Definition
Any of several chemically synthesized forms of the element carbon
Introduction
Carbon compounds form the molecular basis of life on earth. Nature typically presents carbon in molecules chemically bound to other atoms, e.g., in carbon dioxide, carbonates, sugars, and natural gas, just to name a few. On the other hand, carbon can also be found in pure forms, called allotropes. As a result of its unique bonding ability, carbon is capable of forming many allotropes, whose physical properties vary widely with each form. This can easily be appreciated by looking at the two best-known carbon allotropes, diamond and graphite, which consist of extended networks ofsp 3- andsp 2-hybridized carbon atoms, respectively (Fig.1a,b). Diamond is highly transparent, it is the hardest naturally occurring material known, and it shows very low electrical conductivity. Graphite, however, is nontransparent, black, and soft enough to be...
References
Hirsch A (2010) The era of carbon allotropes. Nat Mater 9:868–871. doi:10.1038/nmat2885
Krüger A (2007) Neue Kohlenstoffmaterialien – Eine Einführung. B.G. Teubner Verlag/GWV Fachverlage GmbH, Wiesbaden
Kumar A, Lin PA, Xue A, Hao B, Yap YK, Sankaran RM (2013) Formation of nanodiamonds at near-ambient conditions via microplasma dissociation of ethanol vapour. Nat Commun 4:2618. doi:10.1038/ncomms3618
Gunawan MA, Hierso J-C, Poinsot D, Fokin AA, Fokina NA, Tkachenko BA, Schreiner PR (2014) Diamondoids: functionalization and subsequent applications of perfectly defined molecular cage hydrocarbons. New J Chem 38:28–41. doi:10.1039/c3nj00535f
Dahl JE, Liu SG, Carlson RMK (2003) Isolation and structure of higher diamondoids, nanometer-sized diamond molecules. Science 299:96–99. doi:10.1126/science.1078239
Chen L, Hernandez Y, Feng X, Müllen K (2012) From nanographene and graphene nanoribbons to graphene sheets: chemical synthesis. Angew Chem Int Ed 51:7640–7654. doi:10.1002/anie.201201084
Guldi DM, Martin N (eds) (2010) Carbon nanotubes and related structures: synthesis, characterization, functionalization, and applications. Wiley, Hoboken. doi:10.1002/9783527629930
Petrukhina MA, Scott LT (eds) (2011) Fragments of fullerenes and carbon nanotubes: designed synthesis, unusual reactions, and coordination chemistry. Wiley, Weinheim
Chernick ET, Tykwinski RR (2013) Carbon-rich nanostructures: the conversion of acetylenes into materials. J Phys Org Chem 26:742–749. doi:10.1002/poc.3160
Scott LT, Jackson EA, Zhang Q, Steinberg BD, Bancu M, Li B (2012) A short, rigid, structurally pure carbon nanotube by stepwise chemical synthesis. J Am Chem Soc 134:107–110. doi:10.1021/ja209461g
Langa F, Nierengarten J-F (eds) (2012) Fullerenes: principles and applications, 2nd edn. RSC Publishing, Cambridge. doi:10.1039/9781849732956
Bharat BR, Bally T, Valente A, Cyrański MK, Dobrzycki Ł, Spain SM, Rempała P, Chin MR, King BT (2010) Quadrannulene: a nonclassical fullerene fragment. Angew Chem Int Ed 49:399–402. doi:10.1002/anie.200905633
Heimann RB, Evsyukov SE, Kavan L (eds) (1999) Carbyne and carbynoid structures. Kluwar, Dordrecht
Januszewski JA, Tykwinski RR (2014) Synthesis and properties of long [n]cumulenes (n ≥ 5). Chem Soc Rev 43:3184–3203. doi:10.1039/c4cs00022f
Liu M, Artyukhov VI, Lee H, Xu F, Yakobson BI (2013) Carbyne from first principles: chain of C atoms, a nanorod or a nanorope. ACS Nano 7:10075–10082. doi:10.1021/nn404177r
Chalifoux WA, Tykwinski RR (2010) Synthesis of polyynes to model thesp-carbon allotrope carbyne. Nature Chem 2:967–971. doi:10.1038/nchem.828
Tahara K, Tobe Y (2006) Molecular loops and belts. Chem Rev 106:5274–5290. doi:10.1021/cr050556a
Diederich F, Rubin Y (1992) Synthetic approaches toward molecular and polymeric carbon allotropes. Angew Chem Int Ed 31:1101–1123. doi:10.1002/anie.199211013
Spitler EL, Johnson CA II, Haley MM (2006) Renaissance of annulene chemistry. Chem Rev 106:5344–5386. doi:10.1021/cr050541c
Tahara K, Yamamoto Y, Gross DE, Kozuma H, Arikuma Y, Ohta K, Koizumi Y, Gao Y, Shimizu Y, Seki S, Kamada K, Moore JS, Tobe Y (2013) Syntheses and properties of graphyne fragments: trigonally expanded dehydrobenzo[12]annulenes. Chem Eur J 19:11251–11260. doi:10.1002/chem.201300838
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Prenzel, D., Tykwinski, R.R. (2014). New Synthetic Carbon Allotropes. In: Kobayashi, S., Müllen, K. (eds) Encyclopedia of Polymeric Nanomaterials. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-36199-9_338-1
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DOI: https://doi.org/10.1007/978-3-642-36199-9_338-1
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