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Glycosides of marine invertebrates. XIII. New holothurinogenins of holothurin B1 fromHolothuria floridana

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Abstract

We have isolated for the first time the native aglycone of a triterpene glycoside of the holoturin series — holothurin B1 — and have established its structure as holost-9-ene-3β,12α,17α-triol. The structures of two new holostane derivatives have been established — holosta-8,11-diene-3β,17α-diol and 3β,17α-dihydroxyholost-9-en-12-one. A scheme of transformation of the native genin of holothurin B1 under the conditions of the acid splitting of the glycoside has been put forward.

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Authors
  1. G. B. Elyakov
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  2. N. I. Kalinovskaya
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  3. A. I. Kalinovskii
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  4. V. A. Stonik
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  5. T. A. Kuznetsova
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Additional information

Pacific Ocean Institute of Bioorganic Chemistry, Far Eastern Scientific Center, Academy of Sciences of the USSR, Vladivostok. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 323–327, May–June, 1982.

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Elyakov, G.B., Kalinovskaya, N.I., Kalinovskii, A.I. et al. Glycosides of marine invertebrates. XIII. New holothurinogenins of holothurin B1 fromHolothuria floridana . Chem Nat Compd 18, 298–302 (1982). https://doi.org/10.1007/BF00580455

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  • DOI: https://doi.org/10.1007/BF00580455

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