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Structural investigations of isomeric 2,4-diphenyl-7,8-benzohexahydrothiochromenes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Structural investigations were carried out by means of PMR spectroscopy and x-ray diffraction analysis, and the type of fusion of the heterorings and alicyclic rings in isomeric 2,4-diphenyl-7,8-benzohexahydrothiochromenes previously obtained by the disproportionation and ionic and catalytic hydrogenation of 2,4-diphenyl-7,8-benzo-5, 6-dihydrothiochromene was established. The predominant realization of a diastereomer with trans-fused heterorings and alicyclic rings in all of the reactions mentioned above was demonstrated; the possibility of the formation of the eis isomer in the catalytic reduction of benzodihydrothiochromene was confirmed.

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Authors and Affiliations

  1. N. G. Chernyshevskii Saratov State University, 410601, Saratov

    V. G. Kharchenko, A. P. Kriven'ko, O. V. Fedotova, A. A. Shcherbakov, G. G. Aleksandrov & Yu. T. Struchkov

  2. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, 117312, Moscow

    V. G. Kharchenko, A. P. Kriven'ko, O. V. Fedotova, A. A. Shcherbakov, G. G. Aleksandrov & Yu. T. Struchkov

Authors
  1. V. G. Kharchenko
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  2. A. P. Kriven'ko
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  3. O. V. Fedotova
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  4. A. A. Shcherbakov
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  5. G. G. Aleksandrov
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  6. Yu. T. Struchkov
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1060–1063, August, 1980.

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Kharchenko, V.G., Kriven'ko, A.P., Fedotova, O.V. et al. Structural investigations of isomeric 2,4-diphenyl-7,8-benzohexahydrothiochromenes. Chem Heterocycl Compd 16, 821–824 (1980). https://doi.org/10.1007/BF00513162

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  • DOI: https://doi.org/10.1007/BF00513162

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