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Circularly Polarized Luminescence of Chirally Arranged Achiral Organic Luminophores by Covalent and Supramolecular Methods

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Circularly Polarized Luminescence of Isolated Small Organic Molecules

Abstract

Circularly polarized luminescence (CPL) produced by achiral organic luminophores is described. Achiral organic luminophores can exhibit CPL by the chiral arrangement of the achiral luminophores. Chiral arrangement of achiral luminophores can be constructed through a covalently linked chiral spacer like a binaphthyl moiety. A helical supramolecular assembly also provides chiral environment on an achiral luminophore. The helically stacked assemblies of achiral luminophores are excellent for realizing CPL of the achiral luminophore since the highly assembled structure in the helical assembly provides good CPL activity. The stimuli-responsivity of supramolecular systems provides stimuli-responsive CPL.

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Author information

Authors and Affiliations

  1. Department of Chemistry, School of Science, Tokai University, Hiratsuka, Kanagawa, Japan

    Toshiaki Ikeda

  2. Department of Chemistry, Graduate School of Science, Hiroshima University, Hiroshima, Japan

    Takeharu Haino

Authors
  1. Toshiaki Ikeda
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  2. Takeharu Haino
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Correspondence to Takeharu Haino .

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Editors and Affiliations

  1. Osaka University, Suita, Japan

    Tadashi Mori

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Ikeda, T., Haino, T. (2020). Circularly Polarized Luminescence of Chirally Arranged Achiral Organic Luminophores by Covalent and Supramolecular Methods. In: Mori, T. (eds) Circularly Polarized Luminescence of Isolated Small Organic Molecules. Springer, Singapore. https://doi.org/10.1007/978-981-15-2309-0_9

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