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Metallasilsesquioxanes: Molecular Analogues of Heterogeneous Catalysts

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Applications of Polyhedral Oligomeric Silsesquioxanes

Part of the book series: Advances in Silicon Science ((ADSS,volume 3))

Abstract

As soluble molecular analogues of silica surfaces, polyhedral oligosilsesquioxanes (POS or POSS®) have been used extensively, along with alkylsilanols, to mimic the structure and chemistry of silica surfaces (Figure 3.1).

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Authors and Affiliations

  1. Laboratory of Advanced Catalysis for Sustainability, School of Chemistry F11, University of Sydney, Sydney, New South Wales, Australia

    Antony J. Ward, Anthony F. Masters & Thomas Maschmeyer

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  1. Antony J. Ward
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  2. Anthony F. Masters
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  3. Thomas Maschmeyer
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Correspondence to Thomas Maschmeyer .

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Editors and Affiliations

  1. Michigan Molecular Institute, W. Saint Andrews Rd. 1910, Midland, 48640, Michigan, USA

    Claire Hartmann-Thompson

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Ward, A.J., Masters, A.F., Maschmeyer, T. (2011). Metallasilsesquioxanes: Molecular Analogues of Heterogeneous Catalysts. In: Hartmann-Thompson, C. (eds) Applications of Polyhedral Oligomeric Silsesquioxanes. Advances in Silicon Science, vol 3. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-3787-9_3

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