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Vapor pressure of phenethyl alcohol in the system with water, and polyoxyethylene, 4, lauryl ether (Brij® 30)

  • Thomas-Graham-Medal
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Interfaces, Surfactants and Colloids in Engineering

Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 101))

Abstract

The phase diagram was determined for the system water, phenethyl alcohol and a commercial surfactant, Laureth 4 (Brij® 30), and the vapor pressure of phenethyl alcohol (PEA) measured in the entire system. The phase diagram showed complete solubility of the surfactant and the phenethyl alcohol with limited solubilization of water. The water was dissolved into the surfactant forming a surfactant solution and a lamellar liquid crystal.

The variation of vapor pressure for the solutions was related to the surfactant self-association and to the formation of inverse micelles. The Henry’s constant was 1.5 for PEA in the surfactant and increased systematically for the different phases to a value of approximately 103 for water.

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Author information

Authors and Affiliations

  1. Center for Advanced Materials Processing, Clarkson University, 13669-5814, Potsdam, New York, USA

    S. E. Friberg, T. Huang, L. Fei & S. A. Vona

  2. ICI Surfactants, 3411 Silverside Road, 19850-5391, Wilmington, Delaware, USA

    P. A. Aikens

Authors
  1. S. E. Friberg
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  2. T. Huang
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  3. L. Fei
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  4. S. A. Vona
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  5. P. A. Aikens
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Editor information

H. -J. Jacobasch

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© 1996 Steinkopff Verlag

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Friberg, S.E., Huang, T., Fei, L., Vona, S.A., Aikens, P.A. (1996). Vapor pressure of phenethyl alcohol in the system with water, and polyoxyethylene, 4, lauryl ether (Brij® 30). In: Jacobasch, H.J. (eds) Interfaces, Surfactants and Colloids in Engineering. Progress in Colloid & Polymer Science, vol 101. Steinkopff. https://doi.org/10.1007/BFb0114439

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  • DOI: https://doi.org/10.1007/BFb0114439

  • Published:

  • Publisher Name: Steinkopff

  • Print ISBN: 978-3-7985-1057-9

  • Online ISBN: 978-3-7985-1664-9

  • eBook Packages: Springer Book Archive

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