Abstract
While the reactions of N-diethylaminopropyne, methacrylonitrile and N-benzylidenemethylamine with organoboranes lead to addition of the latter across the multiple bond, methacrylonitrile and N-benzylidenemethylamine react with trichloroborane to yield adducts only.
Similar content being viewed by others
Literatur
Ya. N. Bubnov undB. M. Mikhailov, Izv. Akad. Nauk SSSR, Ser. Khim.1967, 472.
Ya. N. Bubnov, J. Obshch. Khim.38, 260 (1968).
V. A. Dorokhov undM. F. Lappert, Chem. Commun.1968, 250.
V. A. Dorokhov undM. F. Lappert, J. Chem. Soc.A 1969, 433.
H. C. Brown undG. Z. Zweifel, J. Amer. Chem. Soc.82, 4708 (1960).
H. C. Brown undR. L. Sharp, J. Amer. Chem. Soc.88, 5851 (1966).
A. Meller, Organometal. Chem. Rev.2, 1 (1967).
W. Gerrard undM. F. Lappert, J. Chem. Soc. [London]1960, 2182.
H. C. Brown undH. Peasall, J. Amer. Chem. Soc.67, 1765 (1945).
B. M. Mikhailov undF. B. Tutorskaja, Dokl. Akad. Nauk SSSR123, 480 (1958).
Author information
Authors and Affiliations
Additional information
Herrn Prof. Dr.E. Hayek anläßlich seines 70. Geburtstages gewidmet.
2. Mitt.: Mh. Chem.105, 637 (1974).
Rights and permissions
About this article
Cite this article
Meller, A., Gerger, W. Umsetzungen von ungesättigten Organo-Stickstoffverbindungen mit Organoboranen bzw. Trichlorboran. Monatshefte für Chemie 105, 684–688 (1974). https://doi.org/10.1007/BF00912966
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF00912966