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Reactions involving isotopic exchange of heterocyclic compounds with D2O in the presence of transition metals (review)

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The results of isotopic exchange with D2O of various O-, N-, and S-containing heterocycles and some hydrocarbons on transition metals are discussed from the positions of the theory of π-complex adsorption. The effect of various fragments of the molecules (the aromatic or alicyclic ring, electron-donor or electron-acceptor substituents, double bonds, and the number and nature of the heteroatoms) on the character of the substrate-catalyst interaction and on the reaction as a whole is examined on the basis of kinetic data from 1H and 13C NMR spectroscopy and Chromatographic mass spectrometry. Isotopic exchange mechanisms are discussed.

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, 117234, Moscow

    É. A. Karakhanov & A. G. Dedov

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  1. É. A. Karakhanov
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  2. A. G. Dedov
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1011–1021, August, 1982.

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Karakhanov, É.A., Dedov, A.G. Reactions involving isotopic exchange of heterocyclic compounds with D2O in the presence of transition metals (review). Chem Heterocycl Compd 18, 763–772 (1982). https://doi.org/10.1007/BF00506573

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  • DOI: https://doi.org/10.1007/BF00506573

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