Abstract
An electron-transfer process is represented in its simplest form as
in which an electron is transferred from the HOMO of the electron donor (D) to the LUMO of the electron acceptor (A) in one single (overall) process. [For simplicity, the electron donor and acceptor are written here as uncharged and diamagnetic, which is not always the case.] The formulation described in equation (1) does not, however, take into account the interaction between A and D over the diminished intermolecular distance in which the electron is transferred. The corresponding interactions between the products (A·− and D·+) must also be considered in a more comprehensive account of the electron-transfer process. Accordingly, Scheme I depicts the interactions between donor and acceptor in terms of the precursor (electron donor-acceptor or EDA)
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Bockman, T.M., Kochi, J.K. (1993). Electron Donor-Acceptor Interactions and Photo-Induced Electron Transfer of Organometallic Compounds. In: Kalyanasundaram, K., Grätzel, M. (eds) Photosensitization and Photocatalysis Using Inorganic and Organometallic Compounds. Catalysis by Metal Complexes, vol 14. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-2626-9_14
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