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Small-Angle Scattering of Block Copolymers

In the Melt, Solution and Crystal States

  • Reference work entry
Soft Matter Characterization

1 Introduction

Small-angle scattering (SAS) is a powerful technique for examining nanostructures formed by the self-assembly of block copolymers, whether in the melt, solution or crystal state. The current chapter is mainly focused on small-angle x-ray scattering studies (SAXS), although inevitably there is some overlap with small-angle neutron scattering (SANS), which in many ways provides similar information. However, the use of isotope labeling (usually substituting hydrogen for deuterium) permits contrast variation SANS experiments, which can yield information on chain conformation or micellar structure, for example. This is discussed in detail in Volume 3, Chap. 1. SAXS has advantages compared to SANS that it can be performed in the laboratory. On the other hand synchrotron SAXS permits fast time-resolved experiments, which are important in probing dynamic processes. The main use of SAXS is to determine morphology. This is discussed in detail in this chapter, which is organized...

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Authors and Affiliations

  1. University of Leeds Leeds, Leeds, UK

    I. Hamley

  2. University of Reading Reading, Reading, UK

    V. Castelletto

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  1. I. Hamley
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Editors and Affiliations

  1. CERMAV, CNRS-UPR 5301 and Joseph Fourier University, Grenoble Cedex 9, France

    Redouane Borsali

  2. Department of Chemistry, University of California - Stanford Stauffer II, 375 North-South Mall, 94305-5080, Stanford, CA, USA

    Robert Pecora (Professor) (Professor)

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Hamley, I., Castelletto, V. (2008). Small-Angle Scattering of Block Copolymers. In: Borsali, R., Pecora, R. (eds) Soft Matter Characterization. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-4465-6_20

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