Skip to main content
Log in

Infrared spectra and composition dependence investigations of the vitreous V2O5/P2O5 system

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

A series of glasses in the V2O5-P2O5 system was prepared and their compositions analysed. The glass densities and molar volumes were determined. The results obtained revealed three compositional regions. In addition, the infrared absorption spectra of these glasses were measured at room temperature in the frequency range 1600–200 cm−1. The compositional dependence of the bands present, attributed to a given band and mode of vibration, was investigated. However, the infrared data confirmed the results obtained from the density and molar volume measurements.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. H. Harper and P. W. McMillan, Phys. Chem. Glasses15 (1974) 148.

    CAS  Google Scholar 

  2. M. Munakata, Solid State Electron.1 (1960) 159.

    Article  CAS  Google Scholar 

  3. Bh. V. Janakirama Rao, J. Amer. Ceram. Soc.49 (1966) 605.

    Article  CAS  Google Scholar 

  4. F. R. Land Sbergeral and P. J. Bray, J. Chem. Phys.53 (1970) 2757.

    Article  Google Scholar 

  5. A. A. Higazy and B. Bridge, Phys. Chem. Glasses26 (1985) 82.

    CAS  Google Scholar 

  6. A. A. Higazy, M. A. Ewaida, A. Hussein and R. M. El-Bahnasawy, Ind. J. Phys.63A(2) (1989) 124.

    CAS  Google Scholar 

  7. I. Simmon, in “Modern Aspects of the Vitreous State” edited by J. D. Mackenzie (Butterworths, London, 1960) pp. 120–151.

    Google Scholar 

  8. J. Reitzl, J. Chem. Phys.23 (1955) 2407.

    Article  Google Scholar 

  9. I. Simmon and H. O. McHahon, J. Chem. Phys.21 (1953) 21.

    Google Scholar 

  10. G. J. Su, N. U. Borrell and A. R. Miller, Phys. Chem. Glasses3(S) (1962) 167.

    CAS  Google Scholar 

  11. N. F. Borrelli and G. J. Su, ibid.4 (1963) 206.

    Google Scholar 

  12. C. K. Shih and G. J. Su, in “Proceedings of the seventh International Congress on Glass”, Brussels, Paper 48 (1965) p. 133.

    Google Scholar 

  13. A. A. Higazy and B. Bridge, J. Mater. Sci.20 (1985) 2345.

    Article  CAS  Google Scholar 

  14. N. F. Borrelli and G. J. Su, Mater. Res. Bull.3 (1968) 181.

    Article  CAS  Google Scholar 

  15. R. M. Almeida and J. D. Makenzie, J. Non-Cryst. Solids40 (1980) 535.

    Article  CAS  Google Scholar 

  16. VOGEL's “Textbook of Quantitative Inorganic Analysis”, 4th Edn (ELBS Longman, 1985) pp. 390, 498.

  17. L. W. Andrews, J. Amer. Chem. Soc.25 (1903) 756.

    Article  CAS  Google Scholar 

  18. G. S. Jamieson, “Volumetric Iodate Methods” (Reinhold, New York, 1926).

    Google Scholar 

  19. Bh. V. Janakirama-Rao, J. Amer. Ceram. Soc.48 (1965) 311.

    Article  CAS  Google Scholar 

  20. C. Calvo and B. D. Jordan, Phys. Chem. Glasses17 (1976) 220.

    CAS  Google Scholar 

  21. C. F. Drake, T. A. Stephan and B. Yates, J. Non-Cryst. Solids28 (1978) 61.

    Article  CAS  Google Scholar 

  22. M. N. Khan, R. Harani, M. M. Ahmed and C. A. Hogarth, J. Mater. Sci.20 (1985) 2207.

    Article  CAS  Google Scholar 

  23. G. W. Anderson and W. D. Compton, J. Chem. Phys.52 (1970) 6166.

    Article  CAS  Google Scholar 

  24. M. Sayer, A. Mansingh, J. M. Reyes and G. F. Lynch, in “Proceedings of the 2nd International Conference in Low Mobility Materials” Eilat, Israel (Taylor and Francis, 1971) p. 115.

  25. F. Dachille and R. Roy, ibid.42 (1965) 78.

    Google Scholar 

  26. N. A. Ghoneim, J. Non-Cryst. Solids56 (1983) 367.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Khafagy, A.H., Ewaida, M.A., Higazy, A.A. et al. Infrared spectra and composition dependence investigations of the vitreous V2O5/P2O5 system. J Mater Sci 27, 1435–1439 (1992). https://doi.org/10.1007/BF00542899

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00542899

Keywords

Navigation