Abstract
By the interaction of 2-acetyl-5,5-dimethyl-2-cyclohexen-1-one with certain nitroenamines, a number of hexahydro-8-isoquinolones with a nitro group in position 4 have been obtained; potentials of their electrochemical oxidation have been determined, and a possible mechanism and manifestation of structural effects in this process have been suggested and discussed. The structure of 1,3,6,6-tetramethyl-4-nitro-2, 4a-5,6,7,8-hexahydro-8-isoquinolone has been established by means of x-ray diffraction analysis.
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Latvian Institute of Organic Synthesis, Riga LV-11006. E-mail: aiva@osi.lanet.lv. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1372–1380, October, 1998.
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Ozols, Y., Vigante, B., Baumane, L. et al. Hexahydro-8-isoquinolones with electron-acceptor substituents in position 4. Chem Heterocycl Compd 34, 1166–1173 (1998). https://doi.org/10.1007/BF02319495
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DOI: https://doi.org/10.1007/BF02319495