineering University, 1404 Katakura, Hachioji, Tokyo 192, Japan

    Shigeo Shionoya Ph.D.

  2. Department of Electronics, Tottori University, Koyama, Tottori 680, Japan

    Hiroshi Kobayashi Ph.D.

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© 1989 Springer-Verlag Berlin, Heidelberg

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Tiong, S.R., Hiramatsu, M., Matsushima, Y., Ohishi, M., Ohmori, K., Saito, H. (1989). Photoluminescence of Zinc-Sulfo-Selenide Single Crystals Grown by Sublimation Method. In: Shionoya, S., Kobayashi, H. (eds) Electroluminescence. Springer Proceedings in Physics, vol 38. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-93430-8_22

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  • DOI: https://doi.org/10.1007/978-3-642-93430-8_22

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-93432-2

  • Online ISBN: 978-3-642-93430-8

  • eBook Packages: Springer Book Archive

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