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Handbook of Nuclear Chemistry

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1 Detection of Particle Induced X-Ray

1.1 Characteristics of the method

Particle Induced X-Ray Emission (PIXE) is a combined process, in which continuum and characteristic X-rays are generated through the recombination of electrons and electron vacancies produced in ion-atom collision events during slowing down of a beam of charged particles in an object. The unique correspondence between the energies of characteristic X-ray lines and the atomic numbers of the excited atoms makes PIXE a useful method in instrumental analytics. The characteristic features of PIXE as an analytical tool are as follows:

  • applicability to the determination of absolute concentration of elemental constituents in a wide range of atomic number,

  • easy sample preparation; practically non-destructive direct analysis of the surface of the original objects,

  • high sensitivity in trace element determination on small-volume samples,

  • high speed in the preparations and measurements,

  • possibility of obtaining analytical...

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© 2003 Kluwer Academic Publishers

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(2003). Chemical Applications of . In: Handbook of Nuclear Chemistry. Springer, Boston, MA. https://doi.org/10.1007/0-387-30682-X_28

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  • DOI: https://doi.org/10.1007/0-387-30682-X_28

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4020-1305-8

  • Online ISBN: 978-0-387-30682-7

  • eBook Packages: Springer Book Archive

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