Abstract
1(2)-Methyl-5-aminotetrazoles and 2-(Β-cyanoethyl)-5-aminotetrazole are nitrated by tetranitromethane in the presence of bases with the formation of salts of the corresponding 5-nitroaminotetrazole derivatives. In contrast to this, decyanoethylation takes place in nitration of 1-(Β-cyanoethyl)-5-aminotetrazole by tetranitromethane with the formation of 5-nitroaminotetrazole salt. The structure of the 2-methyl-5-nitroaminotetrazole salts (using the 2-methyl-5-nitroaminotetrazole potassium salt) was confirmed by x-ray structural analysis.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1067–1071, August, 1991.
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Mayants, A.G., Klimenko, V.S., Erina, V.V. et al. N-nitration of 1(2)-substituted 5-aminotetrazoles with tetranitromethane. Chem Heterocycl Compd 27, 854–858 (1991). https://doi.org/10.1007/BF00472285
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DOI: https://doi.org/10.1007/BF00472285