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Fluorinated free radicals

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Organofluorine Chemistry

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 192))

Abstract

All aspects of the structure, reactivity and chemistry of fluorine-containing, carbon-based free radicals in solution are presented. The influence of fluorine substituents on the structure, the stability and the electronegativity of free radicals is discussed. The methods of generation of fluorinated radicals are summarized. A critical analysis of the reactivities of perfluoro-n-alkyl, branched chain perfluoroalkyl and partially-fluorinated free radicals towards alkene addition, H-atom abstraction, and towards intramolecular rearrangement reactions is presented. Lastly, a summary of the synthetically-useful chemistry of fluorinated radicals is presented.

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  1. Department of Chemistry, University of Florida, 32611-7200, Gainesville, FL, USA

    William R. Dolbier

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Dolbier, W.R. (1997). Fluorinated free radicals. In: Chambers, R.D. (eds) Organofluorine Chemistry. Topics in Current Chemistry, vol 192. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0119266

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