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Desorption by Resonant Laser-Adsorbate Vibrational Coupling

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Dynamics on Surfaces

Part of the book series: The Jerusalem Symposia on Quantum Chemistry and Biochemistry ((JSQC,volume 17))

Abstract

Features of the desorption induced by resonant laser-adsorbate vibrational interaction on ionic crystal, semiconductor and metal surfaces are reviewed. The description of the multiphoton excitation process is founded on quantum level schemes and stepwise incoherent transitions. Rate equations express the basic mechanism and relate the desorption rate and yield to the intensity, the duration of the laser-surface interaction, and to spectral and thermal properties of the adsorption system. The potential of adsorbate photochemistry induced by monochromatic infrared pulses of tunable lasers in combination with high resolution linear infrared spectroscopy is indicated for a one-component adsorbate with several phases within a single monolayer.

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Author information

Authors and Affiliations

  1. Institut für Physikalische Chemie und Elektrochemie, Universität Hannover, D-3000, Hannover 1, Germany

    J. Heidberg, H. Stein, Z. Szilágyi, D. Hoge & H. Weiß

Authors
  1. J. Heidberg
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  2. H. Stein
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  3. Z. Szilágyi
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  4. D. Hoge
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  5. H. Weiß
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Editor information

Editors and Affiliations

  1. Fondation Edmond de Rothschild, Institut de Biologie Physico-Chimique, Paris, France

    Bernard Pullman

  2. Department of Chemistry, University of Tel Aviv, Israel

    Joshua Jortner  & Abraham Nitzan  & 

  3. Department of Physical Chemistry, The Hebrew University, Jerusalem, Israel

    Benjamin Gerber

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© 1984 D. Reidel Publishing Company

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Heidberg, J., Stein, H., Szilágyi, Z., Hoge, D., Weiß, H. (1984). Desorption by Resonant Laser-Adsorbate Vibrational Coupling. In: Pullman, B., Jortner, J., Nitzan, A., Gerber, B. (eds) Dynamics on Surfaces. The Jerusalem Symposia on Quantum Chemistry and Biochemistry, vol 17. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-5237-9_25

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  • DOI: https://doi.org/10.1007/978-94-009-5237-9_25

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-8815-2

  • Online ISBN: 978-94-009-5237-9

  • eBook Packages: Springer Book Archive

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