Skip to main content

Uranium Series, Opal

  • Living reference work entry
  • First Online:
Encyclopedia of Scientific Dating Methods
  • 165 Accesses

Synonyms

U-series disequilibrium; 230Th/U ages; Opaline silica

Definition

Uranium series dating. A geochronological method that uses intermediate decay products in the 238U or 235U radioactive decay chains to measure the length of time required to reach the current state of radioactive disequilibrium from an initial condition.

Opal. Amorphous or only partially crystalline hydrated silicon dioxide (SiO2∙nH2O) precipitated from aqueous solutions in near-Earth-surface environments.

Mineralogy and Geochemistry of Opal

Opal is a common mineraloid found near the surface of the Earth that consists of silica containing nonstructural water (SiO2∙nH2O). Opal typically forms by precipitation of colloidal silica from silica-saturated aqueous solutions in response to decreases in temperature, neutralization of alkaline solutions, increases in salinity, or evaporative concentration. Sedimentation of colloidal microspheres (<500 nm) results in deposits of amorphous silica gel. Subsequent dewatering...

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Institutional subscriptions

Bibliography

  • Bernal, J.-P., Eggins, S. M., and McCulloch, M. T., 2005. Accurate in situ 238U–234U–232Th–230Th analysis of silicate glasses and iron oxides by laser-ablation MC-ICP-MS. Journal of Analytical and Atomic Spectrometry, 20, 1240–1249.

    Article  Google Scholar 

  • Bischoff, J. L., and Fitzpatrick, J. A., 1991. U-series dating of impure carbonates: an isochron technique using total-sample dissolution. Geochimica et Cosmochimica Acta, 55, 543–554.

    Article  Google Scholar 

  • Darraugh, P. J., Gaskin, A. J., Terrell, B. C., and Sanders, J. V., 1965. Origin of precious opal. Nature, 209, 13–16.

    Article  Google Scholar 

  • Eggins, S. M., Grün, R., McCulloch, M. T., Pike, A. W. G., Chappell, J., Kinsley, L., Mortimer, G., Shelley, M., Murray-Wallace, C. V., Spötl, C., and Taylor, L., 2005. In situ U-series dating by laser-ablation multi-collector ICPMS: new prospects for quaternary geochronology. Quaternary Science Reviews, 24, 2523–2538.

    Article  Google Scholar 

  • Gaillou, E., Delaunay, A., Rondeau, B., Bouhnik-le-Coz, M., Fritsch, E., Cornen, G., and Monnier, C., 2008. The geochemistry of gem opals as evidence of their origin. Ore Geology Reviews, 34, 113–126.

    Article  Google Scholar 

  • Grün, R., Aubert, M., Joannes-Boyau, R., and Moncel, M.-H., 2008. High resolution analysis of uranium and thorium concentration as well as U-series isotope distributions in a Neanderthal tooth from Payre (Ardèche, France) using laser ablation ICP-MS. Geochimica et Cosmochimica Acta, 72, 5278–5290.

    Article  Google Scholar 

  • Hanchar, J. M., 1999. Spectroscopic techniques applied to uranium in minerals. In Burns, P. C., and Finch, R. (eds.), Uranium: Mineralogy, Geochemistry and the Environment. Washington, DC: Mineralogical Society of America. Reviews in Mineralogy, Vol. 38, pp. 499–519.

    Google Scholar 

  • Herdianita, N. R., Browne, P. R. L., Rogers, K. A., and Campbell, K. A., 2000. Mineralogical and textural changes accompanying ageing of silica sinter. Mineralium Deposita, 35, 48–62.

    Article  Google Scholar 

  • Jones, J. B., Sanders, J. V., and Segnit, E. R., 1964. Structure of opal. Nature, 204, 990–991.

    Article  Google Scholar 

  • Jones, J. B., and Segnit, E. R., 1971. The nature of opal. Part 1: nomenclature and constituent phases. Journal of the Geological Society of Australia, 8, 57–68.

    Article  Google Scholar 

  • Kano, K., 1983. Ordering of opal-CT in diagenesis. Geochemical Journal, 17, 87–93.

    Article  Google Scholar 

  • Langmuir, D., 1978. Uranium solution-mineral equilibria at low temperatures with applications to sedimentary ore deposits. Geochimica et Cosmochimica Acta, 42, 547–569.

    Article  Google Scholar 

  • Ludwig, K. R., and Paces, J. B., 2002. Uranium-series dating of pedogenic silica and carbonate, Crater Flat, Nevada. Geochimica et Cosmochimica Acta, 66, 487–506.

    Article  Google Scholar 

  • Ludwig, K. R., Lindsey, D. A., Zielinski, R. A., and Simmons, K. R., 1980. U-Pb ages of uraniferous opals and implications for the history of beryllium, fluorine, and uranium mineralization at Spor Mountain, Utah. Earth and Planetary Science Letters, 46, 221–232.

    Article  Google Scholar 

  • Luo, S., and Ku, T.-L., 1991. U-series isochron dating: a generalized method employing total sample dissolution. Geochimica et Cosmochimica Acta, 55, 555–564.

    Article  Google Scholar 

  • Maher, K., Wooden, J. L., Paces, J. B., and Miller, D. M., 2007. 230Th-U dating of surficial deposits using the ion microprobe (SHRIMP-RG): a microstratigraphic perspective. Quaternary International, 166, 15–28.

    Article  Google Scholar 

  • Neymark, L. A., Amelin, Y. V., and Paces, J. B., 2000. 206Pb-230Th-234U-238U and 207Pb-235U geochronology of quaternary opal, Yucca Mountain, Nevada. Geochimica et Cosmochimica Acta, 64, 2913–2928.

    Article  Google Scholar 

  • Neymark, L. A., and Paces, J. B., 2000. Consequences of slow growth for 230Th/U dating of quaternary opals, Yucca Mountain, Nevada, USA. Chemical Geology, 164, 143–160.

    Article  Google Scholar 

  • Neymark, L. A., Paces, J. B., and Amelin, Y. V., 2003. Reliability of U-Th-Pb dating of secondary silica at Yucca Mountain, Nevada. In High-Level Radioactive Waste Management, Proceedings of the Tenth International Conference, Las Vegas March 30 – April 2, 2003, American Nuclear Society, LaGrange Park, pp. 1–12.

    Google Scholar 

  • Paces, J. B., Neymark, L. A., Marshall, B. D., Whelan, J. F., and Peterman, Z. E., 2001. Ages and origins of calcite and opal in the exploratory studies facility tunnel, Yucca Mountain, Nevada. U.S. Geological Survey Water-Resources Investigations Report, 01-4049, 95 p.

    Google Scholar 

  • Paces, J. B., Neymark, L. A., Whelan, J. F., Wooden, J. L., Lund, S. P., and Marshall, B. D., 2010. Limited hydrologic response to Pleistocene climate change in deep vadose zones — Yucca Mountain, Nevada. Earth and Planetary Science Letters, 300, 287–298.

    Article  Google Scholar 

  • Paces, J. B., Neymark, L. A., Wooden, J. L., and Persing, H. M., 2004. Improved spatial resolution for U-series dating of opal at Yucca Mountain, Nevada, USA, using ion-microprobe and microdigestion methods. Geochimica et Cosmochimica Acta, 68, 1591–1606.

    Article  Google Scholar 

  • Porcelli, D., 2008. Investigating groundwater processes using U- and Th-series nuclides. In Krishnaswami, S., and Cochran, J. K. (eds.), U/Th Series Radionuclides in Aquatic Systems. Radioactivity in the Environment, Vol. 13, pp. 105–153.

    Chapter  Google Scholar 

  • Schwarcz, H. P., and Latham, A. G., 1989. Dirty calcites 1. Uranium-series dating of contaminated soils using leachates alone. Chemical Geology, 80, 35–43.

    Google Scholar 

  • Smith, D. K., 1998. Opal, cristobalite, and tridymite: noncrystallinity versus crystallinity, nomenclature of the silica minerals and bibliography. Powder Diffraction, 13, 2–19.

    Article  Google Scholar 

  • Stirling, C. H., Lee, D.–. C., Christensen, J. N., and Halliday, A. N., 2000. High-precision in situ 238U–234U–230Th isotopic analysis using laser ablation multiple-collector ICPMS. Geochimica et Cosmochimica Acta, 64, 3737–3750.

    Article  Google Scholar 

  • Szabo, B. J., and Kyser, T. K., 1985. Uranium, thorium isotopic analyses and uranium-series ages of calcite and opal, and stable isotopic compositions of calcite from drill cores UE25a#1, USW G-2 and USW G-3/GU-3, Yucca Mountain, Nevada. U.S. Geological Survey Open-File Report, 85–224, 25 p.

    Google Scholar 

  • Szabo, B. J., and Kyser, T. K., 1990. Ages and stable-isotope compositions of secondary calcite and opal in drill cores from tertiary volcanic rocks of the Yucca Mountain area, Nevada. Geological Society of America Bulletin, 102, 1714–1719.

    Article  Google Scholar 

  • Whelan, J. F., Paces, J. B., and Peterman, Z. E., 2002. Physical and stable-isotope evidence for formation of secondary calcite and silica in the unsaturated zone, Yucca Mountain, Nevada. Applied Geochemistry, 17, 735–750.

    Article  Google Scholar 

  • Winograd, I. J., Landwehr, J. M., Coplen, T. B., Sharpe, W. D., Riggs, A. C., Ludwig, K. R., and Kolesar, P. T., 2006. Devils Hole, Nevada, δ18O record extended to the mid-Holocene. Quaternary Research, 66, 202–212.

    Article  Google Scholar 

  • Zielinski, R. A., 1977. Uranium mobility during interaction of rhyolite glass with alkaline solutions: Dissolution of glass. U.S. Geological Survey Open-File Report, 77–744, 26 p.

    Google Scholar 

  • Zielinski, R. A., 1980. Uranium in secondary silica: a possible exploration guide. Economic Geology, 75, 592–602.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to James B. Paces .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2014 Springer Science Business Media Dordrecht (outside the USA)

About this entry

Cite this entry

Paces, J.B. (2014). Uranium Series, Opal. In: Rink, W., Thompson, J. (eds) Encyclopedia of Scientific Dating Methods. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-6326-5_230-1

Download citation

  • DOI: https://doi.org/10.1007/978-94-007-6326-5_230-1

  • Received:

  • Accepted:

  • Published:

  • Publisher Name: Springer, Dordrecht

  • Online ISBN: 978-94-007-6326-5

  • eBook Packages: Springer Reference Earth and Environm. ScienceReference Module Physical and Materials ScienceReference Module Earth and Environmental Sciences

Publish with us

Policies and ethics