Skip to main content
SpringerLink
Log in

Sol-Gel Coatings with Nanocontainers of Corrosion Inhibitors for Active Corrosion Protection of Metallic Materials

Handbook of Sol-Gel Science and Technology

  • 165 Accesses

Abstract

This chapter provides an overview of corrosion protection strategies using sol-gel coatings. The chapter starts by acknowledging current state of corrosion engineering and main directions in corrosion protection of metals specifically addressing how sol-gel systems differ from other coatings types. The examples of application of sol-gel coatings as barrier pretreatments have been presented. With that some preliminary conclusions have been made emphasizing the important need for active corrosion protection using inhibitors. Simple approaches presenting inorganic and organic corrosion inhibitors incorporation to hybrid sol-gel coatings are described. The corrosion performance and associated drawbacks of such approach are presented. The chapter also critically reviews different smart protection systems with controlled inhibitor release based on “smart” micro- and nanocontainers. The inhibitor loading strategies to nanocontainers, types of containers, performance, and associated protection mechanisms are critically discussed. The chapter concludes with final remarks regarding the utilization of sol-gel protective coatings combined with corrosion inhibitors.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution

Institutional subscriptions

References

  • Abdullayev E, Price R, Shchukin D, Lvov Y. Halloysite tubes as nanocontainers for anticorrosion coating with benzotriazole. ACS Appl Mater Interfaces. 2009;1:1437–43.

    Article  Google Scholar 

  • Andreeva DV, Shchukin DG. Smart self-repairing protective coatings. Mater Today. 2008;11:24–30.

    Article  Google Scholar 

  • Andreeva DV, Fix D, Möhwald H, Shchukin DG. Self-healing anticorrosion coatings based on pH-sensitive polyelectrolyte/inhibitor sandwich like nanostructures. Adv Mater. 2008;20:2789–94.

    Article  Google Scholar 

  • Arunchandran C, Ramya S, George RP, Kamachi MU. Self-healing corrosion resistive coatings based on inhibitor loaded TiO2 nanocontainers. J Electrochem Soc. 2012;159(11):C552–9.

    Article  Google Scholar 

  • Arunchandran C, Ramya S, George RP, Kamachi MU. 2-Mercaptobenzothiazole-loaded hollow mesoporous silica-based hybrid coatings for corrosion protection of modified 9Cr-1Mo ferritic steel. Corrosion. 2014;70:496–511.

    Article  Google Scholar 

  • Balan P, Singh Raman RK, Chan E-S, Harun MK, Swamy V. Effectiveness of lanthanum triflate activated silica nanoparticles as fillers in silane films for corrosion protection of low carbon steel. Prog Org Coat. 2016;90:222–34.

    Article  Google Scholar 

  • Ballard RL, Williams JP, Njus JM, Kiland BR, Soucek MD. Inorganic-organic hybrid coatings with mixed metal oxides. Eur Polym J. 2001;37:381–98.

    Article  Google Scholar 

  • Bera S, Rout TK, Udayabhanu G, Narayan R. Comparative study of corrosion protection of sol-gel. Prog Organic Coat. 2015;88:293–303.

    Article  Google Scholar 

  • Bera S, Udayabhanu G, Narayan R, Rout TK. High performance chrome free coating for white rust protection of zinc. Mater Sci Technol. 2016;32:338–47.

    Article  Google Scholar 

  • Bescher E, Mackenzie JD. Sol-gel coatings for the protection of brass and bronze. J Sol-Gel Sci Technol. 2003;26:1223–6.

    Article  Google Scholar 

  • Bohm S, McMurray HN, Powell SM, Worsley DA. Novel environment friendly corrosion inhibitor pigments based on naturally occurring clay minerals. Mater Corros. 2001;52:896–903.

    Article  Google Scholar 

  • Borisova D, Mohwald H, Shchukin DG. Mesoporous silica nanoparticles for active corrosion protection. ACS Nano. 2011;5(3):1939–46 (Borisova et al., 2011).

    Article  Google Scholar 

  • Borisova D, Mohwald H, Shchukin DG. Influence of embedded nanocontainers on the efficiency of active anticorrosive coatings for aluminum alloys Part I: Influence of nanocontainer concentration. ACS Appl Mater Interfaces. 2012;4(6):2931–9.

    Article  Google Scholar 

  • Borisova D, Mohwald H, Shchukin DG. Influence of embedded nanocontainers on the efficiency of active anticorrosive coatings for aluminum alloys Part II: Influence of nanocontainer position. ACS Appl Mater Interfaces. 2013;5(1):80–7.

    Article  Google Scholar 

  • Bradley WF. Diagnostic criteria for clay minerals. Am Mineral. 1945;30:704–13.

    Google Scholar 

  • Brinker CJ, Scherrer G. Sol-gel science: the physics and chemistry of sol-gel processing. San Diego: Academic press; 1990.

    Google Scholar 

  • Buchheit RG, Mamidipally SB, Schmutz P, Guan H. Active corrosion protection in Ce-modified hydrotalcite conversion coatings. Corrosion. 2002;58:3–14.

    Article  Google Scholar 

  • Buchheit RG, Guan H, Mahajanam S, Wong F. Active corrosion protection and corrosion sensing in chromate-free organic coatings. Prog Org Coat. 2003;47:174–82.

    Article  Google Scholar 

  • Chen T, Fu JJ. An intelligent anticorrosion coating based on pH-responsive supramolecular nanocontainers. Nanotechnology. 2012;23:505705.

    Article  Google Scholar 

  • Chen Y, Jin L, Xie Y. Sol-gel processing of organic-inorganic nanocomposite protective coatings. J Sol-Gel Sci Technol. 1998;13:735–8.

    Article  Google Scholar 

  • Chou TP, Chandrasekaran C, Limmer SJ, Seraji S, Wu Y, Forbess MJ, Nguyen C, Cao GZ. Organic-inorganic hybrid coatings for corrosion protection. J Non-Cryst Solids. 2001;290:153–62.

    Article  Google Scholar 

  • Chou TP, Chandrasekaran C, Cao GZ. Sol-gel-derived hybrid coatings for corrosion protection. J Sol-Gel Sci Technol. 2003;26:321–7.

    Article  Google Scholar 

  • Conde A, Duran A, Damborenea JJ. Polymeric sol–gel coatings as protective layers of aluminium alloys. Prog Org Coat. 2003;46:288–96.

    Article  Google Scholar 

  • Critchlow GW, Brewis DM. Review of surface pretreatments for aluminium alloys. Int J Adhes Adhes. 1996;16:255–75.

    Article  Google Scholar 

  • Decher, G., Polyelectrolyte multilayers, an Overview, pp 1–46, in Decher, G., and Schlenoff, J. B. Ed’s, Multilayer thin films: sequential assembly of nanocomposite materials, Wiley, Weinheim 2003.

    Google Scholar 

  • Dias SAS, Lamaka SV, Nogueira CA, Diamantino TC, Ferreira MGS. Sol–gel coatings modified with zeolite fillers for active corrosion protection of AA2024. Corr Sci. 2012;62:153–62.

    Article  Google Scholar 

  • Dias SAS, Marques A, Lamaka SV, Simões A, Diamantino TC, Ferreira MGS. The role of Ce(III)-enriched zeolites on the corrosion protection of AA2024-T3. Electrochim Acta. 2013;112:549–56.

    Article  Google Scholar 

  • Ding CD, Liu Y, Wang MD, Wang T, Fu JJ. Self-healing, superhydrophobic coating based on mechanized silica nanoparticles for reliable protection of magnesium alloys. J Mater Chem A. 2016;4:8041–52.

    Article  Google Scholar 

  • Ferrer EL, Rollon AP, Mendoza HD, Lafont U, Garcia SJ. Double-doped zeolites for corrosion protection of aluminium alloys. Micropor Mesopor Mat. 2014;188:8–15.

    Article  Google Scholar 

  • Fix D, Andreeva DV, Lvov YM, Shchuki DG, Moehwald H. Application of inhibitor-loaded halloysite nanotubes in active anti-corrosive coatings. Adv Funct Mater. 2009;19:1720–7.

    Article  Google Scholar 

  • Galio AF, Lamaka SV, Zheludkevich ML, Dick LFP, Müller IL, Ferreira MGS. Inhibitor-doped sol-gel coatings for corrosion protection of magnesium alloy AZ31. Surf Coat Technol. 2010;204:1479–86.

    Article  Google Scholar 

  • Garcia-Heras M, Jimenez-Morales A, Casal B, Galvan JC, Radzki S, Villegas MA. Preparation and electrochemical study of cerium-silica sol-gel thin films. J Alloys Compd. 2004;380:219–24.

    Article  Google Scholar 

  • Gordon Bierwagen P. Reflections on corrosion control by organic coatings. Prog Org Coat. 1996;28:43–8.

    Article  Google Scholar 

  • Guglielmi M. Sol-gel coatings on metals. J Sol-Gel Sci Technol. 1997;8:443–9.

    Google Scholar 

  • Hench LL, West JK. The sol-gel process. Chem Rev. 1990;90:33–72.

    Article  Google Scholar 

  • Hinton BRW. Corrosion inhibition with rare earth metal salts. J Alloys Compd. 1992;180:15–25.

    Article  Google Scholar 

  • Hoebbel D, Nacken M, Schmidt A. NMR study on the hydrolysis, condensation and epoxide ring-opening reaction in sols and gels of the system glycidoxypropyltrimethoxysilane-water-titaniumtetraethoxide. J Sol-Gel Sci Technol. 1998;12:169–79.

    Article  Google Scholar 

  • Ivanou DK, Yasakau KA, Kallip S, Lisenkov AD, Starykevich M, Lamaka SV, Ferreira MGS, Zheludkevichb ML. Active corrosion protection coating for a ZE41 magnesium alloy created by combining PEO and sol–gel techniques. RSC Adv. 2016;6:12553.

    Article  Google Scholar 

  • Joshua Du Y, Damron M, Tang G, Zheng H, Chu CJ, Osborne JH. Inorganic/organic hybrid coatings for aircraft aluminum alloy substrates. Prog Org Coat. 2001;41:226–32.

    Article  Google Scholar 

  • Judeinstein P, Sanchez C. Hybrid organic-inorganic materials: a land of multidisciplinarity. J Mater Chem. 1996;6:511–25.

    Article  Google Scholar 

  • Kachurina O, Knobbe E, Metroke TL, Ostrander JW, Kotov NA. Corrosion protection with synergistic LBL/Ormosil nanostructured thin films. Int J Nanotechnol. 2004;1:347–65.

    Article  Google Scholar 

  • Khramov AN, Balbyshev VN, Voevodin NN, Donley MS. Nanostructured sol–gel derived conversion coatings based on epoxy- and amino-silanes. Prog Org Coat. 2003;47:207–13.

    Article  Google Scholar 

  • Khramov AN, Voevodin NN, Balbyshev VN, Donley MS. Hybrid organo-ceramic corrosion protection coatings with encapsulated organic corrosion inhibitors. Thin Solid Films. 2004;447–448:549–57.

    Article  Google Scholar 

  • Khramov AN, Voevodin NN, Balbyshev VN, Mantz RA. Sol-gel-derived corrosion-protective coatings with controllable release of incorporated organic corrosion inhibitors. Thin Solid Films. 2005;483:191–6.

    Article  Google Scholar 

  • Lamaka SV, Zheludkevich ML, Yasakau KA, Montemor MF, Cecilio P, Ferreira MGS. TiOx self-assembled networks prepared by templating approach as nanostructured reservoirs for self-healing anticorrosion pre-treatments. Electrochem Commun. 2006;8:421–8.

    Article  Google Scholar 

  • Lamaka SV, Zheludkevich ML, Yasakau KA, Montemor MF, Ferreira MGS. High effective organic corrosion inhibitors for 2024 aluminium alloy. Electrochim Acta. 2007a;52:7231.

    Article  Google Scholar 

  • Lamaka SV, Zheludkevich ML, Yasakau KA, Serra R, Poznyak SK, Ferreira MGS. Nanoporous titania interlayer as reservoir of corrosion inhibitors for coatings with self-healing ability. Prog Org Coat. 2007b;58:127–35.

    Article  Google Scholar 

  • Lamaka SV, Shchukin DG, Andreeva DV, Zheludkevich ML, Möhwald H, Ferreira MGS. Sol-gel/polyelectrolyte active corrosion protection system. Adv Funct Mater. 2008;18:3137–47.

    Article  Google Scholar 

  • Li Y-S, Lu W, Wang Y, Tran T. Studies of (3-mercaptopropyl)trimethoxylsilane and bis(trimethoxysilyl)ethane sol-gel coating on copper and aluminum. Spectrochim Acta Part A. 2009;73:922–8.

    Article  Google Scholar 

  • Liang Y, Wang M, Wang C, Feng J, Li J, Wang L, Fu J. Facile synthesis of smart nanocontainers as key components for construction of self-healing coating with superhydrophobic surfaces. Nanoscale Res Lett. 2016;11:231.

    Article  Google Scholar 

  • MacEwan DMC. Complexes of clay with organic compounds. I Complex formation between montmorillonite and halloysite and certain organic liquids. J Chem Soc Faraday Trans. 1948;44:349–67.

    Article  Google Scholar 

  • Maia F, Yasakau KA, Carneiro J, Kallip S, Tedim J, Henriques T, Cabral A, Venâncio J, Zheludkevich ML, Ferreira MGS. Corrosion protection of AA2024 by sol-gel coatings modified with MBT-loaded polyurea microcapsules. Chem Eng J. 2016;283:1108–17.

    Article  Google Scholar 

  • Mascia L, Prezzi L, Wilcox GD, Lavorgna M. Molybdate doping of networks in epoxy-silica hybrids: domain structuring and corrosion inhibition. Prog Org Coat. 2006;56:13–22.

    Article  Google Scholar 

  • Mayrand M, Quinson JF, Roche A, Roisne V, Guyon H. Heteropolysiloxane coatings on electrogalvanized steel: elaboration and characterization. J Sol-Gel Sci Technol. 1998;12:49–57.

    Article  Google Scholar 

  • McMurray HN, Williams G. Inhibition of filiform corrosion on organic-coated aluminium alloy by hydrotalcite-like anion-exchange pigments. Corrosion. 2004;60:219–28.

    Article  Google Scholar 

  • Metroke TL, Parkhill RL, Knobbe ET. Passivation of metal alloys using sol-gel-derived materials – a review. Prog Org Coat. 2001;41:233–8.

    Article  Google Scholar 

  • Metroke TL, Kachurina O, Knobbe ET. Spectroscopic and corrosion resistance characterization of GLYMO-TEOS Ormosil coatings for aluminum alloy corrosion inhibition. Prog Org Coat. 2002;44:295–305.

    Article  Google Scholar 

  • Metroke TL, Gandhi JS, Apblett A. Corrosion resistance properties of Ormosil coatings on 2024-T3 aluminium alloy. Prog Org Coat. 2004;50:231–46.

    Article  Google Scholar 

  • Miyazawa K, Suzuki K, Wey MY. Microstructure and oxidation-resistant property of sol-gel-derived ZrO2-Y2O3 films prepared on austenitic stainless steel substrates. J Am Ceram Soc. 1995;78:347–55.

    Article  Google Scholar 

  • Montemor MF, Ferreira MGS. Cerium salt activated nanoparticles as fillers for silane films: evaluation of the corrosion inhibition performance on galvanised steel substrates. Electrochim Acta. 2007;52:6976–87.

    Article  Google Scholar 

  • Moutarlier V, Neveu B, Gigandet MP. Evolution of corrosion protection for sol-gel coatings doped with inorganic inhibitors. Surf Coat Technol. 2008;202:2052–8.

    Article  Google Scholar 

  • Ono S, Tsuge H, Nishi Y, Hirano S-I. Improvement of corrosion resistance of metals by an environmentally friendly silica coating method. J Sol-Gel Sci Technol. 2004;29:147–53.

    Article  Google Scholar 

  • Osborne JH, Blohowiak KY, Taylor SR, Hunter C, Bierwagon G, Carlson B, Bernard D, Donley MS. Testing and evaluation of nonchromated coating systems for aerospace applications. Prog Org Coat. 2001;41:217–25.

    Article  Google Scholar 

  • Pabalan RT, Bertetti FP. Cation-exchange properties of natural zeolites. Rev Mineral Geochem. 2001;45:453–518.

    Article  Google Scholar 

  • Parkhill RL, Knobbe ET, Donley MS. Application and evaluation of environmentally compliant spray-coated ormosil films as corrosion resistant treatments for aluminum 2024-T3. Prog Org Coat. 2001;41:261–5.

    Article  Google Scholar 

  • Quinet M, Neveu B, Moutarlier V, Audebert P, Ricq L. Corrosion protection of sol-gel coatings doped with an organic corrosion inhibitor: Chloranil. Prog Org Coat. 2007;58:46–53.

    Article  Google Scholar 

  • Rao AV, Latthe SS, Mahadik SA, Kappenstein C. Mechanically stable and corrosion resistant superhydrophobic sol-gel coatings on copper substrate. Appl Surf Sci. 2011;257:5772–6.

    Article  Google Scholar 

  • Raps D, Hack T, Wehr J, Zheludkevich ML, Bastos AC, Ferreira MGS, Nuyken O. Electrochemical study of inhibitor-containing organic-inorganic hybrid coatings on AA2024. Corros Sci. 2009;51:1012–21.

    Article  Google Scholar 

  • Rives V (Ed). Layered double hydroxide: present and future. New York: Nova Science Publishers, Inc.; 2001.

    Google Scholar 

  • Rosero-Navarro NC, Figiel P, Jedrzejewski R, Biedunkiewicz A, Castro Y, Aparicio M, Pellice SA, Duran A. Influence of cerium concentration on the structure and properties of silica-methacrylate sol–gel coatings. J Sol-Gel Sci Technol. 2010a;54:301–11.

    Article  Google Scholar 

  • Rosero-Navarro NC, Paussa L, Andreatta F, Castro Y, Durán A, Aparicio M, Fedrizzi L. Optimization of hybrid sol–gel coatings by combination of layers with complementary properties for corrosion protection of AA2024. Prog Org Coat. 2010b;69:167–74.

    Article  Google Scholar 

  • Roussi E, Tsetsekou A, Skarmoutsou A, Charitidis CA, Karantonis A. Anticorrosion and nanomechanical performance of hybrid organo-silicate coatings integrating corrosion inhibitors. Surf Coat Technol. 2013;232:131–41.

    Article  Google Scholar 

  • Schem M, Schmidt T, Gerwann J, Wittmar M, Veith M, Thompson GE, Molchan IS, Hashimoto T, Skeldon P, Phani AR, Santucci S, Zheludkevich ML. CeO2-filled sol–gel coatings for corrosion protection of AA2024-T3 aluminium alloy. Corros Sci. 2009;51:2304–15.

    Article  Google Scholar 

  • Schmidt H. New type of non-crystalline solids between inorganic and organic materials. J Non-Cryst Solids. 1985;73:681–91.

    Article  Google Scholar 

  • Schmidt H, Langenfeld S, Naß R. A new corrosion protection coating system for pressure-cast aluminium automotive parts. Mater Des. 1997;18:309–13.

    Article  Google Scholar 

  • Schubert U, Huesing N, Lorenz A. Hybrid inorganic-organic materials by sol-gel processing of organofunctional metal alkoxides. Chem Mater. 1995;7:2010–27.

    Article  Google Scholar 

  • Shchukin DG, Zheludkevich ML, Yasakau KA, Lamaka SV, Ferreira MGS, Möhwald H. Layer-by-layer assembled nanocontainers for self-healing corrosion protection. Adv Mater. 2006;18:1672–8.

    Article  Google Scholar 

  • Shchukin DG, Lamaka SV, Yasakau KA, Zheludkevich ML, Möhwald H, Ferreira MGS. Active anticorrosion coatings with halloysite nanocontainers. J Phys Chem C. 2008;112:958–64.

    Article  Google Scholar 

  • Sheffer M, Groysman A, Mandler D. Electrodeposition of sol–gel films on Al for corrosion protection. Corros Sci. 2003;45:2893–904.

    Article  Google Scholar 

  • Sheffer M, Groysman A, Starosvetsky D, Savchenko N, Mandler D. Anion embedded sol-gel films on Al for corrosion protection. Corros Sci. 2004;46:2975–85.

    Article  Google Scholar 

  • Skorb EV, Fix D, Andreeva DV, Möhwald H, Shchukin DG, Mohwald H. Surface-modified mesoporous SiO2 containers for corrosion protection. Adv Funct Mater. 2009a;19:2373–9.

    Article  Google Scholar 

  • Skorb EV, Skirtach AG, Sviridov DV, Shchukin DG, Möhwald H. Laser-controllable coatings for corrosion protection. ACS Nano. 2009b;3:1753–60.

    Article  Google Scholar 

  • Smarsly B, Garnweitner G, Assink R, Brinker CJ. Preparation and characterization of mesostructured polymer-functionalized sol–gel-derived thin films. Prog Org Coat. 2003;47:393–400.

    Article  Google Scholar 

  • Supplit R, Koch T, Schubert U. Evaluation of the anti-corrosive effect of acid pickling and sol-gel coating on magnesium AZ31 alloy. Corros Sci. 2007;49:3015–23.

    Article  Google Scholar 

  • Tamar Y, Mandler D. Corrosion inhibition of magnesium by combined zirconia silica sol–gel films. Electrochim Acta. 2008;53:5118–27.

    Article  Google Scholar 

  • Tan ALK, Soutar AM, Annergren IF, Liu YN. Multilayer sol–gel coatings for corrosion protection of magnesium. Surf Coat Technol. 2005;198:478–82.

    Article  Google Scholar 

  • Tedim J, Poznyak SK, Kuznetsova A, Raps D, Hack T, Zheludkevich ML, Ferreira MGS. Enhancement of active corrosion protection via combination of inhibitor-loaded nanocontainers. ACS Appl Mater Interfaces. 2010;2:1528.

    Article  Google Scholar 

  • Twite RL, Bierwagen GP. Review of alternatives to chromate for corrosion protection of aluminum aerospace alloys. Prog Org Coat. 1998;33:91–100.

    Article  Google Scholar 

  • Vasconcelos DCL, Carvalho JAN, Mantel M, Vasconcelos WL. Corrosion resistance of stainless steel coated with sol-gel silica. J Non-Cryst Solids. 2000;273:135–9.

    Article  Google Scholar 

  • Voevodin NN, Grebasch NT, Soto WS, Arnold FE, Donley MS. Potentiodynamic evaluation of sol-gel coatings with inorganic inhibitors. Surf Coat Technol. 2001a;140:24–8.

    Article  Google Scholar 

  • Voevodin NN, Balbyshev VN, Khobaib M, Donley MS. Nanostructured coatings approach for corrosion protection. Prog Org Coat. 2003;47:416–23.

    Article  Google Scholar 

  • Vreugdenhil AJ, Woods ME. Triggered release of molecular additives from epoxy-amine sol-gel coatings. Prog Org Coat. 2005;53:119–125.

    Article  Google Scholar 

  • Wang D, Bierwagen GP. Sol–gel coatings on metals for corrosion protection. Prog Org Coat. 2009;64:327–38.

    Article  Google Scholar 

  • White SR, Sottos NR, Geubelle PH, Moore JS, Kessler MR, Sriram SR, Brown EN, Viswanathan S. Autonomic healing of polymer composites. Nature. 2001;409:794–7.

    Article  Google Scholar 

  • Wittmar A, Wittmar M, Ulrich A, Caparrotti H, Veith M. Hybrid sol–gel coatings doped with transition metal ions for the protection of AA 2024-T3. J Sol-Gel Sci Technol. 2012;61:600–12.

    Article  Google Scholar 

  • Yasakau KA, Zheludkevich ML, Karavai OV, Ferreira MGS. Influence of inhibitor addition on the corrosion protection performance of sol-gel coatings on AA2024. Prog Org Coat. 2008;63:352–61.

    Article  Google Scholar 

  • Yasakau KA, Kallip S, Zheludkevich ML, Ferreira MGS. Active corrosion protection of AA2024 by sol-gel coatings with cerium molybdate nanowires. Electrochim Acta. 2013;112:236–46.

    Article  Google Scholar 

  • Yasakau KA, Tedim J, Zheludkevich ML, Ferreira MGS. Active corrosion protection by nanoparticles and conversion films of layered double hydroxides. Corrosion. 2014;70:436–45.

    Article  Google Scholar 

  • Zandi Zand R, Verbeken K, Flexer V, Adriaens A. Effects of ceria nanoparticle concentrations on the morphology and corrosion resistance of cerium–silane hybrid coatings on electro-galvanized steel substrates. Mater Chem Phys. 2014;145:450–60.

    Article  Google Scholar 

  • Zhao W, Lang M, Li Y, Li L, Shi J. Fabrication of uniform hollow mesoporous silica spheres and ellipsoids of tunable size through a facile hard-templating route. J Mater Chem. 2009;19:2778–83.

    Article  Google Scholar 

  • Zheludkevich ML, Serra R, Montemor MF, Yasakau KA, Salvado IMM, Ferreira MGS. Nanostructured sol-gel coatings doped with cerium nitrate as pre-treatments for AA2024-T3 – corrosion protection performance. Electrochim Acta. 2005a;51:208–17.

    Article  Google Scholar 

  • Zheludkevich ML, Serra R, Montemor MF, Ferreira MGS. Oxide nanoparticle reservoirs for storage and prolonged release of the corrosion inhibitors. Electrochem Commun. 2005b;7:836–40.

    Article  Google Scholar 

  • Zheludkevich ML, Salvado IM, Ferreira MGS. Sol–gel coatings for corrosion protection of metals. J Mater Chem. 2005c;15:5099–111.

    Article  Google Scholar 

  • Zheludkevich M, Serra R, Montemor F, Salvado I, Ferreira M. Corrosion protective properties of nanostructured sol–gel hybrid coatings to AA2024-T3. Surf Coat Technol. 2006;200:3084–94.

    Article  Google Scholar 

  • Zheludkevich ML, Shchukin DG, Yasakau KA, Möhwald H, Ferreira MGS. Anticorrosion coatings with self-healing effect based on nanocontainers impregnated with corrosion inhibitor. Chem Mater. 2007;19:402–11.

    Article  Google Scholar 

  • Zheludkevich ML, Poznyak SK, Rodrigues LM, Raps D, Hack T, Dick LF, Nunes T, Ferreira MGS. Active protection coatings with layered double hydroxide nanocontainers of corrosion inhibitor. Corros Sci. 2010;52:602–11.

    Article  Google Scholar 

  • Zheludkevich ML, Tedim J, Freire CSR, Fernandes SCM, Kallip S, Lisenkov A, Gandini A, Ferreira MGS. Self-healing protective coatings with “green” chitosan based pre-layer reservoir of corrosion inhibitor. J Mater Chem. 2011;21:4805–12.

    Article  Google Scholar 

  • Zomorodian A, Brusciotti F, Fernandes A, Carmezim MJ, Moura e Silva T, Fernandes JCS, Montemor MF. Anti-corrosion performance of a new silane coating for corrosion protection of AZ31 magnesium alloy in Hank’s solution. Surf Coat Technol. 2012;206:4368–75.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Materials and Ceramic Engineering, CICECO – Aveiro Institute of Materials, University of Aveiro, Campus Santiago, Aveiro, 3810-193, Portugal

    K. A. Yasakau & M. G. S. Ferreira

  2. Magnesium Innovation Centre, MagIC at Helmholtz-Zentrum Geesthacht, HZG, Max-Planck Str. 1, 21502, Geesthacht, Germany

    M. L. Zheludkevich

  3. Institute for Materials Science, Faculty of Engineering, Kiel University, Kaiserstraße 2, 4143, Kiel, Germany

    M. L. Zheludkevich

Authors
  1. K. A. Yasakau
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. G. S. Ferreira
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. L. Zheludkevich
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to K. A. Yasakau .

Editor information

Editors and Affiliations

  1. Rutgers University, Piscataway, New Jersey, USA

    Lisa Klein

  2. Madrid, Spain

    Mario Aparicio

  3. City University of New York, New York, USA

    Andrei Jitianu

Rights and permissions

Reprints and permissions

Copyright information

© 2016 Springer International Publishing AG

About this entry

Cite this entry

Yasakau, K.A., Ferreira, M.G.S., Zheludkevich, M.L. (2016). Sol-Gel Coatings with Nanocontainers of Corrosion Inhibitors for Active Corrosion Protection of Metallic Materials. In: Klein, L., Aparicio, M., Jitianu, A. (eds) Handbook of Sol-Gel Science and Technology. Springer, Cham. https://doi.org/10.1007/978-3-319-19454-7_141-1

Download citation

  • DOI: https://doi.org/10.1007/978-3-319-19454-7_141-1

  • Received:

  • Accepted:

  • Published:

  • Publisher Name: Springer, Cham

  • Print ISBN: 978-3-319-19454-7

  • Online ISBN: 978-3-319-19454-7

  • eBook Packages: Springer Reference Chemistry and Mat. ScienceReference Module Physical and Materials ScienceReference Module Chemistry, Materials and Physics

Publish with us

Policies and ethics

Chapter history

  1. Latest

    Sol-Gel Coatings with Nanocontainers of Corrosion Inhibitors for Active Corrosion Protection of Metallic Materials
    Published:
    13 March 2017

    DOI: https://doi.org/10.1007/978-3-319-19454-7_141-2

  2. Original

    Sol-Gel Coatings with Nanocontainers of Corrosion Inhibitors for Active Corrosion Protection of Metallic Materials
    Published:
    05 January 2017

    DOI: https://doi.org/10.1007/978-3-319-19454-7_141-1

Search

Navigation