Abstract
The electronic structures of a number of methyl-substituted heterocyclces containing a thiophene or furan ring condensed with a thiazole or pyridine ring and of their quaternary salts and methylene bases were calculated by the Pariser-Parr-Pople method. The features of the electronic structures of the investigated molecules were ascertained. It is shown that methyl-substituted thienothiazoles and thieno- and furopyridines and their quaternary salts are appreciably inferior to the corresponding benzothiazoles and quinoline derivatives used for the synthesis of polymethine dyes with respect to the reactivity of the methyl group.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1202–1206, September, 1976.
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Abramenko, P.I., Kosobutskii, V.A. Electronic structures and reactivities of methyl-substituted thienothiazoles and thieno- and furopyridines. Chem Heterocycl Compd 12, 995–998 (1976). https://doi.org/10.1007/BF00480390
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DOI: https://doi.org/10.1007/BF00480390