Atomic Symbol: Cl
Atomic Number: 17
Atomic Weight: 35.453
Isotopes and Abundances: stable 35Cl (75.76%) and 37Cl (24.24%) and radioactive 36Cl (t1/2 = 301.3 ka)
1 Atm Melting Point: 171.65 K
1 Atm Boiling Point: 239.11 K
Common Valences: −1, 1, 3, 5, 7
Ionic Radii: 1.8 Ã…
Pauling Electronegativity: 3.16
First Ionization Potential: 1256.2 kJ mol−1
Chondritic (CI) Abundance: 680 ppm
Silicate Earth Abundance: 15–30 ppm
Crustal Abundance: 140–470 ppm
Seawater Abundance: 19,300 ppm
Core Abundance: <20 ppb?
Properties
Chlorine is a diatomic toxic green-yellow gas at room temperature with a bleach-like smell. However, Cl is characterized by an S2P5outer electron shell configuration and is highly electronegative, meaning it rarely exists in its elemental form in nature. Chlorine most commonly forms the chloride ion with a valence of -1, but it can exist in a number of different valence states. Chloride forms strong ionic bonds in salts and substitutes for the OH group...
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
About Chlorine. Retrieved May 2016, The Chlorine Institute. Available at: http://chlorineinstitute.org/stewardship/about-chlorine
Barnes JD, Straub SM (2010) Chorine stable isotope variations in Izu Bonin tephra: implications for serpentinite subduction. Chem Geol 272(1–4):62–74
Davy H (1811) On a combination of oxymuriatic gas and oxygene gas. Philos Trans R Soc Lond 101:155–162
Hanor JS (1994) Origin of saline fluids in sedimentary basins. In: Parnell J (ed) Geofluids: origin, migration and evolution of fluids in sedimentary basins, Geological society special publication. Geological Society, London, pp 151–174
Hay WW, Migdisov A, Balukhovsky AN, Wold CN, Flögel S, Söding E (2006) Evaporites and the salinity of the ocean during the Phanerozoic: implications for climate, ocean circulation and life. Palaeogeogr Palaeoclimatol Palaeoecol 240(1–2):3–46
Ivy-Ochs S, Kober F (2008) Surface exposure dating with cosmogenic nuclides. Quat Sci J 57(1–2):179–209
John T, Layne GD, Haase KM, Barnes JD (2010) Chlorine isotope evidence for crustal recycling into the Earth’s mantle. Earth Planet Sci Lett 298(1–2):175–182
Kendrick MA (2017) Halogens in seawater, marine sediments and the altered oceanic lithosphere. In: Harlov DE, Aranovich LY (eds) The role of halogens in terrestrial and extraterrestrial processes. Springer, Berlin. In press
Kendrick MA, Honda M, Pettke T, Scambelluri M, Phillips D, Giuliani A (2013) Subduction zone fluxes of halogens and noble gases in seafloor and forearc serpentinites. Earth Planet Sci Lett 365:86–96
Kendrick MA, Jackson MG, Hauri E, Phillips D (2015) The halogen (F, Cl, Br, I) and H2O systematics of Samoan lavas: assimilated seawater, EM2 and high 3He/4He components. Earth Planet Sci Lett 410:197–209
Kutterolf S, Hansteen TH, Appel K, Freundt A, Krüger K, Pérez W, Wehrmann H (2013) Combined bromine and chlorine release from large explosive volcanic eruptions: a threat to stratospheric ozone? Geology 41(6):707–710
Lodders K (2003) Solar system abundances and condensation temperatures of the elements. Astrophys J 591:1220–1247
McDonough WF, Sun S-s (1995) The composition of the earth. Chem Geol 120:223–253
Michael PJ, Cornell WC (1998) Influence of spreading rate and magma supply on crystallization and assimilation beneath mid-ocean ridges: evidence from chlorine and major element chemistry of mid-ocean ridge basalts. J Geophys Res Solid Earth 103(B8):18325–18356
Rudnick RL, Gao S (2003) Composition of the continental crust. In: Treatise of geochemistry. Elsevier, Amsterdam, pp 1–64
Sano T, Miyoshi M, Ingle S, Banerjee NR, Ishimoto M, Fukuoka T (2008) Boron and chlorine contents of upper oceanic crust: basement samples from IODP Hole 1256D. Geochem Geophys Geosyst 9(12):Q12O15
Schilling JG, Unni CK, Bender ML (1978) Origin of chlorine and bromine in the oceans. Nature 273:631–636
Sharp ZD, Barnes JD (2004) Water-soluble chlorides in massive seafloor serpentinites: a source of chloride in subduction zones. Earth Planet Sci Lett 226(1–2):243–254
Sharp ZD, Draper DS (2013) The chlorine abundance of earth: implications for a habitable planet. Earth Planet Sci Lett 369–370:71–77
Sharp ZD, Shearer CK, McKeegan KD, Barnes JD, Wang YQ (2010) The chlorine isotope composition of the moon and implications for an anhydrous mantle. Science 329(5995):1050–1053
Sharp ZD, Mercer JA, Jones RH, Brearley AJ, Selverstone J, Bekker A, Stachel T (2013) The chlorine isotope composition of chondrites and earth. Geochim Cosmochim Acta 107:189–204
Shimizu K, Saal AE, Myers CE, Nagle AN, Hauri EH, Forsyth DW, Kamenetsky VS, Niu Y (2016) Two-component mantle melting-mixing model for the generation of mid-ocean ridge basalts: implications for the volatile content of the Pacific upper mantle. Geochim Cosmochim Acta 176:44–80
Yardley BWD (2005) 100th anniversary special paper: metal concentrations in crustal fluids and their relationship to ore formation. Econ Geol 100(4):613–632
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2018 Springer International Publishing AG, part of Springer Nature
About this entry
Cite this entry
Kendrick, M.A. (2018). Chlorine. In: White, W.M. (eds) Encyclopedia of Geochemistry. Encyclopedia of Earth Sciences Series. Springer, Cham. https://doi.org/10.1007/978-3-319-39312-4_89
Download citation
DOI: https://doi.org/10.1007/978-3-319-39312-4_89
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-39311-7
Online ISBN: 978-3-319-39312-4
eBook Packages: Earth and Environmental ScienceReference Module Physical and Materials ScienceReference Module Earth and Environmental Sciences