Skip to main content

Electron Spin Resonance (ESR) Dating, General Principles

  • Living reference work entry
  • First Online:
Encyclopedia of Scientific Dating Methods

Synonyms

Electron paramagnetic resonance (EPR)

Definitions

Electron spin resonance: The identification of paramagnetic species through absorption of energy in an external magnetic field.

Electron spin resonance dating: The determination of burial age through measurement of the concentration of free radicals created by natural radiation.

Introduction

To understand electron resonance (ESR) dating, one must, clearly, first understand the principles of electron spin resonance spectroscopy. As the name shows, these principles begin with the nature of atomic structure – a positively charged nucleus surrounded by negatively charged electrons. The technique of ESR spectroscopy was first developed by Zavoisky in 1944. Since then applications have been developed in multiple fields of chemistry and physics, as well as the potential for dating in geology, paleontology, and archaeology. An excellent summary can be found in Rink (1997).

Quantum theory tells us that all systems have a definite...

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Institutional subscriptions

Bibliography

  • Aitken, M. J., Stringer, C. B., and Mellars, P. A. (eds.), 1993. The Origins of Modern Humans and the Impact of Chronometric Dating. Princeton, NJ: Princeton University Press.

    Google Scholar 

  • Bahain, J. J., Burrafato, G., Falguères, C., Gueli, A. M., Stella, G., Troja, S. O., and Zuccarello, A. R., 2011. ESR and U/Th dating methodologies applied to carbonates from Southern Italy. In Turbanti-Memmi, I. (ed.), Proceedings of the 37th International Symposium on Archaeometry. Heidelberg: Springer.

    Google Scholar 

  • Blackwell, B. A. B., Skinner, A. R., and Blickstein, J. I. B., 2001. ESR isochron exercises: how accurately do modern dose rate measurements reflect paleodose rates? Quaternary Geochronology, 20, 1031–1039.

    Google Scholar 

  • Blackwell, B. A. B., Skinner, A. R., Brassard, P., and Blickstein, J. I. B., 2002. Uptake in tooth enamel: Lessons from isochron analyses and laboratory simulation experiments. Advances in ESR Applications, 18, 65–86.

    Google Scholar 

  • Buhay, W. M., Schwarcz, H. P., and Grün, R., 1988. ESR dating of fault gouge: the effect of grain size. Quaternary Science Reviews, 7, 515–522.

    Article  Google Scholar 

  • Callens, F. J., Verbeeck, R. M., Naessens, D. E., Matthys, P. F., and Boesman, E. R., 1989. Effect of carbonate content on the ESR spectrum near g = 2 of carbonated calcium apatites synthesized from aqueous media. Calcified Tissue International, 44(2), 114–124.

    Article  Google Scholar 

  • Deely, A. E., Blackwell, B. A. B., Mylroie, J. E., Carew, J. L., Blickstein, J. I. B., and Skinner, A. R., 2011. Testing cosmic dose rate models for ESR: dating corals and molluscs on San Salvador, Bahamas. Radiation Measurements, 46, 853–859.

    Article  Google Scholar 

  • Dibble, H., Aldeias, V., Alvarez-Fernandez, E., Blackwell, B. A. B., Hallett-Desguez, E., Jacobs, A., Goldberg, P., Lin, A., Morala, A., Olszewski, D., Reed, K., Reed, D., Rezek, A., Richter, D., Roberts, R. G., Sandgathe, D., Schurmans, U., Skinner, A. R., Steele, T., and El-Hajraoui, M., 2012. New excavations at the site of contrebandiers Cave, Morocco. PaleoAnthropology, 2012, 145–201.

    Google Scholar 

  • Döppes, D., Kempe, S., and Rosendahl, W., 2008. Dated paleontological cave sites of Central Europe from Late Middle Pleistocene to early Upper Pleistocene (OI5 to OIS8). Quaternary International, 187, 97–104.

    Article  Google Scholar 

  • Duval, M., 2012. Dose response curve of the ESR signal of the Aluminum center in quartz grains extracted from sediment. Ancient TL, 30(2), 41–50.

    Google Scholar 

  • Duval, M., and Arnold, L. J., 2013. Field gamma dose-rate assessment in natural sedimentary contexts using LaBr3(Ce) and NaI(Tl) probes: a comparison between the “threshold” and “windows” techniques. Applied Radiation and Isotopes, 74, 36–45.

    Article  Google Scholar 

  • Duval, M., Falguères, C., and Bahain, J.-J., 2012. Age of the oldest hominin settlements in Spain: contribution of the combined U-series/ESR dating method applied to fossil teeth. Quaternary Geochronology, 10, 412–417.

    Article  Google Scholar 

  • Fukuchi, T., Imai, N., and Shimokawa, K., 1986. ESR dating of fault movement using various defect centres in quartz; the case in the western South Fossa Magnam, Japan. Earth & Planetary Science Letters, 78, 121–128.

    Article  Google Scholar 

  • Grün, R., 1992. Suggestions for minimum requirements for reporting ESR age estimates. Ancient TL, 10, 37–41.

    Google Scholar 

  • Grün, R., 2007. Electron spin resonance dating. In Scott A. Elias (ed) Encyclopedia of Quaternary Science. Oxford: Elsevier, pp. 1505–1516.

    Google Scholar 

  • Grün, R., and McDermott, F., 1994. Open system modeling for U-Series and ESR dating of teeth. Quaternary Geochronology (Quaternary Science Reviews), 13, 121–125.

    Article  Google Scholar 

  • Haskell, E., Kenner, G., Hayes, R., Sholom, S., and Chumak, V., 1997. An EPR intercomparison using teeth irradiated prior to crushing. Radiation Measurements, 27(2), 419–424.

    Article  Google Scholar 

  • Hennig, G. J., Geyh, M. A., and Grün, R., 1982. The first inter-laboratory ESR comparison project phase II: evaluation of equivalent doses (ED) of calcites. Nuclear Tracks and Radiation Measurements, 10(4–6), 945–952.

    Google Scholar 

  • Ikeya, M., 1978. Electron spin resonance as a method of dating. Archaeometry, 20, 147–158.

    Article  Google Scholar 

  • Ikeya, M., 1993. New Applications of Electron Spin Resonance. Singapore: World Scientific.

    Book  Google Scholar 

  • Kai, A., Miki, T., and Ikeya, M., 1988. ESR dating of teeth, bones and eggshells excavated at a Paleolithic site of Doura Cave, Syria. Quaternary Science Reviews, 7, 503–507.

    Article  Google Scholar 

  • Kasuya, M., Brumby, S., and Chappell, J., 1991. ESR signals from natural gypsum single crystals: implications for ESR dating. Nuclear Tracks and Radiation Measurements, 18, 329–333.

    Article  Google Scholar 

  • Lyons, R., 1989. Contributions to Electron Spin Resonance Dating. PhD thesis, University of Auckland.

    Google Scholar 

  • Mascarenhas, S., Baffa Filho, O., and Ikeya, M., 1982. Electron spin resonance dating of human bones from Brazilian shell-mounds (Sambaquis). American Journal of Physical Anthropology, 59, 413–417.

    Article  Google Scholar 

  • Mathew, G., Rao, T.K.G., Shoni, P.S., Karanth, P.V., 2004. ESR dating of interfault gypsum from Katrol hill range, Kachchh, Gujarat: Implications for neotectonism. Current Science,89, 1269–1274.

    Google Scholar 

  • McKeever, S. W. S., and Moscovitch, M., 2003. On the advantages and disadvantages of optically stimulated luminescence dosimetry and thermoluminescence dosimetry. Radiation Protection Dosimetry, 104, 263–270.

    Article  Google Scholar 

  • Molodkov, A., 1998. ESR dating of quaternary shells: recent advances. Quaternary Science Reviews, 7, 477–484.

    Article  Google Scholar 

  • Monnier, J. L., Hallégouët, B., Hinguant, S., Laurent, M., Auguste, P., Bahain, J.-J., Falguères, C., Gebhardt, A., Marguerie, D., Molines, N., Morzadec, H., and Yokoyama, Y., 1994. A new regional group of the Lower Palaeolithic in Brittany (France), recently dated by Electron Spin Resonance. Comptes Rendus de l'Académie des sciences de Paris, 319, 155–160.

    Google Scholar 

  • Murray, A. S., Olley, J. M., and Wallbrink, P. J., 1992. Natural radionuclide behavior in the fluvial environment. Radiation Protection Dosimetry, 45, 285–288.

    Google Scholar 

  • Nambi, K. S. V., 1982. ESR and TL dating studies on some marine gypsum crystals. PACT Journal, 6, 314–321.

    Google Scholar 

  • Prescott, J. R., and Hutton, J. T., 1988. Cosmic ray and gamma ray dosimetry for TL and ESR. Nuclear Tracks and Radiation Measurements, 14, 223–227.

    Article  Google Scholar 

  • Radtke, U., Grün, R., and Schwarcz, H. P., 1988. Electron spin resonance dating of the pleistocene coral reef tracts of barbados. Quaternary Research, 29, 197–215.

    Article  Google Scholar 

  • Richter, D., Dombrowski, H., Neumaier, S., Guibert, P., and Zink, A. C., 2010. Environmental gamma dosimetry with OSL of α-Al2O3:c for in situ sediment measurements. Radiation Protection Dosimetry, 141, 27–35.

    Article  Google Scholar 

  • Rink, W. J., 1997. Electron spin resonance (ESR) dating and ESR applications in quaternary science and archaeometry. Radiation Measurements, 27, 975–1025.

    Article  Google Scholar 

  • Rink, W. J., Schwarcz, H. P., Lee, H. K., Valdés, V. C., de Quirós, F. B., and Hoyos, M., 1996. ESR dating of tooth enamel: comparison with AMS 14C at El Castillo Cave, Spain. Journal of Archaeological Science, 23, 945–951.

    Article  Google Scholar 

  • Sato, F., Toyoda, S., Banerjee, D., and Ishibashi, J., 2011. Thermal stability of ESR signals in hydrothermal barite. Radiation Measurements, 46, 866–870.

    Article  Google Scholar 

  • Schellmann, G., and Radtke, U., 2004. A revised morpho- and chronostratigraphy of the Late and Middle Pleistocene coral reef terraces on Southern Barbados (West Indies). Earth-Science Reviews, 64(3–4), 157–187.

    Article  Google Scholar 

  • Schellmann, G., Beerten, K., and Radtke, U., 2008. Electron spin resonance (ESR) dating of Quaternary materials. Eiszeitalter und Gegenwart (Quaternary Science Journal), 57, 150–178.

    Google Scholar 

  • Schwarcz, H. P., 1985. ESR studies of tooth enamel. Nuclear Tracks, 10, 865–867.

    Google Scholar 

  • Schwarcz, H. P., and Rink, W. J., 2001. Skinflint dating. Quaternary Science Reviews, 20, 1047–1050.

    Article  Google Scholar 

  • Skinner, A. R., 1983. Overestimate of stalagmitic calcite ESR dates due to laboratory heating. Nature, 304, 152.

    Article  Google Scholar 

  • Skinner, A. F., 1985. Comparison of ESR and 230Th/234U ages in fossil aragonitic corals. In Proceedings of the First International Symposium on ESR Dating, Ionics Ube, Japan, pp. 135–138.

    Google Scholar 

  • Skinner, A. R., and Rudolph, M. N., 1997. The use of the E signal in flint for ESR dating. Applied Radiation and Isotopes, 47, 1399–1404.

    Article  Google Scholar 

  • Skinner, A. R., Blackwell, B. A. B., Chasteen, N. D., Shao, J., and Min, S. S., 2000. Improvements in dating tooth enamel by ESR. Applied Radiation and Isotopes, 52, 1337–1344.

    Article  Google Scholar 

  • Skinner, A. R., Blackwell, B. A. B, Lothian, V.S., 2001a. Calibrating ESR dating using 2 Myr-old teeth Paleoanthropology Society Abstracts, P.16

    Google Scholar 

  • Skinner, A. R., Chasteen, N. D., Shao, J., and Blackwell, B. A. B., 2001b. Q-band studies of the ESR signal in tooth enamel. Quaternary Science Reviews (Quaternary Geochronology), 20, 1027–1030.

    Article  Google Scholar 

  • Steinhauser, G., Sterba, J. H., and Hammer, V. M., 2013. Nuclear forensics of a colored gemstone: evidence of proton bombardment of a blue topaz. Applied Radiation and Isotopes, 75, 18–21.

    Article  Google Scholar 

  • Toyoda, S., Ikeya, M., Dunnell, R. C., and McCutcheon, P. T., 1993. The use of electron spin resonance (ESR) for the determination of prehistoric lithic heat treatment. Applied Radiation and Isotopes, 44, 227–231.

    Article  Google Scholar 

  • Toyoda, S., Voinchet, P., Falguères, C., Dolo, J. M., and Laurent, M., 2000. Bleaching of ESR signals by the sunlight: a laboratory experiment for establishing the ESR dating of sediments. Applied Radiation and Isotopes, 52, 1357–1362.

    Article  Google Scholar 

  • Walther, R., and Zilles, D., 1994. ESR studies on bleached sedimentary quartz. Quaternary Science Reviews, 13, 611–614.

    Article  Google Scholar 

  • Xu, L., and Zhou, S., 2009. Quaternary glaciations recorded by glacial and fluvial landforms in the Shaluli Mountains, Southeastern Tibetan Plateau. Geomorphology, 103(2), 268–275.

    Article  Google Scholar 

  • Zavoisky, E., 1945. Spin-magnetic resonance in paramagnetics. Journal of Physics, 9, 245.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Anne Skinner .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2014 Springer Science+Business Media Dordrecht

About this entry

Cite this entry

Skinner, A. (2014). Electron Spin Resonance (ESR) Dating, General Principles. In: Rink, W., Thompson, J. (eds) Encyclopedia of Scientific Dating Methods. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-6326-5_6-1

Download citation

  • DOI: https://doi.org/10.1007/978-94-007-6326-5_6-1

  • Received:

  • Accepted:

  • Published:

  • Publisher Name: Springer, Dordrecht

  • Online ISBN: 978-94-007-6326-5

  • eBook Packages: Springer Reference Earth and Environm. ScienceReference Module Physical and Materials ScienceReference Module Earth and Environmental Sciences

Publish with us

Policies and ethics