Abstract
The role of activation/termination sequences on the efficiency of electron transfer chain catalysis is discussed and illustrated by two examples related to transition metal catalysis of organic reactions.
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References
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The proximity of a negative charge, should enhance the lability of the α CH bond as observed e.g. for alcoolates: C. Amatore, J. Badoz-Lambling, C. Bonnel-Huyghes, J. Pinson, J.M. Savéant and A. Thiébault, J. Am. Chem. Soc., 104, 1982, 1979.
See: I. Colon and D.R. Kelsey, J. Org. Chem., 51, 1986, 2627, for a detailled presentation of the reaction and of the pertinent references.
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Compare with ref.15.
This phenomenon is similar to “Redox Catalysis” in terms of kinetic behavior. Compare: (a) R.S. Nicholson and I. Shain, Anal. Chem., 36, 1964, 706
C.P. Andrieux, C. Blocman, J.M. Dumas-Bouchiat, F. M’Halla and J.M. Savéant, J. Am. Chem. Soc., 102, 1980, 3806, and refs. therein.
All three effects are observed by Colon and Kelsey. Compare figs. 1–4 in ref.14.
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© 1989 Kluwer Academic Publishers
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Amatore, C., Jutand, A., Verpeaux, J.N. (1989). Role of Termination Steps on the Efficiency of Electron Transfer Chain Catalysis. In: Chanon, M., Julliard, M., Poite, J.C. (eds) Paramagnetic Organometallic Species in Activation/Selectivity, Catalysis. NATO ASI Series, vol 257. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0877-2_15
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DOI: https://doi.org/10.1007/978-94-009-0877-2_15
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