Abstract
New polymeric thin films containing nonlinear optical chromophores aligned by corona poling for χ (2) experiments have been monitored by spectroscopic and optical waveguiding techniques, as well as by second harmonic generation and electrooptic measurements. Stability has been improved considerably in various crosslinked epoxy polymers by attaching the chromophores at several molecular positions to inhibit relaxation. With increased chromophore concentration and improved alignment, films exhibiting nonlinearities exceeding lithium niobate have now been demonstrated. Several electrooptic phase modulators have been constructed with these new materials and some preliminary results are presented.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Singer, K. D., Lalama, S. L, Sohn, J. E. and Small, R. D. (1987) ‘Electro-Optic Organic Materials’, ‘Nonlinear Optical Properties of Organic Molecules and Crystals’, D. S. Chemla and J. Zyss, (eds.), Academic Press, Orlando, 1, pp. 437–468.
Williams, D. J. (1987) ‘Nonlinear Optical Properties of Guest-Host Polyme Structures’, ‘Nonlinear Optical Properties of Organic Molecules and Crystals’, D. S. Chemla and J. Zyss, (eds.), Academic Press, Orlando, 1, pp. 405–435.
Singer, K. D., Kuzyk, M. G. and Sohn, J. E. (1987) J. Opt. Soc. Am. B4, p. 968.
Eich, M., Sen, A., Looser, H. Bjorklund, G. C., Swalen, J. D., Twieg, R. J. Yoon, D. Y. (1989) J. Appl Phys., 66, p. 2559.
Mortazavi, M. A., Knoesen, A., Kowel, S. T., Higgins, B. G. and Dienes, A. (1989) J. Opt. Soc. Am. B6, p. 733.
Page, R H., Jurich, M. C., Reck, B., Sen, A., Twieg, R. J., Swalen, J. D., Bjorklund, G. C. and Willson. C. G. (1990) J. Opt. Soc. Am. B7, p. 1239.
Eich, M., Reck, B., Yoon, D. Y., Willson, C. G. and Bjorklund, G. C. J. Appl. Phys. 66, p. 3241.
Reck, B., Eich, M., Jungbauer, D., Twieg, R. J., Willson, C. G., Yoon, D. Y. and Bjorklund, G. C. (1989) Proc. SPIE, 1147 p. 74.
Jungbauer, D., Reck, B., Twieg, R. J., Yoon, D. Y., Willson, C. G. and Swalen, J. D. (1990) Appl. Phys. Lett. 56 p. 2610.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1991 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Swalen, J.D. et al. (1991). Poled Epoxy Polymers for Optoelectronics. In: Messier, J., Kajzar, F., Prasad, P. (eds) Organic Molecules for Nonlinear Optics and Photonics. NATO ASI Series, vol 194. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-3370-8_31
Download citation
DOI: https://doi.org/10.1007/978-94-011-3370-8_31
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-5490-4
Online ISBN: 978-94-011-3370-8
eBook Packages: Springer Book Archive