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Interfaces and Physical Properties of Nanostructured Solids

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Mechanical Properties and Deformation Behavior of Materials Having Ultra-Fine Microstructures

Part of the book series: NATO ASI Series ((NSSE,volume 233))

Abstract

In nanostructured solids (crystallite size ca. 10 nm) the physical properties are strongly modified by the disordered structure of the interfaces. A combination of microscopic and macroscopic studies is therefore of pivotal interest.

In this paper a review is given on studying the atomic structure of interfaces in nanocrystalline solids by nuclear probes such as positrons and muons. Highly compressible free volumes of the size of interfacial vacancies and of nanovoids in the triple junctions are detected as structural elements of the elastically soft interfaces which exhibit a width of the structural and the magnetic perturbations of 3 to 4 atoms. The interfacial structure substantially relaxes prior to crystallite growth.

As examples for macroscopic studies He desorption and magnetic properties of nanocrystalline metals are discussed. He desorption occurs at much lower temperatures than in coarse-grained metals and is impeded after interfacial relaxation. In the interfaces of n-Ni the Curie temperature and the magnetic moment per atom are reduced due to the open disordered structure.

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References

  1. H. Gleiter in Deformation of Polycrystals: Mechanisms and Microstructures eds. N. Hansen et al., Roskilde: Risk Nat. Laboratory 1981, p.15

    Google Scholar 

  2. H. Gleiter and P. Marquardt, Z. Metallkunde 75, 263 (1984)

    CAS  Google Scholar 

  3. V.N. Lapovok, V.I. Novikov, S.V. Svirida, A.N. Seminikin, and L.I. Trusov, Sov. Phys. Solid State 25, 1063 (1983)

    Google Scholar 

  4. R. Birringer, U. Herr, and H. Gleiter, Trans. Jap. Inst. Met. Suppl. 27 43 (1986)

    Google Scholar 

  5. R.W. Siegel and H. Hahn, in Current Trends in the Physics of Materials, eds. M. Yussouff, World Scientific Singapore 1987, p.403

    Google Scholar 

  6. H.-E. Schaefer, R. Würschum, R. Birringer, and H. Gleiter, Physical Research Vol.8, ed. K. Hennig, Akademie-Verlag, Berlin 1988, p.580

    Google Scholar 

  7. H. Gleiter, Progress in Materials Science 33 233 (1989)

    Article  Google Scholar 

  8. R.W. Siegel, Annu. Rev. Mat. Sci. 21 559 (1991)

    Article  CAS  Google Scholar 

  9. X. Zhu, R. Birringer, U. Herr, and H. Gleiter, Phys. Rev. 35 9085 (1987)

    Article  CAS  Google Scholar 

  10. T. Haubold, R. Birringer, B. Lengeler and H. Gleiter, J. Less-Common Metals 145 557 (1988)

    Article  CAS  Google Scholar 

  11. E. Soininen, H. Huomo, P.A. Huttunen, J. Mäkinen, A. Vehanen, and P. Hautojärvi, Phys. Rev. B41 6227 (1990)

    Google Scholar 

  12. H.-E. Schaefer, phys.stat.sol.(a) 102 47 (1987)

    Article  CAS  Google Scholar 

  13. -E. Schaefer, R. Würschum, and J. Bub, Mat. Sci. Forum 105–110 439 (1992)

    Article  CAS  Google Scholar 

  14. R. Würschum, W. Bauer, K. Maier, A. Seeger, and H.-E. Schaefer, J. Phys.: Condens. Matter 1 SA33 (1989)

    Article  Google Scholar 

  15. M. Forster, W. Claudy, H. Hermes, M. Koch, K. Maier, J. Major, H. Stoll, and H.-E. Schaefer, Mat. Sci. Forum, 105–110 1005 (1992).

    Article  CAS  Google Scholar 

  16. M. Forster, Dissertation Stuttgart University 1991

    Google Scholar 

  17. M.J. Puska and R.M. Nieminen, J. Phys. F13 333 (1983)

    Article  Google Scholar 

  18. M.J. Puska and C. Corbell, Phys. Rev. B38 9874 (1988)

    Google Scholar 

  19. R. Würschum, Dissertation Stuttgart University 1988

    Google Scholar 

  20. R. Würschum, W. Greiner, G. Soyez, and H.-E. Schaefer, Mat. Sci. Forum, 105–110 1337 (1992)

    Article  Google Scholar 

  21. H.-E. Schaefer, R. Würschum, R. Birringer, and H. Gleiter, Phys. Rev. B38, 9545 (1988)

    Google Scholar 

  22. R. Würschum, M. Scheytt, and H.-E. Schaefer, phys.stat.sol.(a) 102, 119 (1987)

    Article  Google Scholar 

  23. H.-E. Schaefer, W. Eckert, O. Stritzke, R. Würschum, and W. Templ, in Positron Annihilation,eds. L. Dorikens-Vanpraet, M. Dorikens, and D. Segers, World Scientific Publ., Singapore, 1989, p.79

    Google Scholar 

  24. H.-E. Schaefer in Positron Annihilation, eds. P.G. Coleman, S.C. Sharma, and L.M. Diana, North Holland Publ., Amsterdam, 1982, p.369

    Google Scholar 

  25. R. Würschum, W. Greiner, R.Z. Valiev, M. Rapp, W. Sigle, O. Schneeweiss, and H.-E. Schaefer, Scripta Met.Mater.25, 2451 (1991)

    Article  Google Scholar 

  26. M. Doyama and R.M.J. Cotterill, in Positron Annihilation, R.R. Hasiguti and K. Fujiwara (eds.), Japan Inst. of Metals, Sendai, 1979, p.89

    Google Scholar 

  27. G. Dlubek, O. Brümmer, N. Meyendorf, P. Hautojärvi, A. Vehanen, and J. Yli-Kauppila, J. Phys. F 9 1961 (1979)

    Article  Google Scholar 

  28. B.T.A. McKee, S. Saimoto, A.T. Stewart, and M.J. Stott, Canad. J. Phys. 52, 759 (1974)

    CAS  Google Scholar 

  29. O.K. Alekseeva, V.A. Onishckuk, V.P. Shantarovich, I.Y. Dekhtyar, and V.I. Shevchenko, phys.stat.sol.(b) 95, K135 (1979)

    Article  CAS  Google Scholar 

  30. H.-E. Schaefer and M. Forster, Mat. Sci. Eng. A109 161 (1981)

    Google Scholar 

  31. G. Palumbo, S.J. Thorpe, K.T. Aust, Scripta Metall. Mater. 24 1347 (1990)

    Article  CAS  Google Scholar 

  32. R.Z. Valiev, O.A. Kaibyshev, R.I. Kuznetsova, R.Sh. Musalimov, and N.K. Tsenev, Dokl.Acad.Nauk SSSR 301, 864 (1988) (in Russian); R.Z. Valiev, this conference

    Google Scholar 

  33. A. Vehanen, K.G. Lynn, P.J. Schultz, A.N. Goland, C.L. Snead jr., H.J. Güntherodt and E. Cartier, in Positron Annihilation, eds. P.G. Coleman, S.C. Sharma, and L.M. Diana, (North Holland, Amsterdam, 1982), p.587

    Google Scholar 

  34. N. Shiotani, in [23], p.561

    Google Scholar 

  35. H.-R. Sinning, M.M. Nicolaus, and F. Haeßner, Mat.Sci.Eng.A133,371 (1991)

    CAS  Google Scholar 

  36. M. Hasegawa, O. Yoshinari, H. Matsui, and S. Yamaguchi, J. of Physics: Condensed Matter 1, SA77 (1989)

    Article  CAS  Google Scholar 

  37. R.B. Gregory, J.Appl.Phys.70, 4665 (1991)

    Article  CAS  Google Scholar 

  38. S.S. Gorelik and M.S. Blanter, Russian Metallurgy 2, 79 (1982)

    Google Scholar 

  39. I.K. MacKenzie, P.J. Schultz, and J.A. Jackman, Solid State Commun. 33, 1011 (1989)

    Article  Google Scholar 

  40. W. Eckert, Dissertation, Universität Stuttgart, 1992

    Google Scholar 

  41. ] H. Kisker, R. Würschum, H. Kronmüller, and H.-E. Schaefer, to be published

    Google Scholar 

  42. H. Gleiter, this conference

    Google Scholar 

  43. A. Kumpmann, B. Günther, and 11.-D. Kunze, this conference

    Google Scholar 

  44. R.W. Siegel, this conference

    Google Scholar 

  45. M.J. Mayo, this conference

    Google Scholar 

  46. M. Weller, J. Diehl, and 11.-E. Schaefer, Phil. Mag. A 63, 527 (1991)

    Google Scholar 

  47. C. Landesberger, G. Wallner, and J. Peisl, private communication 1987

    Google Scholar 

  48. J. Rupp and R. Birringer, Phys.Rev.B36, 7888 (1987)

    Google Scholar 

  49. H.-J. Höfler, Dissertation Saarbrücken University 1991

    Google Scholar 

  50. H. Gleiter, phys.stat.sol.(a) 131 (1992), in the press

    Google Scholar 

  51. H.-J. Weber, Diploma Thesis Stuttgart University 1989

    Google Scholar 

  52. A. Seeger and G. Schottky, Acta Metall. 7, 495 (1959)

    Article  CAS  Google Scholar 

  53. L.I. Trusov, Yu.A. Voskresenskii, I.A. Repin, V.I. Novikov, S.V. Svirida, and A.N. Semenikhin, Sov.Phys.Sol.State 29, 1185 (1987)

    Google Scholar 

  54. W. Greiner, Diploma thesis, Stuttgart University 1990

    Google Scholar 

  55. M. Charles, C. Mairy, J. Hillairet, and V. Levy, J.Phys.F6, 979 (1976)

    Article  Google Scholar 

  56. W. Maysenhölder, Dissertation Stuttgart University 1981

    Google Scholar 

  57. W.B. Daniels and C.S. Smiths, Phys.Rev.111, 173 (1958)

    Article  Google Scholar 

  58. S.N. Khanna, B.K. Rao, P. Jena, D. Esterling, and M.J. Puska, Phys.Rev.B37, 6 (1988)

    Google Scholar 

  59. A. Schenk, Muon Spin Rotation Spectroscopy, Adam Hilger Publ., Bristol 1985

    Google Scholar 

  60. T.E.O. Ericson, V.W. Hughes, and D.E. Nagle, The Meson Factories, University of California Press, Berkeley 1991, p.701

    Google Scholar 

  61. A. Seeger, Hyperfine Inter. 17–19 75 (1984)

    Article  Google Scholar 

  62. A. Seeger and P. Monachesi, Phil. Mag. B46 283 (1982)

    Article  Google Scholar 

  63. K.-P. Arnold, C. Baines, K.-P. Döring, K. Förderer, M. Gladisch, D. Herlach, M. Krenke, G. Majer, J. Major, H.-J. Mundinger, J. Rosenkranz, W. Schäfer, L. Schimmele, M. Schmolz, W. Schwarz, and A. Seeger, SIN Newletter 19 NL 91 (1987)

    Google Scholar 

  64. A. Mößlang, H. Graf, G. Balzer, E. Recknagel, A. Weidinger, Th. Wichert, and R.I. Grynszpan, Phys. Rev. B27 2674 (1983)

    Google Scholar 

  65. E. Yagi, G. Flik, K. Förderer, N. Haas, D. Herlach, J. Major, A. Seeger, W. Jakobs, M. Krause, M. Krauth, H.-J. Mundinger, and H. Orth, Phys. Rev. B30 441 (1984)

    Google Scholar 

  66. M. Schmolz, Dissertation Stuttgart University, 1988

    Google Scholar 

  67. W. Wunderlich, R. Maurer, and Y. Ishida, Scripta Metall. Mater. 24 403 (1990)

    Article  CAS  Google Scholar 

  68. S. Schuhmacher, R. Birringer, S. Strauß, and H. Gleiter, Acta Metall. 37, 2485 (1989)

    Article  Google Scholar 

  69. J. Horvath, R. Birringer, and H. Gleiter, Sol.Stat.Comm. 62, 319 (1987)

    Article  CAS  Google Scholar 

  70. T. Mütschele and R. Kirchheim, Scripta Met. 21, 135 (1987)

    Article  Google Scholar 

  71. D.B. Poker and J.M. Williams, Appl.Phys.Lett. 40, 851 (1982)

    Article  CAS  Google Scholar 

  72. M.J. Baskes and C.F. Melius, Phys. Rev. B20 3197 (1979)

    Google Scholar 

  73. W. Schilling in Point Defects and Defect Interaction in Metals, eds. J.I. Takamura, M. Doyama, and M. Kirita.ni, University of Tokyo Press, 1982, p.303

    Google Scholar 

  74. J. Rothaut, H. Schroeder, and H. Ullmaier, Phil. Mag. A47, 781 (1983)

    Article  Google Scholar 

  75. W. Jäger and J. Roth, J. Nucl. Mater. 93–94 756 (1980)

    Article  Google Scholar 

  76. P. Jung and K. Schröder, J. Nucl. Mater. 155–157, 1137 (1988)

    Article  Google Scholar 

  77. R. Pauthenet, J. Appl. Phys. 53 2031 (1982)

    Google Scholar 

  78. E.C. Stoner, Proc. Roy. Soc. A165, 372 (1938)

    Google Scholar 

  79. K. Tamura and H. Endo, Phys. Lett. 29A, 52 (1969)

    Google Scholar 

  80. R. Feder, S.F. Alvarado, E. Tamura, and E. Kisker, Surf. Sci. 127 83 (1983)

    Article  CAS  Google Scholar 

  81. G.A. Mulhollan, A.R. Köymen, D.M. Lind, F.B. Dunning, G.K. Walters, E. Tamura, and R. Feder, Surf. Sci. 204 503 (1988)

    Article  CAS  Google Scholar 

  82. S. Onishi, A.J. Freeman, and M. Weinert, Phys. Rev. B28 6741 (1983)

    Google Scholar 

  83. U. Gradmann, J. Magn. Magn. Mater. 100 481 (1991)

    Article  CAS  Google Scholar 

  84. J. Richter, K. Handrich, and J. Schreiber, phys. stat. sol. (b) 68, K61 (1975)

    Article  Google Scholar 

  85. J. Richter, J. Schreiber, and K. Handrich, phys. stat. sol.(b) 74, K125 (1976)

    Article  Google Scholar 

  86. K.H. Bennemann, J. de Phys. C4, 305 (1974)

    Google Scholar 

  87. J. Geshev, O. Popov, V. Masheva, and M. Mikhov, J. Magn. Magn. Mater. 92, 185 (1990)

    Article  Google Scholar 

  88. W. Wagner, A. Wiedemann, W. Petry, A Geibel, and H. Gleiter, J. Mater. Research 6, 2305 (1991)

    Article  CAS  Google Scholar 

  89. R. Schäfer and A. Hubert, J. Appl. Phys. 69, 5325 (1991)

    Article  Google Scholar 

  90. L. Néel, Comptes Rend. Acad. Sci. Paris 224 1488 (1947)

    Google Scholar 

  91. E. Kneller, Ferromagnetismus, Springer Verlag, Berlin 1962

    Book  Google Scholar 

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Author information

Authors and Affiliations

  1. Institut für Theoretische und Angewandte Physik, Stuttgart University, Pfaffenwaldring 57, D-7000, Stuttgart 80, Germany

    Hans-Eckhardt Schaefer

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  1. Hans-Eckhardt Schaefer
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Editors and Affiliations

  1. Division of Materials Science and Technology, Los Alamos National Laboratory, Los Alamos, New Mexico, USA

    Michael Nastasi

  2. Center for Materials Science, Los Alamos National Laboratory, Los Alamos, New Mexico, USA

    Don M. Parkin

  3. Institut für Neue Materialien, Universität des Saarlandes, Saarbrücken, Germany

    Herbert Gleiter

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Schaefer, HE. (1993). Interfaces and Physical Properties of Nanostructured Solids. In: Nastasi, M., Parkin, D.M., Gleiter, H. (eds) Mechanical Properties and Deformation Behavior of Materials Having Ultra-Fine Microstructures. NATO ASI Series, vol 233. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-1765-4_4

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  • DOI: https://doi.org/10.1007/978-94-011-1765-4_4

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