Abstract
Polymers containing highly loosely held electrons in their backbones, often referred to as conjugated polymers or conducting polymers, have attracted much research effort in the last ten years or so. Many investigations were first motivated by the observation that oxidizing or reducing the backbone (doping) of polyacetylene at a level equivalent to removing/adding an electron in one out of every 5–15 repeat units, increased the conductivity of the matrix by many orders of magnitude.1–3 Because the electrons in these delocalized systems are also easily polarized by an external electric field such as that found in light, these types of polymers have also attracted interest for their nonlinear optical properties.4–6 These polymers have also been proposed as “molecular wires” for nanotechnology.7
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References
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Gorman, C.B., Grubbs, R.H. (1991). Conjugated Polymers: The Interplay Between Synthesis, Structure, and Properties. In: Brédas, J.L., Silbey, R. (eds) Conjugated Polymers. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-3476-7_1
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